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Search Publications by: Valeri I. Babushok (Assoc)

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Displaying 26 - 50 of 90

Influence of Antimony-Halogen Additives on Flame Propagation

July 8, 2016
Author(s)
Valeri I. Babushok, Peter Deglmann, Gregory T. Linteris, Roland H. Kraemer
A kinetic model for flame inhibition by antimony-halogen compounds in hydrocarbon flames is developed. Thermodynamic data for the relevant species are assembled from the literature, and calculations are performed for a large set of additional species of Sb

Influence of Hydrocarbon Moiety of DMMP on Flame Propagation in Lean Mixtures

July 7, 2016
Author(s)
Gregory T. Linteris, Valeri I. Babushok, Viswanath R. Katta, Fumiaki Takahashi
Phosphorus-containing compounds (PCCs) have been found to be significantly more effective than CF3Br for reducing burning velocity when added to stoichiometric hydrocarbon-air flames. However, when added to lean flames, DMMP (dimethylmethylphosphonate) is

Understanding Overpressure in the FAA Aerosol Can Test by C3H2F3Br (2-BTP)

March 18, 2016
Author(s)
Gregory T. Linteris, Valeri I. Babushok, John L. Pagliaro, Jeffrey A. Manion, Donald R. Burgess Jr., Fumiaki Takahashi, Viswanath R. Katta, Patrick T. Baker
Thermodynamic equilibrium calculations, as well as perfectly-stirred reactor (PSR) simulations with detailed reaction kinetics, are performed for a potential halon replacement, C3H2F3Br (2-BTP, C3H2F3Br, 2-Bromo-3,3,3-trifluoropropene), to understand the

A Chemical Kinetic Mechanism for 2-Bromo-3,3,3-trifluoropropene (2-BTP) Flame Inhibition

July 22, 2015
Author(s)
Donald R. Burgess Jr., Valeri I. Babushok, Gregory T. Linteris, Jeffrey A. Manion
The present paper is concerned with the development of a detailed chemical kinetic mechanism to describe the flame inhibition chemistry of the fire suppressant 2-bromo-3,3,3-trifluoropropene (2-BTP). Currently 2-BTP is considered as a fire suppressant to

Experimental and Numerical Simulations of the Gas-Phase Effectiveness of Phosphorus Compounds

February 2, 2015
Author(s)
Nicolas Bouvet, Gregory T. Linteris, Valeri I. Babushok, Fumiaki Takahashi, Viswanath R. Katta
The effectiveness of phosphorus-containing compounds as gas-phase combustion inhibitors varies widely with flame type. To understand this behavior, experiments are performed with dimethyl methylphosphonate (DMMP) added to the oxidizer stream of methane-air

Hydrocarbon Flame Inhibition by C3H2F3Br (2-BTP)

November 14, 2014
Author(s)
Valeri I. Babushok, Gregory T. Linteris, Donald R. Burgess Jr., Patrick T. Baker
The kinetic mechanism of hydrocarbon flame inhibition by the potential halon replacement 2-BTP has been assembled, and is used to study its effects on premixed methane-air flames. Simulations with varying CH4-air stoichiometry and agent loading have been

Modeling of 2-bromotrifluoropropene flame inhibition

August 14, 2014
Author(s)
Donald R. Burgess Jr., Jeffrey A. Manion, Valeri I. Babushok, Gregory T. Linteris
We developed a new chemical mechanism for modeling flame inhibition by 2-bromotrifluoropene (2-BTP). The modeling results qualitatively predicted agent behavior in cup-burner and FAA Aerosol Can tests over a wide range of conditions. The ban on igh ozone

Influence of Flame Characteristics on Gas- Phase Fire Retardant Effectiveness

May 30, 2014
Author(s)
Gregory T. Linteris, Nicolas Bouvet, Valeri I. Babushok, Fumiaki Takahashi, Viswanath R. Katta, Stanislav Stoliarov, Peter B. Sunderland
The presentation discusses the influence of flame characteristics on gas-phase fire retardant effectiveness. First, the action of super-effective agents in co-flow diffusion flames is reviewed, highlighting how particle formation had a detrimental effect

