Skip to main content
U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

Search Publications by:

Search Title, Abstract, Conference, Citation, Keyword or Author
Displaying 1 - 25 of 134

Imidazolium Modified Clay Based ABS Nanocomposites: A Comparison Between Melt-Blending and Solution Sonication Processes

October 12, 2021
Author(s)
M Modesti, S Besco, A Lorenzetti, Mauro Zammarano, V Causin, C Marega, Jeffrey W. Gilman, D M. Fox, Paul C. Trulove, Hugh C. De Long, P H. Maupin
Acrylonitrile-butadiene-styrene (ABS) nanocomposites containing imidazolium-modified montmorillonite have been prepared by melt-blending and solution-sonication in order to study the effects of processing on the morphology and properties of the polymer

Layered Double Hydroxides as Cation Exchange Materials

October 12, 2021
Author(s)
Paul Braterman, Nandika A. D'Souza, Jeffrey W. Gilman, Mickey C. Richardson, Laxmi K. Sahu, Mauro Zammarano
Layered double hydroxides (LDH) are a class of materials formally related to brucite-like hydroxides by the incorporation of higher valent cations, such as Al(III). The layer charge is neutralized by the insertion of any of a large range of exchangeable

Optical Probes for Monitoring Intercalation and Exfoliation in Melt Processed Polymer Nanocomposites

October 12, 2021
Author(s)
P H. Maupin, Jeffrey W. Gilman, Richard H. Harris Jr., S Bellayer, Anthony J. Bur, S C. Roth, A B. Morgan, J R. Harris, M Murariu
Laser induced fluorescence spectroscopy of the optical probe Nile Blue A in polymer clay nanocomposites is described. Concentration quenching of fluorescence dominates probe behavior until the clay platelets are physically separated by polymer

Synthesis and Characterization of Siloxy-Containing Imidazolium Ionic Liquids

October 12, 2021
Author(s)
Paul A. Wheeler, Jeffrey W. Gilman, L J. Mathias
A novel family of siloxy-containing imidazolium ionic liquids was synthesized and their thermal and decomposition properties studied. Three of the four compounds exhibited an unexpectedly low decomposition temperature of ca. 200 C that appears to be due to

Synthesis of Imidazolium Salts and Their Application in Epoxy Montmorillonite Nanocomposites

October 12, 2021
Author(s)
Joseph Langat, S Bellayer, P Hudrlik, A Hudrlik, P H. Maupin, Jeffrey W. Gilman, D T. Raghavan
Considerable research has been conducted in improving the performance characteristics of nanocomposites, however, relatively few attempts have been made to address the thermal stability of nanocomposite. An attempt is being made to improve the thermal

Flourescently labeled cellulose nanofibers for environmental health and safety studies

April 9, 2021
Author(s)
Jeremiah Woodcock, Ilabahen A. Patel, Ryan Beams, Stephan J. Stranick, Jeffrey W. Gilman, Douglas M. Fox, Marina Mulenos, Christie Sayes, Maryam Salari, Deloid Glen, Philip Demokritou, Bryan Harper, Harper Stacey, Ong Kimberly, Jo Anne Shatkin
An optimal methodology for locating and tracking cellulose nanofibers (CNF) in vitro and in vivo is crucial to evaluate the environmental health and safety properties of these nanomaterials. Here, we report the use of a new boron-dipyrromethene (BODIPY)

Comparative study of multiwall carbon nanotube nanocomposites by Raman, SEM, and XPS measurement techniques

March 3, 2021
Author(s)
Yanmei Piao, Vipin Tondare, Chelsea S. Davis, Justin Gorham, Elijah Petersen, Jeffrey W. Gilman, Keana Scott, Andras Vladar, Angela R. Hight Walker
Substantial ongoing research efforts are investigating the production of novel composite material enhanced by the incorporation of nanomaterial fillers such as multiwall carbon nanotubes (MWCNTs). While the addition of MWCNTs have been shown to improve the

Damage sensing using a mechanophore crosslinked epoxy resin in single-fiber composites

May 26, 2020
Author(s)
Jeremiah W. Woodcock, Richard J. Sheridan, Ryan Beams, Stephan J. Stranick, William F. Mitchell, Jeffrey W. Gilman, Gale A. Holmes, Catherine L. Brinson, Vamshi Gudapati, hartman David, Amol Vaidya
Natural and man-made composite materials must be tough, durable and damage tolerant1,2. For man-made composites to rival, or exceed, the dynamic, multifunctional performance of natural materials new information about the fundamental mechanisms responsible

Interfaces In Aromatic Polymer-Nanocellulose Composites

March 22, 2019
Author(s)
Douglas M. Fox, Jeremiah Woodcock, Sindhu Seethamraju, Jeffrey W. Gilman, Katrina Wakeman, Tess Ravick
Formation of well dispersed cellulose – polymer composites is a challenge. This is magnified when preparing composites using nanoscale materials, where the bulk properties are dominated by interfacial properties. In this chapter, synthetic and processing

