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This is the first in a series of articles which present a new framework for computing the uncertainty in electron excited X-ray microanalysis measurements. This article will discuss the framework and apply it to a handful of simple but useful sub
Cassandra M. Reese, Wei Guo, Brittany J. Thompson, Phillip K. Logan, Christopher Stafford, Derek L. Patton
We present a quantitative method of measuring the compressive strain of wrinkled polymer films and coatings with knowledge of the "skin" thickness, wrinkle wavelength, and wrinkle amplitude. The derived analytical expression is validated with a well
Kunal Kupwade-Patil, Ali Bumajdad, Terrence J. Udovic, Kenneth Littrell, Oral Buyukozturk
This work investigates the effect of early-age hydration on microstructural evolution of cement paste with local volcanic ash using neutron-based beamline techniques. Early-age hydration dynamics of Portland cement paste with volcanic ash was examined via
Thien Tran, Xiaoyi Chen, Sarthak Doshi, Christopher Stafford, Haiqing Lin
Conventional approaches to mitigate fouling of membrane surfaces impart hydrophilicity to the membrane surface, which increases the water of hydration and fluidity near the surface. By contrast, we demonstrate here that tuning the membrane surface energy
Ryan F. Need, Seul-Ki Bac, Xinyu Liu, Sanghoon Lee, Brian Kirby, Margaret Dobrowolska, Jacek Kossut, Jacek K. Furdyna
Controlling changes in magnetic anisotropy across epitaxial film interfaces is an important prerequisite for many spintronic devices. For the canonical dilute magnetic semiconductor GaMnAs, magnetic anisotropy is highly tunable through strain and doping
Dean Hobbis, Hsin Wang, Joshua Martin, George S. Nolas
Temperature-dependent thermal properties of phase-pure polycrystalline ternary chalcogenides Cu4Bi4S9 and Cu4Bi4Se9 are reported. The large unit cell and complex structure results in very low thermal conductivity values ( 0.7 W/m-K at room temperature) for
Carl Simon, Becky Robinson-Zeigler, Michael Yaszemski, Jayesh Doshi, Michael Francis, Sherif Soliman, Lexi Garcia
As the tissue engineering and regenerative medicine (TERM) industry transitions from small-scale development of prototypes for research and design purposes to large-scale production for the clinic there is a need to ensure that products are properly
Producing ultraviolet-light-shielding (UV-shielding) materials via green chemistry has been attracting researchers' attention. Herein, a polymer composite produced by hybridizing instant coffee with poly (vinyl alcohol) (PVA) is reported. It has been shown
Yassine Quessab, Jun-Wen Xu, Chung Ting Ma, W. Zhou, Grant A. Riley, Justin Shaw, Hans Nembach, S. J. Poon, Andrew D. Kent
Skyrmions can be stabilized in magnetic systems with broken inversion symmetry and chiral interactions, such as Dzyaloshinskii-Moriya interactions (DMI). Further, compensation of magnetic moments in ferrimagnetic materials can significantly reduce magnetic
Xin Zhang, Rui-Biao Lin, Jing Wang, Bin Wang, Bin Liang, Taner N. Yildirim, Jian Zhang, Wei Zhou, Banglin Chen
Metal-organic frameworks are promising materials for onboard hydrogen storage thanks to the tunable pore size, pore volume, and pore geometry. In consideration of pore structures, the correlation between the pore volume and hydrogen storage capacity is
Jack F. Douglas, Andrea Giuntoli, Francesco Puosi, Dino Leporini, Francis W. Starr
We examine the influence of steady shear on structural relaxation in a model coarse-grained unentagled polymer melt over a wide range of temperature and shear rates. Shear is found to progressively suppress the α-relaxation process observed in the
M. Waschk, A. Sarkar, J. Barthel, J. Voigt, S. Schroder, P. Zakalek, M. Schmitz, Brian Kirby, S. Putter, J. Schubert, T. Bruckel
The ability to create atomically perfect, epitaxial heterostructures of correlated complex perovskite oxides using state-of-art thin film deposition techniques has generated new physical phenomena at engineered interfaces. Here we report on the impact of
Bai-Qiao Song, Qing-Yuan Yang, Shi-Qiang Wang, Matthias Vandichel, Amrit Kumar, Clare Crowley, Naveen Kumar, Cheng-Hua Deng, Victoria GasconPerez, Matteo Lusi, Hui Wu, Wei Zhou, Michael J. Zaworotko