Flame Inhibition by CF3CHCl2 (HCFC-123)

May 20, 2014
Author(s)
Valeri I. Babushok, Gregory T. Linteris, Oliver Meier, John Pagliaro
A kinetic model is suggested for hydrocarbon-air flame propagation with addition of hydrochloroflurocarbon (HCFC) fire suppressants, encompassing the combined chemistry of fluorine- and chlorine-containing species. Calculated burning velocities using the

The Exothermic Reaction of Fire Suppressants

March 13, 2013
Author(s)
Gregory T. Linteris, Valeri I. Babushok, Fumiaki Takahashi, Viswanath R. Katta, Oliver Meier
Several fire suppressants are under consideration to replace CF3Br for use in suppressing fires in aircraft cargo bays. In Federal Aviation Administration performance tests simulating the explosion of an aerosol can, however, the replacements HFC-125, 2-

Unwanted Combustion Enhancement by C6F12O Fire Suppressant

August 7, 2012
Author(s)
Gregory T. Linteris, Valeri I. Babushok, Peter B. Sunderland, Fumiaki Takahashi, Viswanath R. Katta, Oliver Meier
Several agents are under consideration to replace CF3Br for use in suppressing fires in aircraft cargo bays. In a Federal Aviation Administration (FAA) performance test simulating the explosion of an aerosol can, however, the replacements, when added at

Combustion Properties of Halogenated Fire Suppressants

August 1, 2012
Author(s)
Gregory T. Linteris, Valeri I. Babushok, Oliver Meier
Previous experimental studies have shown that some halogenated fire suppressant agents added to hydrocarbon-air systems can enhance the combustion. For example, their addition to the air stream can widen the flammability limits of lean mixtures, and

Inhibition of Silane Ignition by Iodine Containing Additives

October 16, 2008
Author(s)
Valeri I. Babushok, Wing Tsang
The results of numerical studies on the influence of iodine and hydrogen iodide additives on silane self-ignition limits are reported. The entire matrix of possibilities with regard to silane and oxygen ratios was covered. The temperature and pressures

Catalytic Inhibition of Laminar Flames by Transition Metal Compounds

June 1, 2008
Author(s)
Gregory T. Linteris, M D. Rumminger, Valeri I. Babushok
Some of the most effective flame inhibitors ever found are metallic compounds. Their effectiveness, however, drops off rapidly with an increase of agent concentration, and varies widely with flame type. Iron pentacarbonyl, for example, can be up to two

Catalytic Inhibition of Laminar Flames by Transition Metal Compounds.

June 1, 2008
Author(s)
Gregory T. Linteris, Valeri I. Babushok, M D. Rumminger
Some of the most effective flame inhibitors ever found are metallic compounds. Their effectiveness, however, drops off rapidly with an increase of agent concentration, and varies widely with flame type. Iron pentacarbonyl, for example, can be up to two

Development of Database on Gas-Chromatographic Retention Properties of Organic Compounds

July 2, 2007
Author(s)
Valeri I. Babushok, Peter J. Linstrom, J J. Reed, I G. Zenkevich, Robert L. Brown, William G. Mallard, Stephen E. Stein
A comprehensive database of gas chromatographic properties of chemical compounds has been developed using multiple literature sources. The collection of retention data for non-polar and polar stationary phases currently contains 292,924 data records for 42

Estimation of Kov ts Retention Indices Using Group Contributions

March 17, 2007
Author(s)
Stephen E. Stein, Valeri I. Babushok, Robert L. Brown, Peter J. Linstrom
We have constructed a group contribution method for estimating Kov ts retention indices by using observed data from a set of diverse organic compounds. Our database contains observed retention indices for over 35,000 different molecules. These were

Condensation Flame of Acetylene Decomposition

January 1, 2004
Author(s)
Valeri I. Babushok, A W. Miziolek
Acetylene decomposition flame propagation was studied as the result of the condensation reaction. The used kinetic models reasonably predict the level of burning velocity of acetylene decomposition flame. Nevertheless the models do not demonstrate pressure