An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Photoemission spectra at hv=21.2 eV reveal two 5p levels for xenon physisorbed on a tungsten (100) surface. The spin-orbit splitting of the two levels and their intensity ratio correspond closely to gas-phase measurements, while the 5p 3/2 peak is
In recent theoretical work by Gadzuk and by Liebsch, the importance of angle resolved photoemission studies of surfaces and chemisorbed atoms has been demonstrated. In the theory due to Gadzuk, the role of the initial state in the photoemission process has
It is shown that recent measurements of field ion energy distributions from clean tungsten surfaces probe the density of metal states in the vicinity of the surface. We find j() = (2/kh)m| d3rm(r) z|2(-m), where j() is the ion current a , mand m are
Creation of a deep localized hole in the process of x-ray photoemission from metals is followed by a drastic rearrangement of the surrounding electrons in the Fermi sea. This rearrangement in which low-energy electron-hole pairs are produced, in analogy
Relativistic Hartree-Fock-Wigner-Seitz band calculations have been performed for the actinide metals Ac through Am in order to estimate 5f excitation energies. Our calculations predict that the tetravalent state (i.e., four s-d conduction electrons) is
We calculate the dielectric response of adsorbate atoms on a metal surface assuming an Anderson model of the system. The dielectric function is then used to predict the change in the surface optical reflectance caused by the adsorbates. General results are
It is shown that the combination of spin-polarization and field-emission energy distribution measurements on ferromagnetic transition metals will provide direct information about the one-dimensional surface density of states in a direction normal to the
Recent theoretical work has suggested the possibility of determining chemisorption bond geometry by the use of uv photoemission. This possibility is being investigated experimentally in an apparatus developed at NBS. The apparatus is described, and
The upward shift in atomic energy levels (or decrease in electron binding energies) which occurs upon sorption of an atom on a metal surface due to polarization of the valence band electrons, is considered. The polarization shift or extra-atomic relaxation
A theory of the angular distributions of electrons photoemitted from submonolayer films of chemisorbed atoms is presented. Chemisorption is treated within the surface-molecule limit of the Anderson model. It is shown that the key features which
A useful picture of chemisorption on metal surfaces is one in which a localized molecule is formed between the adatom and its nearest neighbor substrate atoms. The interaction responsible for the molecule formation is treated as the coupling between the
Field-emission measurements of the total-energy distribution from a clean metal surface are shown to provide information about the density of states near the surface. Specifically, we find the field-emitted current per unit energy at energy ω to be given
Recent measurements of the L 23VV auger spectrum of Al by Powell, have shown that the observed energy distributions do not correspond to the self-convolution of the Al bulk density of states. Attempts to account for this discrepancy in terms of energy
The technique of measuring the energy distribution of electron which have been field emitted from a cold cathode is considered. The genral historical and introductory theory is presented. A survey of the experimental techniques and existing energy
Measurements of the L 2,3VV (V=valence) Auger spectrum of aluminum and the M 4,5VV Auger spectrum of silver cannot be simply related to the valence-band density of states. The data for Al indicate a strong energy variation of the transition probability