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Search Publications by: Daniel A Fischer (Fed)

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Displaying 201 - 225 of 230

Formation of SEI on Cycled Lithium-Ion Battery Cathodes: Soft X-ray Absorption Study

January 1, 2002
Author(s)
Mahalingam Balasubramanian, H S. Lee, X Sun, Xiao-Qing Yang, A R. Moodenbaugh, James McBreen, Daniel A. Fischer, Ziwen Fu
The formation of a solid electrolyte interface (SEI) on LiNi 0.85Co 0.15O 2 cathodes from lithium-ion cells cycled at 40EC and 70EC was observed and characterized using soft x-ray absorption spectroscopy (XAS). XAS measurements were made in the energy

Polymer Chain Relaxation: Surface Outpaces Bulk

July 1, 2001
Author(s)
William E. Wallace, Daniel A. Fischer, K Efimenko, Wen-Li Wu, Jan Genzer
In this work we show how carbon near-edge X-ray absorption fine structure (NEXAFS) can be applied to detect both surface and bulk segmental relaxation in uniaxially deformed polystyrene samples. We demonstrate that by simultaneously monitoring the partial

Abstracts for the MSEL Assessment Panel, March 2001

January 26, 2001
Author(s)
Leslie E. Smith, Alamgir Karim, Leonid A. Bendersky, C Lu, J J. Scott, Ichiro Takeuchi, Kathleen M. Flynn, Vinod K. Tewary, Davor Balzar, G A. Alers, Stephen E. Russek, Charles C. Han, Haonan Wang, William E. Wallace, Daniel A. Fischer, K Efimenko, Wen-Li Wu, Jan Genzer, Joseph C. Woicik, Thomas H. Gnaeupel-Herold, Henry J. Prask, Charles F. Majkrzak, Norman F. Berk, John G. Barker, Charles J. Glinka, Eric K. Lin, Ward L. Johnson, Paul R. Heyliger, David T. Read, R R. Keller, J Blendell, Grady S. White, Lin-Sien H. Lum, Eric J. Cockayne, Igor Levin, C E. Johnson, Maureen E. Williams, Gery R. Stafford, William J. Boettinger, Kil-Won Moon, Daniel Josell, Daniel Wheeler, Thomas P. Moffat, W H. Huber, Lee J. Richter, Clayton S. Yang, Robert D. Shull, R A. Fry, Robert D. McMichael, William F. Egelhoff Jr., Ursula R. Kattner, James A. Warren, Jonathan E. Guyer, Steven P. Mates, Stephen D. Ridder, Frank S. Biancaniello, D Basak, Jon C. Geist, Kalman D. Migler
Abstracts relating to research and development in the NIST Materials Science and Engineering Laboratory (MSEL) are presented for a poster session to be presented to the 2001 MSEL Assessment Panel.

Combined 63,65 Cu NQR and NMR Study of Y 1-x Ca x Ba 2 Cu 3 O y

November 1, 2000
Author(s)
D M. Potrepka, J. I. Budnick, A R. Moodenbaugh, Daniel A. Fischer, W A. Hines
Zero-field 63,65Cu nuclear quadrupole resonance (NQR) and nuclear magnetic resonance (NMR) spectra were obtained at 1.3 K for powdered samples of Y 1-xCa xBa 2Cu 3O y with 0 less than or equal to} x less than or equal to} 0.20. The results for the

The Effect of Changing Molecular End Groups on Surface Properties: Synthesis and Characterization of Poly (Styrene-b-Semifluorinated Isoprene) Block Copolymers With -CF 2 H End Groups

October 1, 2000
Author(s)
T Hayakawa, J G. Wang, M Xiang, X Li, M Ueda, Christopher K. Ober, Jan Genzer, E Sivaniah, E J. Kramer, Daniel A. Fischer
Poly(styrene-b-semifluorinated isoprene) block copolymers with -CF 2H terminated side groups were synthesized by the esterification reaction of a poly(styrene-b-hydroxylated 1,2-/3,4-isoprene) block copolymer with semifluorinated acid chlorides. Two

Molecular Orientation of Single and Two-Armed Monodendron Semifluorinated Chains on Soft and Hard Surfaces Studied Using NEXAFS