Hierarchical Cellulose Nanocrystal Blends for Bioinspired Damage Tolerant Photonic Films

May 4, 2018
Author(s)
Bharath NMN Natarajan, Ajay Krishnamurthy, Caglar Dogu Emiroglu, Amanda L. Forster, E. J. Foster, Christoph Weder, Douglas M. Fox, Jan Obrzut, Jeffrey W. Gilman
Attempts to emulate strong and tough natural composites using wood cellulose nanocrystals (CNCs) fall short in mechanical performance due to the low shear transfer ability of CNC interfaces in their helicoidal ensembles. This shortcoming is ascribed to the

Road Mapping Workshop Report on Overcoming Barriers to Adoption of Composites in Sustainable Infrastructure

December 20, 2017
Author(s)
Richard J. Sheridan, Jeffrey W. Gilman, John Busel, David Hartman, Gale A. Holmes, Daniel Coughlin, Paul Kelley, Dustin Troutman, Jim Gutierrez, Charles Bakis, Robert Moser, Ellen Lackey, James R. Fekete, Stephanie S. Watson, Jae Hyun Kim, Aaron M. Forster, Ajay Krishnamurthy, Bharath NMN Natarajan, William O'Donnell
The February 2017 “Road Mapping Workshop on Overcoming Barriers to Adoption of Composites in Infrastructure” brought together designers, manufacturers, researchers, and end-users to identify barriers and potential solutions. Composite products produced in

Moisture Uptake Characterization in Nanocellulose Using Microwave Cavity

August 17, 2017
Author(s)
Caglar Emiroglu, Bharath N. Natarajan, Jeffrey W. Gilman, James Alexander Liddle, Jan Obrzut
Cellulose nanocrystal films with different helical modulation lengths are characterized. Films are obtained by tuning the rate of evaporation and surface functionalization. Dielectric constant measurements are performed and the water confinement is

Phase mask-based multimodal superresolution microscopy

July 6, 2017
Author(s)
Ryan Beams, Jeremiah W. Woodcock, Jeffrey W. Gilman, Stephan J. Stranick
We demonstrate a multimodal superresolution microscopy technique based on a phase masked excitation beam in combination with spatially filtered detection. The theoretical foundation for calculating the focus from a non-paraxial beam with an arbitrary

Dielectric Characterization of Confined Water in Chiral Cellulose Nanocrystal Films

April 10, 2017
Author(s)
Bharath N. Natarajan, Caglar Emiroglu, Jan Obrzut, Douglas M. Fox, Beatriz Pazmino, Jack F. Douglas, Jeffrey W. Gilman
A known deterrent to a large scale development and use of cellulose nanocrystals (CNCs) is their affinity for moisture, which has a profound effect on dispersion, wetting, interfacial adhesion, matrix crystallization and water uptake. To quantify the

A Comparison of Quality of Dispersion of Single Wall Carbon Nanotubes Using Different Surfactants and Biomolecules

February 19, 2017
Author(s)
Jeffrey W. Gilman, R Haggenmueller, Sameer Rahatekar, Jeffrey Fagan, Jae H. Chun, Matthew Becker, Rajesh R. Naik, Todd Krauss, Lisa Carlson, Shana O. Kelley, Paul C. Trulove, D M. Fox, John Kadla
The application of single wall carbon nanotubes (SWCNT) in current and future applications crucially depends on the ability to process SWCNT in a solvent to yield high quality dispersions characterized by individual SWCNTs and possessing a minimum of SWCNT

Delamination of Organo-Modified Layered Double Hydroxides in Polyamide 6 by Melt Processing

February 19, 2017
Author(s)
Mauro Zammarano, S Bellayer, Jeffrey W. Gilman, Massimiliano Franceschi, Frederick Beyer, Richard H. Harris Jr., Meriani Sergio
Layered double hydroxide/polyamide 6 nanocomposites (LDH/PA6) were prepared from organo-modified LDH by melt processing. The anionic exchange capacity of LDH was varied in order to investigate its influence on the degree of exfoliation. LDH were dispersed

Development of High Throughput Methods for Polymer Flammability Property Characterization

February 19, 2017
Author(s)
Jeffrey W. Gilman, Rick D. Davis, John R. Shields, D Wentz, L D. Brassell, A B. Morgan, R Lyon, J E. Zanetto
Recently we have developed several new high throughput (HT) methods to quantitatively evaluate the flammability of flame retarded (FR) polymers. The most recent results are due to the efforts of the High Throughput Methods for Materials Flammability

Dielectric Spectroscopy During Extrusion Processing of Polyamide-6 Nanocomposites

February 19, 2017
Author(s)
Rick D. Davis, Anthony J. Bur, Jeffrey W. Gilman, Young Jong Lee, P R. Start
During extrusion processing dielectric spectroscopy was conducted on polyamide-6 (PA6) and organoclay/polyamide-6 nanocomposites. Off-line curve fitting of the on-line dielectric data generated dielectric dispersion parameters that appear sensitive to