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Displaying 151 - 175 of 437

Predicting structural properties of fluids by thermodynamic extrapolation

May 16, 2018
Author(s)
Nathan Mahynski, Sally Jiao, Harold W. Hatch, Marco A. Blanco Medina, Vincent K. Shen
We describe a methodology for extrapolating the structural properties of multicomponent fluids from one thermodynamic state to another. These properties generally include features of a system that may be computed from an individual configuration such as

Influence of Ion Solvation on the Properties of Electrolyte Solutions

April 3, 2018
Author(s)
Marat Andreev, Juan J. DePablo, Alexandros Chremos, Jack F. Douglas
It is widely appreciated that the addition of salts to water leads to significant changes in the thermodynamic and dynamic properties of these aqueous solutions, which have great significance in biology and manufacturing applications. However, no

3D printed ABS-MOF composite materials and their gas storage properties

March 19, 2018
Author(s)
Michael Bible, Makfir Sefa, Julia Scherschligt, Zeeshan Ahmed, James A. Fedchak, Hartings Mathew
Metal organic framework materials (MOFs) have been primarily recognized for their ability to promote selective storage of gas molecules. In their as-synthesized (powdered) form, MOFs are not easily processed for use in end-devices where their properties

Vacuum Furnace for Degassing Stainless-Steel Vacuum Components

March 1, 2018
Author(s)
James A. Fedchak, Julia K. Scherschligt, Daniel S. Barker, Stephen P. Eckel, Alex P. Farrell, Makfir Sefa
Ultra-high vacuum systems must often be constructed of materials with ultra-low outgassing rates to achieve pressure of 10-6 Pa and below. In such a case, any component placed into the ultra-high vacuum system must also be constructed of materials with

Quasi-Two-dimensional Phase Transition of Methane Adsorbed in Cylindrical Silica Mesopores

November 29, 2017
Author(s)
Daniel W. Siderius, William P. Krekelberg, Wei-Shan NMN Chiang, Vincent K. Shen, Yun Liu
Using Monte Carlo and molecular dynamics simulations, we examine the adsorption of methane in cylindrical silica mesopores in an effort to understand a possible phase transition of adsorbed methane in MCM-41 and SBA-15 silica that was previously identified

On the Melting Curve of Sulfur Hexafluoride

November 9, 2017
Author(s)
Allan H. Harvey
A previous correlation for the melting curve of sulfur hexafluoride (SF6) is inconsistent with the thermodynamic slope at the triple point derived from the Clapeyron equation. It is shown that this is probably due to the previous authors combining an

Perspectives for a new realization of the pascal by optical methods

October 24, 2017
Author(s)
Jay H. Hendricks, Karl Jousten, Jack A. Stone Jr., Patrick F. Egan, Tom Rubin, Christof Gaiser, Rene Schodel, James A. Fedchak, Jacob E. Ricker, Jens Fluegge, Stephen P. Eckel, Julia K. Scherschligt, Daniel S. Barker, Kevin O. Douglass, Gregory F. Strouse, Uwe Sterr, Waldimir Sabuga
Since the beginning of measurement of pressure in the 17th century, the unit of pressure has been defined by the relationship of force per unit area. The present state of optical technology now offers the possibility of using a thermodynamic definition

An integrated and automated calibration system for pneumatic piston gauges

October 17, 2017
Author(s)
Yuanchao Yang, Robert G. Driver, John S. Quintavalle, Julia Scherschligt, Katie M. Schlatter, Jacob Edmond Ricker, Gregory F. Strouse, Douglas A. Olson, Jay H. Hendricks
Recently, a transducer-aided crossfloat (TAC) method for pneumatic piston gauges was proposed. The concept is to use a pressure transducer as a very short-term transfer standard between the standard piston gauge and the test one. Different from the

Reference Correlations for the Viscosity and Thermal Conductivity of n-Undecane

September 26, 2017
Author(s)
Marc J. Assael, T.B. Papalas, Marcia L. Huber
This paper presents new wide-ranging correlations for the viscosity and thermal conductivity of n-undecane based on critically evaluated experimental data. The correlations are designed to be used with a recently published equation of state that is valid

Calorimetric Determination of Enthalpies of Vaporization

September 12, 2017
Author(s)
Eugene Paulechka, Dzmitry H. Zaitsau
A review of calorimeters and experimental procedures used for measurement of enthalpies of vaporization for pure liquids is presented. The calorimetric approaches that are illustrated give an insight into direct determination of enthalpies of vaporization

Internal Pressure and Internal Energy of Saturated and Compressed Phases

September 12, 2017
Author(s)
Joe W. Magee, Ilmutdin Abdulagatov, Nikolai Polikhronidi, Rabiyat Batyrova
Following a critical review of the field, a comprehensive analysis is provided of the internal pressure of fluids and fluid mixtures and its determination in a wide range of temperatures and pressures. Further, the physical meaning is discussed of the

Yang-Yang Critical Anomaly

September 12, 2017
Author(s)
Joe W. Magee, Ilmutdin Abdulagatov, Nikolai Polikhronidi, Rabiyat Batyrova
Following a critical review of related research, a method is described to evaluate the Yang-Yang critical anomaly strength function, , from experimental measurements of two-phase liquid ( ) and vapor ( ) isochoric heat capacities and liquid ( ) and vapor (

New measurement of the Boltzmann constant k by acoustic thermometry of helium-4 gas

September 11, 2017
Author(s)
Laurent Pitre, Fernando Sparasci, Michael R. Moldover, Cecile Guianvarch, Catherine Martin, Martin Himbert, Mark Plimmer, James B. Mehl, Giuliano Albo, Bo Gao, Lara Risegari
The SI unit of temperature will soon be redefined in terms of a fixed value of the Boltzmann constant k derived from an ensemble of measurements worldwide. We report on a new determination of k using acoustic thermometry of helium-4 gas in a 3-litre quasi

ThermoData Engine (TDE) Version 10.2 (Pure Compounds, Binary Mixtures, Ternary Mixtures, and Chemical Reactions): NIST Standard Reference Database 103b

August 31, 2017
Author(s)
Vladimir Diky, Chris D. Muzny, Alexander Y. Smolyanitsky, Ala Bazyleva, Robert D. Chirico, Joe W. Magee, Yauheni Paulechka, Andrei F. Kazakov, Scott A. Townsend, Eric W. Lemmon, Michael D. Frenkel, Kenneth G. Kroenlein
The ThermoData Engine is a software expert system implementing the concept of dynamic data evaluation for thermophysical and thermochemical properties of, primarily, organic compounds. This new release provides a substantially expanded database of

Surface interaction parameter measurement of solvated polymers via model end-tethered chains

August 11, 2017
Author(s)
Richard J. Sheridan, Sara V. Orski, Ronald L. Jones, Sushil K. Satija, Kathryn L. Beers
We present a method for the direct measurement of the relative energy of interaction between a solvated polymer and a solid interface. By tethering linear chains covalently to the surface, we ensured the idealized and constant configuration of polymer

A Boltzmann Constant Determination Based on Johnson Noise Thermometry

August 10, 2017
Author(s)
Nathan E. Flowers-Jacobs, Alessio Pollarolo, Kevin J. Coakley, Anna E. Fox, Horst Rogalla, Weston L. Tew, Samuel P. Benz
A value for the Boltzmann constant was measured electronically using an improved version of the Johnson Noise Thermometry (JNT) system at the National Institute of Standards and Technology (NIST), USA. This system is different from prior ones, including
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