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Chemistry

Analytical chemistry

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Displaying 1251 - 1275 of 2094

Sensitivity of coherent dual-comb spectroscopy

March 31, 2010
Author(s)
Nathan R. Newbury, Ian R. Coddington, William C. Swann
Coherent dual comb spectroscopy can provide high-resolution, high-accuracy measurements of a sample response in both magnitude and phase. We discuss the achievable signal-to-noise ratio (SNR) due to both additive white noise and multiplicative noise, and

Effect of N-Terminal Glutamic Acid and Glutamine on Fragmentation of Peptide Ions

March 27, 2010
Author(s)
Bhaskar Godugu, Pedatsur Neta, Yamil Simon, Stephen Stein
A prominent dissociation path for electrospray generated tryptic peptide ions is the dissociation of the peptide bond linking the second and third residues from the amino-terminus. The formation of the resulting b 2 and y n-2 fragments has been

Uncertainties in Electron Probe Microanalysis

March 12, 2010
Author(s)
Ryna B. Marinenko, Stefan D. Leigh
This tutorial discusses the importance of citing valid uncertainties when reporting analytical results and the need for a universally accepted approach for evaluating uncertainties. Today, the CIPM procedure has been accepted by numerous international

Classical Trajectories and RRKM Modeling of Collisional Excitation and Dissociation of Benzylammonium and tert Butyl Benzylammonium Ions in a Quadrupole-Hexapole-Quadrupole Tandem Mass Spectrometer

March 1, 2010
Author(s)
Vadim D. Knyazev, Stephen Stein
Collision-induced dissociation of the benzylammonium and the 4-tert butyl benzylammonium ions was studied experimentally in an electrospray ionization quadrupole-hexapole-quadrupole tandem mass spectrometer. Ion fragmentation efficiencies were determined

Fluorinated Copolymer Nanoparticles for Multimodal Imaging Applications

February 18, 2010
Author(s)
Mark M. Bailey, Christine M. Mahoney, Elodie Dempah, Jeffrey M. Davis, Matthew Becker, Supang Khondee, Eric J. Munson, Cory J. Berkland
Nanomaterials have emerged as valuable tools in biomedical imaging techniques, such as magnetic resonance imaging (MRI), fluorescence, positron emission tomography (PET), and others. Some have been designed to serve as multimodal imaging agents, combining

Development of a Candidate Reference Measurement Procedure for the Determination of 25-hydroxyvitamin D3 and 25-hydroxyvitamin D2 in Human Serum Using Isotope-Dilution Liquid Chromatography/Tandem Mass Spectrometry

February 5, 2010
Author(s)
Susan S. Tai, Mary Bedner, Karen W. Phinney
Vitamin D exists in two major forms, vitamin D3 and vitamin D2. Vitamin D helps the body absorb calcium and promote optimal growth. Both forms of vitamin D are metabolized to 25-hydroxyvitamin D in the body, and the levels of 25-hydroxyvitamin D3 (25-(OH

Microsensors in Dynamic Backgrounds: Toward Real-Time Breath Monitoring

January 15, 2010
Author(s)
Kurt D. Benkstein, Baranidharan Raman, Christopher B. Montgomery, C Martinez, Stephen Semancik
We evaluated MEMS microsensor array with chemi-resistive elements for use as a non-invasive clinical diagnostic tool to detect the presence or absence of trace amounts of disease biomarkers in simulated breath samples. The microsensor environment was

Symmetry and Fourier analysis of the ab-initio-determined torsional variation of structural and Hessian-related quantities for application to vibration-torsion-rotation interactions in CH3OH

January 11, 2010
Author(s)
Li-Hong Xu, Jon T. Hougen, Jonathan M. Fisher, Ronald M. Lees
The aim of the present paper is to investigate the use of quantum chemistry calculations to obtain the torsional dependence of various structural and vibrational-force-field-related quantities that could help in estimating the vibration-torsion-rotation

Architecture and Dynamics of C18 Bonded Interphases with Small Molecule Spacers

December 15, 2009
Author(s)
Lane C. Sander, Katrice A. Lippa, Catherine A. Rimmer, Maximilian Kuhnle, Volker Friebolin, Klaus Albert
The relationship between alkyl phase structure and chromatographic performance is investigated for a series of octadecyl (C18)- modified silica surfaces with defined spacing of the alkyl surface by a “pre-endcapping” technique. Stationary phases were

Nanoelectronic Fabrication with Flip Chip Lamination

December 15, 2009
Author(s)
Mariona Coll Bau, Curt A. Richter, Christina Hacker
Nanoelectronic fabrication with Flip chip lamination Mariona Coll, CA Richter, CA Hacker, Colloquium Catalan Institute of Nanoscience and Nanotechnology CIN2, Barcelona Spain, Dec 2009.
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