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In this talk I will 1) briefly review SEDs history of the optical thin metrology project, 2) describe the principle of internal photoemission (IPE) and the applications to determine the band alignments of metal-oxide-semiconductor structures, and 3)
Two selected members of the homologous series, An+2BBnO3n+3 (A= Sr, and Ca; B and B=Co) have been investigated for their crystal structure because of their potential applications as thermoelectric materials. A combined Rietveld refinement and a spin
Mingdong M. Li, Suvajyoti S. Guha, Rebecca A. Zangmeister, Michael J. Tarlov, Michael R. Zachariah
Electrospray (ES) sources are commonly used to introduce non-volatile materials (e.g. nanoparticles, proteins, etc.) in to the gas phase for characterization by mass spectrometry and ion mobility. Recent studies in our group using electrospray ion mobility
The 2010 Materials Research Society (MRS) Fall Meeting took place in the Hynes Convention Center and the Sheraton Boston Hotel, starting the weekend following the Thanksgiving Holidays from November 27 to December 3. This large-scale meeting included forty
We investigate a new kind of PVOH physical gel in which the volatile water is replaced with a non-volatile ionic liquid (IL). High melting IL containing Br- anion was chosen so that the hydrogen-bond accepting Br- can enhance miscibility with PVOH while
Xiaohong Gu, Somia Awad, Hongmin Chen, James Lee, E. Abdel-Hady, Y Jean
The free volume properties in a system of zinc oxide (ZnO) nanoparticles (20 nm) dispersed in waterborne polyurethane (WBPU) were measured using positron annihilation lifetime spectroscopy. Two glass-transition temperatures (Tg), lower Tg ~ 220 K and
Mauro Zammarano, Paul H. Maupin, Li Piin Sung, Jeffrey W. Gilman, Douglas M. Fox
Morphological characterization of polymer nanocomposites is a fundamental challenge that is complicated by multiple length scales. Here, we report a technique for high-throughput monitoring of interphase and dispersion in polymer nanocomposites based on
Paul C. DeRose, Melody V. Smith, Klaus Mielenz, Jeffrey R. Anderson, Gary W. Kramer
Standard Reference Material (SRM) 2942 is a cuvette-shaped, Ce-ion-doped glass, recommended for use for relative spectral correction of emission and day-to-day performance verification of steady-state fluorescence spectrometers. Properties of this standard
Triphenylphosphine (PPh3) is commonly used during syntheses of stable closed-shell monolayer protected clusters (MPCs). Models of transition metal (TM) cluster and nanoparticle syntheses commonly assign PPh3 a passive role as a chemical placeholder
Konrad Rykaczewski, John H. Scott, Andrei G. Fedorov
Nanostructured superhydrophobic surfaces show promise as promoters of dropwise condensation and may lead to significant efficiency improvements in numerous industrial processes. Droplets with diameters below ~10 µm account for the majority of the heat
Christopher C. White, Kar T. Tan, Emmett P. O'Brien, Donald L. Hunston, R. S. Williams
The paper describes the development, implementation and testing of two thermally driven outdoor exposure instruments. These devices are unique in their ability to impose thermally driven strain while monitoring the resulting stress and displacement for
John M. Harris, Ganjigunte R. Iyer, Daneesh O. Simien, Jeffrey Fagan, JiYeon Huh, Jun Y. Chung, Steven Hudson, Jan Obrzut, Jack F. Douglas, Christopher Stafford, Erik K. Hobbie
Thin membranes of length purified single-wall carbon nanotubes (SWCNTs) are uniaxially compressed by depositing them on prestretched polymer substrates. Upon release of the strain, the topography, microstructure and conductivity of the films are
Christopher C. White, Kar T. Tan, Donald L. Hunston
Sustainability calculations are based on assumptions about the energy required to produce, transport place in-service items. A critical component of these calculations is the expected service life of the material, component or system. Estimates of the
John A. Howarter, Peter M. Johnson, Jun Y. Chung, Christopher Stafford
The delamination characteristics of patterned and hierarchical interfaces are of great interest due to the advanced adhesion capabilities found with many biological surfaces. Using nature-inspired design principles, micro- and nanostrucutred surfaces have
Fan Zhang, Andrew J. Allen, Lyle E. Levine, Jan Ilavsky, Gabrielle G. Long, Anthony M. Santana
In this paper, we present the development of ultrasmall-angle X-ray scattering - X-ray photon correlation spectroscopy (USAXS-XPCS). This technique takes advantage of Bonse-Hart crystal optics and is capable of probing the slow equilibrium and
The results of a study of using neutron diffraction for determining the retained austenite content of TRIP steels are presented. The study covers a wide area of materials, deformation modes (uniaxial, biaxial and plane strain), strains, and the retained
David L. VanderHart, Jack F. Douglas, Steven Hudson, Joseph M. Antonucci, Elizabeth A. Wilder
The molecule 1,3:2,4-Di-O-Benzylidene sorbitol (DBS) is a common gelator that forms thermally reversible gels in diverse organic solvents. Solid state 13C and proton NMR techniques, along with electron microscopy, are utilized in an exploratory study of
Variable temperature high resolution far infrared absorption measurements were carried out for single walled carbon nanotubes samples with different diameter distributions. At a temperature where kBT is significantly lower than the phonon energy, the broad
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general
Paul A. O'Connell, Greg B. McKenna, Edwin Chan, Christopher Stafford
Recently Chan et al. published a paper describing a method to use the wrinkling of a thin elastic film on which is adhered a thin polymer film to extract the viscoelastic properties of the polymer. Results were presented for the rubbery plateau modulus and
Carl G. Simon Jr., Kaushik Chatterjee, Laurence C. Chow, Limin Sun, Marian F. Young
There is a need to improve rapid methods for screening cell-biomaterial interactions. Current methods employ a flat 2D format even though 3D scaffolds are more representative of the tissue environment in vivo and cells are responsive to topological
Edwin P. Chan, Santanu S. Kundu, Qinhuang Lin, Christopher M. Stafford
The viscoelastic properties of polymer thin films can have a significant impact on the performance in many small-scale devices. In this work, we use thermal wrinkling, which is a phenomenon based on a thermally-initiated instability, to measure
Structural properties of polymeric scaffolds for bone tissue engineering play key role in directing osteogenesis. These properties depend on the chemical nature and the fabrication process of biomaterial. There are many protocols for fabricating scaffolds
Rahul P. Trivedi, Kristine A. Bertness, Ivan I. Smalyukh
We develop an integrated system of holographic optical trapping and multimodal nonlinear microscopy and perform simultaneous three-dimensional optical manipulation and non-invasive structural imaging of composite soft-matter systems. We combine different