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The Fano-Anderson model for a discrete state embedded within a continuum is revisited within the context of excitation and decay processes which lead to some manifestations of Fano lineshape profiles. The phenomenon of resonance tunneling between an STM
We have performed an evaluation of calculated and measured electron inelastic mean free paths (IMFPs) for selected materials and for electron energies between 50 eV and 10,000 eV. This evaluation is based on IMFPs calculated from experimental optical data
This Paper describes the NIST development of standards and procedures for the calibration of the Raman Spectral Intensity. The work is based on the NIST proposal of the use of luminescent glass standards for the transfer of the white light calibration to
Vytautas Reipa, S L. Yeh, H G. Monbouquette, V L. Vilker
Decanethiol was coadsorbed with tetradecylmethyl viologen (C 14MV; 1-Methyl-1 -tetradecyl-4,4 -bipyridinium chloride) on gold electrodes in order to improve stability of C 14MV as an electrochemical mediator for coupling to nitrate reductase enzymes
Fahriye N. Sari, Marcia J. Holden, M P. Mayhew, V L. Vilker, B Coxon
The backbone dynamics of uniformly 15N-labeled reduced and oxidized putidaredoxin (Pdx) have been studied by 2D 15N NMR relaxation measurements. 15N T 1 and T 2 values and 1H- 15N NOE s have been measured for the diamagnetic region of the protein. These
Terrence J. Jach, Yanbao Zhang, R. Colella, M. De Boissieu, M. Boudard, A. I. Goldman, T Lograsso, D W. Delaney, S. Kycia
We have observed dynamical diffraction in the [024024] and[046046] reflections of the icosahedral quasicrystal A1PdMn in the back-reflection geometry (θ B = 90 ). The x-ray fluorescence from the Al and Pd atoms exhibits strong standing wave behavior
The theory and implementation of quantitative gas phase absorption measurements based on cavity-ringdown spectroscopy with pulsed lasers is discussed. The response of ringdown cavities is modeled using an eigenmode description of the electromagnetic field
Lee J. Richter, T Petralli-Mallow, John C. Stephenson
We present a novel procedure for vibrationally-resolved sum-frequency generation (SFG) in which a broad-bandwidth IR pulse is mixed with a narrow-bandwidth visible pulse. The resultant SFG spectrum is dispersed with a spectrograph and detected in parallel
Fahriye N. Sari, Marcia J. Holden, M P. Mayhew, V L. Vilker, B Coxon
Putidaredoxin is a di-iron protein whose paramagnetic region is not well characterized by 1H detected NMR. We have studied the structure of this region in greater detail by directly observed 15N NMR of oxidized and reduced putidaredoxin preparations in
The major NIST atomic spectroscopy data tables and the new NIST atomic spectra database (ASD) on the Internet are briefly reviewed. The need for critical assessments of atomic transition probabilities data is discussed, and the still unsatisfactory data