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Displaying 351 - 375 of 1733

Mechanical response of thermally annealed Nafion thin films

December 7, 2016
Author(s)
Bradley R. Frieberg, Kirt A. Page, Joshua R. Graybill, Marlon L. Walker, Gery R. Stafford, Christopher L. Soles
The proton exchange membranes (PEMs) in a hydrogen fuel cell experiences hundreds if not thousands of cycles between wet and dry conditions during their service life, which leads to swelling and shrinking of the membrane material. This can lead to

Scalable Manufacturing of Layer-by-Layer Membranes for Water Purification

December 1, 2016
Author(s)
Christopher M. Stafford
Water is critical to the health and security of our nation. And as our population expands and water scarcity becomes a reality, we as a people need to think creatively on how we safeguard access to clean water. The manufacturing of today’s state-of-the-art

Epoxy Composites Using Wood Pulp Components as Fillers

November 30, 2016
Author(s)
Douglas M. Fox, Noy Kaufman, Jeremiah W. Woodcock, Jeffrey W. Gilman, John R. Shields, Rick D. Davis, Szabolcs Matko, Mauro Zammarano, Chelsea S. Davis
The components of wood, especially lignin and cellulose, have great potential for improving the properties of polymer composites. In this chapter, we discuss some of the latest developments from our lab on incorporating wood based materials into epoxy

The influence of the aromatic character in the gas chromatography elution order: the case of polycyclic aromatic hydrocarbons

November 8, 2016
Author(s)
Jorge O. Ona Ruales, Walter B. Wilson, Federica Nalin, Lane C. Sander, Patricia Schubert, Stephen A. Wise
A link between the aromatic character of polycyclic aromatic hydrocarbons (PAHs) and gas chromatography (GC) elution order in columns with a polysiloxane backbone in the stationary phase is reported for the first time. The aromatic character was calculated

Film morphology evolution during solvent vapor annealing of highly efficient small molecule donor/acceptor blends

September 15, 2016
Author(s)
Sebastian Engmann, Hyun W. Ro, Andrew Herzing, Chad R. Snyder, Lee J. Richter, Paul Geraghty, David Jones
Solution-processable small molecule photovoltaics based on the novel molecular donor, benzodithiophene terthiophene rhodamine (BTR), recently have shown maximum power conversion efficiencies above 8% for active layer thicknesses up to 400 nm, using post

Giant surface conductivity enhancement in a carbon nanotube composite by ultraviolet light exposure

July 29, 2016
Author(s)
Christian J. Long, Nathan D. Orloff, Kevin A. Twedt, Thomas F. Lam, Luis Fernando Vargas Lara, Minhua Zhao, Bharath NMN Natarajan, Keana C. Scott, Eric Marksz, Tinh Nguyen, Jack F. Douglas, Jabez J. McClelland, Edward J. Garboczi, Jan Obrzut, James A. Liddle
Carbon nanotube composites are lightweight, multifunctional materials with readily adjustable mechanical and electrical properties—relevant to the aerospace, automotive, and sporting goods industries as high-performance building materials. Here, we combine

Ultraviolet/Ozone as a tool to control grafting density in surface-initiated controlled-radical polymerizations via ablation of bromine

July 21, 2016
Author(s)
Richard J. Sheridan, Sara V. Orski, Shinichiro Muramoto, Christopher M. Stafford, Kathryn L. Beers
We used an ultraviolet-ozone (UVO) cleaner to create substrates for atom-transfer radical polymerization (ATRP) with varying surface initiator coverage. We collected complementary time-of-flight secondary ion mass spectrometry (ToF-SIMS) and X-ray

Evolution of Dendrimer Conformational Structure with Generation Number

June 20, 2016
Author(s)
Beatriz A. Pazmino, Jack F. Douglas
We simulate the conformational structure of a coarse-grained model of dendrimer molecules in good solvent as a function of generation number G and find that they evolve through a substantially more complex structures than regular star polymer with

How to measure absolute P3HT crystallinity via 13C CPMAS NMR

April 20, 2016
Author(s)
Ryan C Nieuwendaal
We outline the details of acquiring quantitative 13C cross-polarization magic angle spinning (CPMAS) NMR spectra on the most ubiquitous polymer for organic electronics (OE) applications, poly(3-hexylthiophene) (P3HT), despite other groups’ claims that

Structural control of mixed ionic and electronic transport in conducting polymers

April 17, 2016
Author(s)
Jonathan Rivnay, Sahika Inal, Brian Collins, Michelle Sessolo, Eleni Stavrindou, Christopher Tassone, Dean DeLongchamp, George Malliaras
Poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate), PEDOT:PSS, has been utilized for over two decades as a stable, solution-processable conductor. While electrical properties have been the subject of intense materials investigation, recent

Super Stiff and Highly Transparent Multilayer Thin Films Prepared through Hydrogen-Bonding Layer- by-Layer Assembly of Graphene and Polymer

February 8, 2016
Author(s)
Fangming Xiang, Dorsa Parviz, Tara M. Givens, Ping Tzeng, Eric Davis, Christopher Stafford, Micah J. Green, Jaime C. Grunlan
Since its discovery in 2004, graphene has been intensely studied due to its high elastic modulus, thermal conductivity, electrical conductivity, and gas impermeability. Although it is possible to use small quantities of graphene sheets for fundamental

Morphological origins of polarization-induced scattering anisotropy from organic thin films

January 14, 2016
Author(s)
Eliot Gann, Brian A. Collins, Maolong Tang, John R. Tumbleston, Subhrangsu Mukherjee, Harald W. Ade
Anisotropic scattering patterns have been observed from organic thin films that are isotropic on the scale of the probe in polarized resonant X-ray scattering experiments. The symmetry is broken by local correlations between molecular orientation and

ASTM Workshop on Standards & Measurements for Tissue Engineering Scaffolds

January 1, 2016
Author(s)
Carl G. Simon Jr., John Test, Michael Yaszemski, Reto Luginbuehl, Anthony Ratcliffe, Paul Tomlins
A “Workshop on Standards & Measurements for Tissue Engineering Scaffolds” was held on May 21, 2013 and was sponsored by the American Society of Testing and Materials International (ASTM International) in Indianapolis, IN. The purpose of the workshop was to

The Occurrence of Repeated Fiber Breaks in Microcomposites

November 10, 2015
Author(s)
Gale A. Holmes, Edward D. McCarthy, Nathanael A. Heckert, Stefan D. Leigh, Jae Hyun Kim, Jeffrey W. Gilman
The mechanical integrity of a structural composite is strongly affected by the strength and toughness of the fiber–matrix interface/interphase (Norwood, 1994), with interfacial shear strength (IFSS) considered the best quantifying metric. IFSS outputs are
Displaying 351 - 375 of 1733
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