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Stabilizing Lithium and Sodium Fast-Ion Conduction in Solid Polyhedral-Borate Salts at Device-Relevant Temperatures

Published

Author(s)

Wan Si NMN Tang, Motoaki Matsuo, Hui Wu, Vitalie Stavila, Atsushi Unemoto, Shin-Ichi Orimo, Terrence J. Udovic

Abstract

Mechanically milling a variety of lithium and sodium closo-borate compounds enables the room-temperature stabilization of their fast-ion-conducting, high-T-like disordered phases. This represents a viable strategy for better exploiting the impressive superionic properties of these compounds.
Citation
Energy Storage Materials
Volume
4

Keywords

ball-milling, closo-borates, diffraction, ionic conductivity, lithium conductors, mechanical milling, quasielastic neutron scattering, sodium conductors, solid-state conductors

Citation

Tang, W. , Matsuo, M. , Wu, H. , Stavila, V. , Unemoto, A. , Orimo, S. and Udovic, T. (2016), Stabilizing Lithium and Sodium Fast-Ion Conduction in Solid Polyhedral-Borate Salts at Device-Relevant Temperatures, Energy Storage Materials, [online], https://tsapps.nist.gov/publication/get_pdf.cfm?pub_id=919925 (Accessed March 4, 2024)
Created June 30, 2016, Updated October 12, 2021