U.S. flag

An official website of the United States government

Official websites use .gov
A .gov website belongs to an official government organization in the United States.

Secure .gov websites use HTTPS
A lock ( ) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.

PUBLICATIONS

Optical Probes for Monitoring Intercalation and Exfoliation in Melt Processed Polymer Nanocomposites

Published

Author(s)

P H. Maupin, Jeffrey W. Gilman, Richard H. Harris Jr., S Bellayer, Anthony J. Bur, S C. Roth, A B. Morgan, J R. Harris, M Murariu

Abstract

Laser induced fluorescence spectroscopy of the optical probe Nile Blue A in polymer clay nanocomposites is described. Concentration quenching of fluorescence dominates probe behavior until the clay platelets are physically separated by polymer intercalation. Further separation into an exfoliated structure results in an intense increase in probe fluorescence. Preliminary results indicate the ability to discriminate between intercalated and exfoliated structures in nanocomposites formed by melt processing.
Citation
Macromolecular Rapid Communications
Pub Type
Journals

Keywords

extrusion, fluorescence, laser, nanocomposite, organoclay
Fire and Buildings and Construction

Citation

Maupin, P. , Gilman, J. , Harris Jr., R. , Bellayer, S. , Bur, A. , Roth, S. , Morgan, A. , Harris, J. and Murariu, M. (2021), Optical Probes for Monitoring Intercalation and Exfoliation in Melt Processed Polymer Nanocomposites, Macromolecular Rapid Communications (Accessed December 7, 2024)

Issues

If you have any questions about this publication or are having problems accessing it, please contact reflib@nist.gov.

Created October 12, 2021