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Matthew R. Hammond, Regis J. Kline, Andrew A. Herzing, Lee J. Richter, David Germack, Hyun W. Ro, Christopher L. Soles, Daniel A. Fischer, Tao Xu, Luping Yu, Michael F. Toney, Dean M. DeLongchamp
We report quantitative measurements of ordering, molecular orientation, and nanoscale morphology in the active layer of bulk heterojunction organic photovoltaic cells based on a thieno[3,4-b]thiophene-alt-benzodithiophene copolymer (PTB7), which has been
The analysis of complex fluids such as fuels poses significant challenges arising primarily from the multiplicity of components, the different properties of the components (polarity, polarizability, etc) and matrix properties (such as dirty samples)
Panagiotis Keivanidis, Frederic Laquai, Joseph W. Robertson, Baluschev Stanislav, Josemon Jacob, Klaus Mullen, Gerhard Wegner
The mechanism of triplet-triplet annihilation (TTA) induced up-converted delayed luminescence is studied in two different binary organic systems consisting of platinum(II) octaethyl porphyrin mixed with either poly(fluorene) (PF26) or ladder-type
Marc J. Assael, John-Alexander Assael, Marcia L. Huber, Richard A. Perkins, Yasayuki Takata
The paper contains new, representative equations for the thermal conductivity of normal and parahydrogen. The equations are based in part upon a body of experimental data that has been critically assessed for internal consistency and for agreement with
Joseph T. Hodges, David A. Long, Daniel K. Havey, S. S. Yu, M Okumura, Charles E. Miller
Frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) was employed to measure over 100 transitions in the R-branch of the b1Σg+←X3Σg-(0,0) band for the rare O2 isotopologues. The use of 17O- and 18O-enriched mixtures allowed for line positions to be
Nanostructured materials for hydrogen storage with a composition of Mg85Ni15-xMx (M=Y or La, x=0 or 5) are formed by devitrification of amorphous and amorphous-nanocrystalline precursors produced by melt-spinning. All three compositions exhibit a maximum
Behrang H. Hamadani, Nadine E. Gergel-Hackett, Paul M. Haney, Nikolai B. Zhitenev
We have studied the local charge transport properties of organic bulk heterojunction solar cells based on the blends of poly(3-hexylthiophene) (P3HT) and phenyl-C61-butyric acid methyl ester (PCBM) with a photoconductive atomic force microscope (PCAFM). We
Joseph T. Hodges, A. Cygan, Piotr Maslowski, Katarzyna E. Bielska, S. Wojtewicz, J. Domyslawska, Hisashi Abe, R.S. Trawinski, R. Ciurylo
We describe a high sensitivity and high spectral resolution laser absorption spectrometer based upon the frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) technique. We used the Pound-Drever-Hall (PDH) method to lock the probe laser to the high
Matthew T. Boyd, S. A. Klein, Douglas T. Reindl, Brian P. Dougherty
The Five-Parameter Model is an electrical performance model for photovoltaic solar cells that predicts the voltage and current output by representing the cells as an equivalent electrical circuit with radiation and temperature dependent components. An
New experimental data on the thermal conductivity of the methyl esters methyl oleate and methyl linoleate in the liquid phase are reported that allow the development of correlations. These new experimental data, covering a temperature range of 302 K to 509
The production capacity of corn ethanol as a transportation fuel is experiencing rapid growth in the United States. The demand is driven by increased prices of gasoline, government mandates, incentives, desire for cleaner fuels, and the need to achieve
Biodiesel fuel is an alternative fuel that can be derived from a number of renewable feedstocks including plant and vegetable oils, algae, animal fats, waste oils, etc. The fatty acid methyl ester (FAME) profile, and thus the resultant properties, of the
Daniel S. Hussey, David L. Jacobson, Jason B. Siegel, C. D. Stefan, Xinfan Lin, David Gorsich
This paper shows how neutron radiography can be used for in situ quantification of the lithium concentration across battery electrodes, a critical physical system state. The change in lithium concentration between the charged and discharged states of the
Bret Windom, Tara Lovestead, Mark Mascal, Edward Nikitin, Thomas J. Bruno
Diminishing petroleum reserves, the potential of supply disruptions, price volatility, as well as environmental considerations resulting from polluting emissions, have led to development of alternative liquid fuels and fuel additives produced from
In recent years, civilian and military users of aviation kerosene have been interested in expanding the scope of fuel feed stocks to include non-petroleum sources. The most well known examples of such alternative sources of fuel are the Fisher-Tropsch
Pratik Dholabhai, Shahriar Anwar, James B. Adams, Peter A. Crozier, Renu Sharma
Abstract We present a kinetic lattice Monte Carlo model for investigating the oxygen vacancy diffusion in praseodymium-doped ceria. The current approach uses a database of activation energies for oxygen vacancy migration, calculated using first-principles
Pratik Dholabhai, James B. Adams, Peter A. Crozier, Renu Sharma
Oxygen vacancy formation and migration in ceria (CeO2) is central to its performance as an ionic conductor. Ceria doped with suitable aliovalent dopants has enhanced oxygen ion conductivity - higher than that of yttria stabilized zirconia (YSZ), the most
Marcia L. Huber, Thomas J. Bruno, Robert D. Chirico, Vladimir Diky, Andrei F. Kazakov, Eric W. Lemmon, Chris D. Muzny, Michael D. Frenkel
The NIST ThermoData Engine (TDE) is a large electronic database containing experimental data with detailed descriptions of relevant metadata and uncertainties that incorporates expert- system software to automatically generate dynamically evaluated data
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general
David L. Jacobson, Richard Fu, Takeshi Shiomi, Ugur Pasaogullari, Joshua Preston, Shinichi Miyazaki, Yuichiro Tabuchi, Daniel S. Hussey
A fundamental experimental and numerical study of the water transport across a perfluorosulfonic acid (PFSA) membrane under a temperature gradient is presented. The water transport phenomenon was experimentally investigated through water flux measurement
Akram Boukai, Paul M. Haney, Aaron Katzenmeyer, Gregg M. Gallatin, Albert A. Talin, Peidong Yang
A significant fraction of the cost of a planar p-n junction silicon solar cell stems from the silicon purification process.1 Eliminating the purification step would decrease the cost, yet also decrease the solar cell efficiency significantly. Here, we have
The distillation curve is the only practical measurement used to characterize the vapor/liquid equilibrium (volatility) of a complex mixture. In earlier work, we described an improved method and apparatus for distillation curve measurement at atmospheric
The purpose of this work was to determine vapor pressures for saturated biodiesel esters at the low-temperature end of their liquid range. A "concatenated" gas saturation apparatus capable of simultaneous measurements on 18 samples was used for
Kuldeep R. Prasad, William M. Pitts, Jiann C. Yang
The natural and forced mixing and dispersion of hydrogen released in an accidental manner in a partially enclosed compartment with vents at multiple heights is investigated using theoretical tools. The key to the analysis is determination of the position
Andrew A. Herzing, Lee J. Richter, Ian M. Anderson
The three-dimensional characterization of third generation photovoltaic device structures at the nanometer scale is essential to the development of efficient, reliable, and inexpensive solar cell technologies. Electron tomography is a powerful method for