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Search Publications by: Terrence J Udovic (Assoc)

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Displaying 26 - 50 of 166

Low-Temperature Rotational Tunneling of Tetrahydroborate Anions in Lithium Benzimidazolate-Borohydride Li 2 (blm)BH 4

August 7, 2019
Author(s)
Alexander V. Skripov, Mirjana NMN Dimitrievska, Olga A. Babanova, R. V. Skoryunov, Alexei V. Soloninin, Fabrice Morelle, Y. Filinchuk, Antonio Faraone, Hui Wu, Wei Zhou, Terrence J. Udovic
To investigate the dynamical properties of the novel hybrid compound, lithium benzimidazolate-borohydride Li 2(bIm)BH 4 (where bIm denotes a benzimidazolate anion, C 7N 2H 5u-^), we have used a set of complementary techniques: neutron powder diffraction

Nuclear Magnetic Resonance Study of Anion and Cation Dynamics in CsSiH 3

March 31, 2019
Author(s)
R. V. Skoryunov, O. A. Babanova, A. V. Soloninin, A. V. Skripov, J.-N. Chotard, R. Janot, W. S. Tang, Mirjana NMN Dimitrievska, Terrence J. Udovic
In order to study the dynamical properties of cesium silanide CsSiH 3, we have measured the 1H and 133Cs nuclear magnetic resonance (NMR) spectra and spin-lattice relaxation rates in this compound over the temperature range of 5 K to 354 K. The results of

Tracking the Progression of Anion Reorientational Behavior between a-Phase and b-Phase Alkali-Metal Silanides, MSIH 3 , by Quasielastic Neutron Scattering

October 25, 2018
Author(s)
Mirjana NMN Dimitrievska, Jean-Noel Chotard, Raphael Janot, Antonio Faraone, Wan Si Tang, Alexander V. Skripov, Terrence J. Udovic
Quasielastic neutron scattering (QENS) measurements over a wide range of resolutions were used to probe the reorientational behavior of the pyramidal SiH 3- anions in the mono-alkali silanides (MSiH 3, where M-K, Rb, and Cs) within the low-temperature

Nature of Decahydro-Closo-Decaborate Anion Reorientations in an Ordered Alkali-Metal Salt: Rb 2 B 10 H 10

July 12, 2018
Author(s)
Mirjana NMN Dimitrievska, Vitalie Stavila, Alexei V. Soloninin, Roman V. Skoryunov, Olga A. Babanova, Hui Wu, Wei Zhou, Wan Si Tang, Antonio Faraone, Jacob Daniel Tarver, Benjamin Trump, Alexander V. Skripov, Terrence J. Udovic
The ordered monoclinic phase of the alkali-metal decahydro-closodecaborate salt Rb 2B 10H 10 was found to be stable from about 250 K all the way up to an order-disorder phase transition temperature of approximately equal} 762 K. The broad temperature range

Nuclear Magnetic Resonance Study of Anion and Cation Reorientational Dynamics in (NH 4 ) 2 B 12 H 12

January 29, 2018
Author(s)
Alexander V. Skripov, Roman V. Skoryunov, Alexei V. Soloninin, Olga A. Babanova, Vitalie Stavila, Terrence J. Udovic
Diammonium dodecahydro-closedidecabirate (NH 4) 2B 12H 12 is the ionic compound combining NH 4 + cations and [B 12H 12] 2- anions both of which can exhibit high reorientational mobility. To study the dynamical properties of this unusual material, we have

Order-Disorder Transitions and Superionic Conductivity in the Sodium Nido-Undeca(carba)borates

December 26, 2017
Author(s)
Wan Si NMN Tang, Mirjana NMN Dimitrievska, Vitalie Stavila, Wei Zhou, Hui Wu, A. Alec Talin, Terrence J. Udovic
The salt compounds NaB 11H 14, Na-7-CB 10H 13, Li-7-CB 10H 13, Na-7,8-Cd2^B 9H 12, and Na-7,9-C 2B 9H 12 all contain geometrically similar, monocharged, nido-undeca(carba)borate anions (i.e., truncated icosohedral-shaped clusters constructed of only eleven