August 1, 2000
Author(s)
Jan Genzer, E Sivaniah, E K. Kramer, J G. Wang, M Xiang, K Char, Christopher K. Ober, Robert A. Bubeck, Daniel A. Fischer, M Graupe, R Colorado, O E. Shmakova, T R. Lee
Near-edge absorption fine structure (NEXAFS) measurements are used to probe the molecular orientation of semifluorinated (SF) mesogens, -(CH 2)x(CF 2)yF, which are attached to I) the isoprene backbone of polyisoprene or a styrene-isoprene diblock copolymer

Multilevel Structure of Reinforcing Silica and Carbon

June 1, 2000
Author(s)
D W. Schaefer, T Rieker, M M. Agamalian, J S. Lin, Daniel A. Fischer, S Sukumaran, C I. Chen, G Beaucage, C Herd, J Ivie
We study the structure of colloidal silica and carbon on length scales from 0.25 -1 7 using x-ray, neutron and light scattering. These materials consist of primary particles of the order of 100 , aggregated into micrometer-sized aggregates that in turn are

The Orientation of Semifluorinated Alkanes Attached to Polymers at the Surface of Polymer Films

March 1, 2000
Author(s)
Jan Genzer, E Sivaniah, E K. Kramer, J G. Wang, H Kerner, M Xiang, K Char, Christopher K. Ober, B M. DeKoven, Robert A. Bubeck, M K. Chaudhury, S Sambasivan, Daniel A. Fischer
The surface molecular orientation of a liquid crystalline (LC) layer made up a semi-fluorinated (SF) single side-groups [-CO-(CH 2) x-1-(CF 2) yF] (single SF groups) attached to polyisoprene homopolymer or the isoprene block of a styrene-isoprene diblock

Hole State Density of La 1-x Sr x CoO^d3-D} (0less then or equal to}xless then or equal to}0.5) Across the Insulator/Metal Phase Boundary

February 1, 2000
Author(s)
A R. Moodenbaugh, B Nielson, S Sambasivan, Daniel A. Fischer, T Friessnegg, S Aggarwal, R Ramesh, B Pfeffer
The oxygen K near edge x-ray absorption fine structure (NEXAFS) of polycrystalline and film La1-xSrxCoO3-d at room temperature was studied using fluorescence yield techniques. The bulk sensitive nature of fluorescence yield (relative to electron yield)

Temperature Dependence of Molecular Orientation on the Surfaces of Semi-Fluorinated Polymer Thin Films

February 1, 2000
Author(s)
Jan Genzer, E Sivaniah, E K. Kramer, J G. Wang, H Koerner, K Char, Christopher K. Ober, B M. DeKoven, Robert A. Bubeck, Daniel A. Fischer, S Sambasivan
Near-edge X-ray absorption fine structure is used to investigate the temperature dependence of molecular orientation of semi-fluorinated liquid crystalline (SF-LC) mesogens, which are attached to the modified isoprene backbone of i) a polyisoprene

Orientation of Surface Bound Proteins Studied by Near Edge X-Ray Absorption Fine Structure

January 25, 2000
Author(s)
L Gamble, J R. Long, P S. Stayton, Daniel A. Fischer, S Sambasivan, David G. Castner
The orientation of surface bound proteins may play an important role in the function and properties of materials to which they are adsorbed. Near edge absorption fine structure (NEXAFS) is a technique which allows the user to determine the presence of

In Situ Characterization of Catalytic Propylene Oxidation on the Pt (111) Surface

January 17, 2000
Author(s)
A M. Gabelnick, A T. Capitano, D J. Burnett, Daniel A. Fischer, J L. Gland
The catalytic oxidation of propylene with both propylene and oxygen in the gas phase has been characterized on the Pt(111) surface. In situ soft x-ray kinetic and spectroscopic measurements using fluorescence detection have been used to characterize this

Effects of Annealing on UHMWPE Molecular Orientation

January 1, 2000
Author(s)
S Sambasvian, Daniel A. Fischer, M C. Shen, John A. Tesk, Stephen M. Hsu
Ultra-high molecular weight polyethylene (UHMWPE) is the dominant material used in artificial joints due to its outstanding wear resistance. At the same time, UHMWPE wear debris has been found to contribute to the loosening of the im-plants. As life
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