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Mauro Zammarano, Paul H. Maupin, Li Piin Sung, Jeffrey W. Gilman, Douglas M. Fox
Morphological characterization of polymer nanocomposites is a fundamental challenge that is complicated by multiple length scales. Here, we report a technique for high-throughput monitoring of interphase and dispersion in polymer nanocomposites based on
Paul C. DeRose, Melody V. Smith, Klaus Mielenz, Jeffrey R. Anderson, Gary W. Kramer
Standard Reference Material (SRM) 2942 is a cuvette-shaped, Ce-ion-doped glass, recommended for use for relative spectral correction of emission and day-to-day performance verification of steady-state fluorescence spectrometers. Properties of this standard
Triphenylphosphine (PPh3) is commonly used during syntheses of stable closed-shell monolayer protected clusters (MPCs). Models of transition metal (TM) cluster and nanoparticle syntheses commonly assign PPh3 a passive role as a chemical placeholder
Konrad Rykaczewski, John H. Scott, Andrei G. Fedorov
Nanostructured superhydrophobic surfaces show promise as promoters of dropwise condensation and may lead to significant efficiency improvements in numerous industrial processes. Droplets with diameters below ~10 µm account for the majority of the heat
Christopher C. White, Kar T. Tan, Emmett P. O'Brien, Donald L. Hunston, R. S. Williams
The paper describes the development, implementation and testing of two thermally driven outdoor exposure instruments. These devices are unique in their ability to impose thermally driven strain while monitoring the resulting stress and displacement for
John M. Harris, Ganjigunte R. Iyer, Daneesh O. Simien, Jeffrey Fagan, JiYeon Huh, Jun Y. Chung, Steven Hudson, Jan Obrzut, Jack F. Douglas, Christopher Stafford, Erik K. Hobbie
Thin membranes of length purified single-wall carbon nanotubes (SWCNTs) are uniaxially compressed by depositing them on prestretched polymer substrates. Upon release of the strain, the topography, microstructure and conductivity of the films are
Christopher C. White, Kar T. Tan, Donald L. Hunston
Sustainability calculations are based on assumptions about the energy required to produce, transport place in-service items. A critical component of these calculations is the expected service life of the material, component or system. Estimates of the
John A. Howarter, Peter M. Johnson, Jun Y. Chung, Christopher Stafford
The delamination characteristics of patterned and hierarchical interfaces are of great interest due to the advanced adhesion capabilities found with many biological surfaces. Using nature-inspired design principles, micro- and nanostrucutred surfaces have
Fan Zhang, Andrew J. Allen, Lyle E. Levine, Jan Ilavsky, Gabrielle G. Long, Anthony M. Santana
In this paper, we present the development of ultrasmall-angle X-ray scattering - X-ray photon correlation spectroscopy (USAXS-XPCS). This technique takes advantage of Bonse-Hart crystal optics and is capable of probing the slow equilibrium and
The results of a study of using neutron diffraction for determining the retained austenite content of TRIP steels are presented. The study covers a wide area of materials, deformation modes (uniaxial, biaxial and plane strain), strains, and the retained
David L. VanderHart, Jack F. Douglas, Steven Hudson, Joseph M. Antonucci, Elizabeth A. Wilder
The molecule 1,3:2,4-Di-O-Benzylidene sorbitol (DBS) is a common gelator that forms thermally reversible gels in diverse organic solvents. Solid state 13C and proton NMR techniques, along with electron microscopy, are utilized in an exploratory study of
Variable temperature high resolution far infrared absorption measurements were carried out for single walled carbon nanotubes samples with different diameter distributions. At a temperature where kBT is significantly lower than the phonon energy, the broad
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general
Paul A. O'Connell, Greg B. McKenna, Edwin Chan, Christopher Stafford
Recently Chan et al. published a paper describing a method to use the wrinkling of a thin elastic film on which is adhered a thin polymer film to extract the viscoelastic properties of the polymer. Results were presented for the rubbery plateau modulus and
Carl G. Simon Jr., Kaushik Chatterjee, Laurence C. Chow, Limin Sun, Marian F. Young
There is a need to improve rapid methods for screening cell-biomaterial interactions. Current methods employ a flat 2D format even though 3D scaffolds are more representative of the tissue environment in vivo and cells are responsive to topological
Edwin P. Chan, Santanu S. Kundu, Qinhuang Lin, Christopher M. Stafford
The viscoelastic properties of polymer thin films can have a significant impact on the performance in many small-scale devices. In this work, we use thermal wrinkling, which is a phenomenon based on a thermally-initiated instability, to measure
Structural properties of polymeric scaffolds for bone tissue engineering play key role in directing osteogenesis. These properties depend on the chemical nature and the fabrication process of biomaterial. There are many protocols for fabricating scaffolds
Rahul P. Trivedi, Kristine A. Bertness, Ivan I. Smalyukh
We develop an integrated system of holographic optical trapping and multimodal nonlinear microscopy and perform simultaneous three-dimensional optical manipulation and non-invasive structural imaging of composite soft-matter systems. We combine different
Yeon Sook Chung, Nayool Shin, Jihoon Kang, Youngeun Jo, Vivek Prabhu, Regis J. Kline, John E. Anthony, Do Y. Yoon
The blend films of small molecule semiconductors with insulating polymers exhibit not only an excellent solution processability, but also superior performance characteristics (field-effect mobility, on/off ratio, threshold voltage and stability) over those
In this paper, we will provide an overview of the internal photoemission (IPE) and the significance of this technique when combined with spectroscopic ellipsometry (SE) to investigate the interfacial electronic properties of heterostructures. In particular
Benita Dair, Dave M. Saylor, T. E. Cargal, Grace R. French, Kristen M. Kennedy, Rachel S. Casas, Jonathan E. Guyer, James A. Warren, Steven K. Pollack
With the advent of Nanotechnology, silver nanoparticles increasingly are being used in coatings, especially in medical device applications, to capitalize on their antimicrobial properties. The increased antimicrobial efficacy of nanoparticulate silver
Nicholas Nanninga, Andrew J. Slifka, Yaakov Levy, Calvin L. White
Hydrogen pipeline systems offer an economical means of storing and transporting energy in the form of hydrogen gas. Pipelines can be used to transport hydrogen that has been generated at solar and wind farms to and from salt cavern storage locations. In
The use of cementitious materials has been proposed in a variety of waste management systems because these materials can have a variety of desirable performance characteristics: hydraulic isolation, chemical isolation, structural stability. Cementitious
A new kind of physical gels was prepared using the mixtures of poly(vinyl alcohol) (PVOH) and high melting ionic liquid (IL), 1-ethylpyridinium bromide. As the IL content was increased, the stiffness of the mixtures decreased sharply while extensibility