Structural, Chemical, and Dynamical Frustration: Origins of Superionic Conductivity in closo-Borate Solid Electrolytes

October 11, 2017
Author(s)
Kyoung E. Kweon, Joel B. Varley, Patrick Shea, Nicole Adelstein, Prateek Mehta, Tae Wook Heo, Terrence J. Udovic, Vitalie Stavila, Brandon C. Wood
Li 2B 12H 12 and Na 2B^12^H 12 closoboranes exhibit unusually high ionic conductivity, making them attractive as a new class of candidate electrolytes in solid-state Li- and Na-ion batteries. However, further optimization of these materials requires a

Latent Porosity in Alkali-Metal M 2 B 12 F 12 Salts: Structures and Rapid Room-Temperature Hydration/Dehydration Cycles

October 2, 2017
Author(s)
Dmitry V. Peryshkov, Eric V. Bukovsky, Matthew R. Lacroix, Hui Wu, Wei Zhou, W. Matthew Jones, Matic Lozinsek, Travis C. Folsom, D. Luke Heyliger, Terrence J. Udovic, Steven H. Strauss
Structures of the alkali metal hydrates Li 2(H 2O) 4Z, LiK(H 2O) 4, Na 2(H 2O) 3Z, and Rb 2(H 2O) 2Z, unit cell parameters for Rb 2Z and Rb 2(H 2O) 2Z, and the DFT-optimized structures of K 2Z, K 2(H 2O) 2Z, Rb 2Z, Rb 2(H 2O) 2Z, Cs 2Z, and Cs 2(H 2O)Z are

Comparison of the Coordination of B 12 F 12 ^2-^, B 12 Cl 12 2- , and B 12 H 12 ^2-^ to Na + in the Solid State: Crystal Structures and Thermal Behavior of Na 2 (B 12

April 6, 2017
Author(s)
Eric V. Bukovsky, Dmitry V. Peryshkov, Hui Wu, Wei Zhou, Wan Si NMN Tang, W. Matthew Jones, Vitalie Stavila, Terrence J. Udovic, Steven H. Strauss
The synthesis of high-purity Na 2B 12F 12 and the crystal structures of Na 2(B 12F 12) (5 K neutron powder diffraction (NPD)), Na 2(H 2O) 4(B 12F 12) (120 K single-crystal X-ray diffraction (SC-XRD), Na 2(B 12Cl 12) (5 K and 295 K NPD), and Na 2(H 2O) 6(B

Fast Sodium Ionic Conduction in Na 2 B 10 H 10 -Na 2 B 12 H 12 Pseudo-Binary Complex Hydride and Application to a Bulk-Type All-Solid-State Battery

March 6, 2017
Author(s)
Koji Yoshida, Toyoto Sato, Atsushi Unemoto, Motoaki Matsuo, Tamio Ikeshoji, Terrence J. Udovic, Shin-Ichi Orimo
In the present work, we developed highly ion-conductive Na 2B 10H 10-Na 2B 12H 12 closo-borane (solid-solution) salts via mechanically ball-milling admixtures of the pure Na 2B 10H 10 and Na 2B 12H 12 components. They were characterized by XRD, Raman

Vibrational Properties of b-KSiH 3 and b-RbSiH 3 : A Combined Raman and Inelastic Neutron Scattering Study

February 1, 2017
Author(s)
Janos Mink, Yuan-Chih Lin, Maths Karlsson, Carin Osterberg, Terrence J. Udovic, Henrik Fahlquist, Ulrich Haussermann
The hydrogen storage materials ASiH 3 (A=K, Rb) represent complex metal hydrides built from metal cations and pyramidal SiH 3- ions. At room temperature, SiH 3-moieties are randomly oriented because of dynamical disorder (α-modifications). At temperatures