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Bioscience

Biomaterials

Search Publications

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  • Published Date
Displaying 501 - 525 of 1729

CONTINUOUS FLOW ENZYME-CATALYZED POLYMERIZATION IN A MICROREACTOR

March 25, 2011
Author(s)
Santanu S. Kundu, Atul S. Bhangale, William E. Wallace, Kathleen M. Flynn, Charles M. Guttman, Richard Gross, Kathryn L. Beers
Enzymes immobilized on solid supports are increasingly used for chemical transformation because the process is greener and sustainable. Here we use microreactors to study enzyme catalyzed ring opening polymerization of -caprolactone to polycaprolactone. A

Effect of interfaces and adhesion on the creep compliance of thin polymer coatings

February 13, 2011
Author(s)
Peter M. Johnson, John A. Howarter, Christopher Stafford
Thin film indentation experiments on viscoelastic materials allowed for the deconvolution of the bulk compliance from interfacial responses at the buried interface. This technique could discriminate both large changes in the interfacial strength due to

Manipulation of adhesion via sub-surface patterning

February 13, 2011
Author(s)
John A. Howarter, Peter M. Johnson, Jun Y. Chung, Christopher Stafford
The delamination characteristics of patterned and hierarchical interfaces are of great interest due to the advanced adhesion capabilities found with many biological surfaces. Using nature-inspired design principles, micro- and nanostrucutred surfaces have

OCT For Depth Detection of Buried Particles in Polymeric Materials

February 13, 2011
Author(s)
Robert C. Chang, Anant Agrawal, Peter M. Johnson, Christopher Stafford
In this work, we demonstrate a method to produce novel optical phantoms usable for the characterization of OCT axial resolution and contrast. By varying the diameter of the microspheres and the thickness of the polymer layers, different spatial frequencies

In situ Formation of Silver Nanoparticles in Photocrosslinking Polymers

February 2, 2011
Author(s)
Yajun Cheng, Diana N. Zeiger, John A. Howarter, Xinran Zhang, Nancy Lin, Joseph M. Antonucci, Sheng Lin-Gibson
Nanocomposites of difunctional methacrylate polymer/silver nanoparticles have been synthesized by coupling photoinitiated free radical polymerization with in situ silver ion reduction. A polymerizable methacrylate bearing a secondary amino function group

Controlled in situ Nanocavitation in Polymeric Materials

January 18, 2011
Author(s)
Yajun Cheng, Joseph M. Antonucci, Steven Hudson, Nancy Lin, Xinran Zhang, Sheng Lin-Gibson
A new strategy to produce polymer-inorganic composites with ultra low volume shrinkage has been developed. Small amount of cavitation agent, acetone dicarboxylic acid (ADCA), was introduced into acrylate-glass composites and decomposed in situ to carbon

Influence of substrate on crystallization in polythiophene/fullerene blends

January 13, 2011
Author(s)
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general

Comment on Viscoelastic properties of con ned polymer lms measured via thermal wrinkling by Edwin P. Chan, Kirt A. Page, Se Hyuk Im, Derek L. Patton, Rui Huang and Christopher M. Stafford, Soft Matter (Communications), 5, 4638 4641 (2009).

January 11, 2011
Author(s)
Paul A. O'Connell, Greg B. McKenna, Edwin Chan, Christopher Stafford
Recently Chan et al. published a paper describing a method to use the wrinkling of a thin elastic film on which is adhered a thin polymer film to extract the viscoelastic properties of the polymer. Results were presented for the rubbery plateau modulus and

Effects of Polymeric Nanogratings on Cell Orientation

December 30, 2010
Author(s)
Nancy J. Lin, Sheng Lin-Gibson, Jirun Sun, Yifu Ding
Surface topography is known to play a critical role in the biological response to materials, with surface features on the order of both microns and nanometers altering cell response, including morphology, adhesion, cytoskeletal orientation, and gene

3D Polymer Scaffold Arrays

December 5, 2010
Author(s)
Carl G. Simon Jr., Yanyin Yang, Shauna M. Dorsey, Murugan Ramalingam, Kaushik Chatterjee
We have developed a combinatorial platform for screening the effect polymer scaffold properties and composition on cell response. Traditional research involves preparing samples one at a time for characterization and testing. Combinatorial and high

Thickness dependence of the elastic modulus of tri (8-hydroxyquinolinato) aluminum (III)

November 2, 2010
Author(s)
Jessica M. Torres, Nathan Bakken, Christopher Stafford, Jian Li, Bryan D. Vogt
The intrinsic flexibility of organic molecules has been suggested to enable bendable electronics in comparison to their stiffer, inorganic counterparts. However, very little is known regarding the mechanical properties of these conjugated molecular glasses

Effect of 3D Hydrogel Scaffold Stiffness on Human Bone Marrow Stromal Cell Differentiation

November 1, 2010
Author(s)
Carl G. Simon Jr., Sapun Parekh, Marcus T. Cicerone, Sheng Lin-Gibson, Kaushik Chatterjee, Marian F. Young
There is growing recognition cells can sense and respond to the mechanical properties of tissue scaffolds and that these interactions are critical in optimizing scaffold design [1-4]. Previous studies in planar 2D culture format have shown that human bone

Cell Contact Guidance in Response to Nanopattern Shape and Height

October 18, 2010
Author(s)
Sheng Lin-Gibson, Jirun Sun, Nancy J. Lin, Jing N. Zhou, Hyun W. Ro, Christopher L. Soles, Marcus T. Cicerone, Yifu Ding
Understanding the correlation between cell contact guidance (CG) and nanoscale surface features is vital in designing advanced medical devices to manipulate cell behaviors. Nanoscale surface features that mimic extracellular matrix are critical

Microencapsulated POSS in Cellulose Using 1-Ethyl-3-Methylimidazolium Acetate

October 10, 2010
Author(s)
Douglas M. Fox, Mauro Zammarano, Jeffrey W. Gilman
Polyhedral oligomeric silsesquioxane (POSS) and cellulose were reacted in the ionic liquid, 1-ethyl-3-methylimidazolium acetate (EmiAc). Side reactions between the EmiAc and each reactant were prevalent, but use of water as the coagulating solvent produced

Stability and Surface Topography Evolution in Nanoimprinted Polymer Patterns under a Thermal Gradient

September 16, 2010
Author(s)
Christopher Soles, Yifu Ding, H. Jerry Qi, Kyle J. Alvine, Hyun W. Ro, Dae Up Ahn, Jack Douglas, Sheng Lin-Gibson
Nanostructures created in polymer films by nanoimprint lithography are subject to large stresses, both those from the imprinting processes as well as stresses arising from the intrinsic thermodynamic instabilities. These stresses can induce nanostructure
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