Unemoto, A.
, Wu, H.
, Udovic, T.
, Matsuo, M.
, Ikeshoji, T.
and Orimo, S.
(2016),
Fast Lithium-Ionic Conduction in a New Complex Hydride-Sulphide Crystalline Phase, Chemical Communications, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=919201
(Accessed May 10, 2024)
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Fast Lithium-Ionic Conduction in a New Complex Hydride-Sulphide Crystalline Phase
Published
Author(s)
Atsushi Unemoto, , , Motoaki Matsuo, Tamio Ikeshoji, Shin-Ichi Orimo
Abstract
A new crystalline phase derived from a 90LiBH4:10P2S5 mixture displays high lithium-ionic conductivity of log(ς/S cm-1) = 3.0 at 300 K. It is stable up to 473 K and has both a wide potential window of 0-5 V and favorable mechanical properties for battery assembly. Its incorporation into a bulk-type all-solid-state TiS2/Li battery enabled repeated battery operation at 300 K.Citation
Chemical Communications
Volume
52
Issue
3
Pub Type
Journals
Download Paper
Keywords
battery, conductivity, ionic conduction, lithium, lithium borohydride, neutron scattering, phosphorus pentasulfide, solid electrolyte, solid-state battery
Citation
Issues
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Created January 10, 2016, Updated October 12, 2021