Closed-to-open structural transformations in flexible coordination networks are of interest for their potential utility in gas storage and separation. Herein, we report the first example of a flexible SiF 6 2--pillared square grid material, [Cu(SiF 6)(L) 2
Storing hydrogen efficiently in condensed material under mild conditions is a key technique challenge. Here, we developed a new family of hydrogen storage material spanning across the domain of inorganic and organic hydrides, namely metalorganic hydrides
We perform a systematic study of thermal resistance/conductance of tilt grain boundaries (GBs) in Si using classical molecular dynamics. The GBs studied are naturally divided into three groups according to the structural units forming the GB core. We find
Yingxiang Ye, Rui-Biao Lin, Hui Cui, Ali Alsalme, Wei Zhou, Taner N. Yildirim, Zhangjing Zhang, Shengchang Xiang, Banglin Chen
We reported a microporous MOF FJU-101 with open naphthalene diimide functional groups for room temperature (RT) high methane storage. At RT and 65 bar, the total volumetric CH 4 storage capacity of 212 cm -3 in FJU-101a is significantly higher than the
Many measurements have indicated that thin polymer films in their glass state exhibit an interfacial layer of enhanced mobility that grows in thickness upon heating, as found also in crystalline materials approaching their melting temperature Tm, while
Amy E. Engelbrecht-Wiggans, Ajay Krishnamurthy, Lucas H. Kaplan, Amanda L. Forster, Thanh N. Hoang, Viviana Bentley
Traditionally, soft body armor has been made from materials such as poly(p-phenylene terephthalamide) (PPTA) and ultra-high molar mass polyethylene (UHMMPE). However, to diversify the fiber choices in the United States body armor market, copolymer fibers
For glass-forming polymers, direct quantitative comparison of atomistically detailed molecular dynamics simulations with thermomechanical experiments is hindered by the vast mismatch between the accessible timescales. Recently, we demonstrated the
Matthew R. Rosenberger, Hsun-Jen Chuang, Vladimir Oleshko, Madeleine Phillips, Kathleen M. McCreary, Saujan V. Sivaram, C. Stephen Hellberg, Berend T. Jonker
Van der Waals layered materials, such as the transition metal dichalcogenides (TMDs), are an exciting class of materials with weak interlayer bonding which enables one to create so-called van der Waals heterostructures (vdWH). One promising attribute of
Ann C. Chiaramonti Debay, Luis Miaja Avila, Benjamin W. Caplins, Paul T. Blanchard, Norman A. Sanford, Brian Gorman, David R. Diercks
This paper reports construction of an extreme ultraviolet (EUV) radiation-triggered atom probe tomograph and describes the results from initial experiments on amorphous SiO2. Femtosecond-pulsed coherent EUV radiation of 29.6 nm wavelength (41.85 eV photon
Sonal Bhadauriya, Jianan Zhang, Jaejun Lee, Michael R. Bockstaller, Alamgir Karim, Richard J. Sheridan, Christopher Stafford
We combine in-situ heated atomic force microscopy (AFM) with automated line-by-line spectral analysis to quantify the relaxation or decay of nanopatterned polymer films at temperatures above the glass transition. This approach enables assessment of pattern
Sindhu Seethamraju, Jan Obrzut, Jack F. Douglas, Jeremiah Woodcock, Jeffrey W. Gilman
We investigated a chemically modified Rhodamine B dye as a sensor of local water content in dye-modified epoxy resins, where these measurements were combined with dielectric measurements to estimate the dye-water association ratio in the material. In
Joel M. Sarapas, Tyler B. Martin, Alexandros Chremos, Jack F. Douglas, Kathryn L. Beers
Many naturally occurring polyelectrolytes of importance in diverse biological functions have the form of bottlebrush polymers, and there is correspondingly widespread interest in the synthesis and characterization of bottlebrush polymers to capitalize on
Solid state refrigeration based on caloric effect has been regarded as an attractive alternative to conventional gas compression technique. Boosting the caloric effect of a system to its optimum is a long-term pursuit. Here, we report enhanced