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Chemistry

Chemical thermodynamics & chemical properties

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Displaying 76 - 100 of 523

Reference Materials for Phase Equilibrium Studies. 1. Liquid-Liquid Equilibria (IUPAC Technical Report)

July 8, 2021
Author(s)
Ala Bazyleva, William E. Acree, Jr., Robert D. Chirico, Vladimir Diky, Glenn T. Hefter, Johan Jacquemin, Joe W. Magee, John P. O'Connell, James D. Olson, Ilya Polishuk, Kurt Schmidt, John M. Shaw, J. P. M. Trusler, Ronald D. Weir
This article is the first of three projected IUPAC Technical Reports resulting from IUPAC Project 2011-037-2-100 (Reference Materials for Phase Equilibrium Studies). The goal of that project was to select reference systems with critically evaluated

Good reporting practice for thermophysical and thermochemical property measurements (IUPAC Technical Report)

April 16, 2021
Author(s)
Ala Bazyleva, Jens Abildskov, Andre Anderko, Olivier Baudouin, Yury Chernyak, Jean-Charles de Hemptinne, Vladimir Diky, Ralf Dohrn, J. R. Elliott, Johan Jacquemin, Jean-Noel Jaubert, Kevin Joback, Ursula Kattner, Georgios Kontogeorgis, Herbert Loria, Paul M. Mathias, John O'Connell, Wolffram Schroer, G. J. Smith, Ana Soto, Shu Wang, Ronald D. Weir
Scientific projects frequently involve measurements of thermophysical, thermochemical, and other related properties of chemical compounds and materials. These measured property data have significant potential value for the scientific community, but

Selective Filling of n-Hexane in a Tight Nanopore

January 12, 2021
Author(s)
Jeffrey Fagan, Haoran Qu, Archith Rayabharam, Narayana Aluru, Xiaojian Wu, Peng Wang, Yunfeng Li, YuHuang Wang
Molecular sieving may occur when two similarly sized molecules compete for a nanopore. This size-selectivity generally favors the adsorption of molecules with smaller kinetic diameter into the pore while excluding larger ones. In nearly all known examples

Entropic-based separation of diastereomers. Size-exclusion chromatography with on-line viscometry and refractometry detection for analysis of blends of mannose and galactose methyl-alpha-pyranosides at "ideal" size-exclusion conditions

January 11, 2021
Author(s)
Andre M. Striegel, Steven Trainoff
TThe separation of carbohydrate diastereomers by an ideal size-exclusion mechanism, i.e., in the absence of enthalpic contributions to the separation, can be considered one of the grand challenges in chromatography: Can a difference in the location of a

Study of the Reactions of OH with HCl, HBr, and HI between 298 K and 460 K.

November 24, 2020
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Igor Larin
The reactions between OH radicals and hydrogen halides (HCl, HBr, HI) have been studied between 298 K to 460 K by using a discharge flow – electron paramagnetic resonance technique. The rate constants at room temperature were found to be kHCl(298 K) = (7.9

Rapid Vapor-Collection Method for Vapor Pressure Measurements of Low-Volatility Compounds

November 24, 2020
Author(s)
Jason A. Widegren, Tara Lovestead, Megan Harries, Cheryle Beuning, Bridger L. Johnston
Dynamic vapor microextraction (DVME) is a new method that enables rapid vapor pressure measurements on large molecules with state-of-the-art measurement uncertainty for vapor pressures near 1 Pa. Four key features of DVME that allow for the rapid

New refrigerants and system configurations for vapor compression refrigeration

November 13, 2020
Author(s)
Mark O. McLinden, Christopher J. Seeton, Andy Pearson
The high global warming potential (GWP) of current refrigerants in cooling equipment based on the vapor-compression cycle has triggered a major effort to find and implement more environmentally benign alternatives. Here, we review the basics of the vapor

Unphysical critical curves of binary mixtures predicted with GERG models

October 19, 2020
Author(s)
Ian H. Bell, Ulrich K. Deiters
When applied to asymmetric binary mixtures (e.g., methane + pentane or heavier alkanes, hydrogen-containing mixtures), the GERG equation of state (GERG-2004 or GERG-2008) predicts critical curves with physically unreasonable temperature maxima above the
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