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A survey is given of the available cross-section data for ionization of inner-shell electrons by incident electrons in the range of interest for electron-probe microanalysis and for Auger-electron spectroscopy of solid surfaces. Owing to the paucity of
Mean free paths for electrons in bulk jellium are calculated for hot electrons with energies from a few hundred to a few thousand electron volts and for values of r s from 1.5 to 5. Exchange and correlation effects are included and the results are compared
Electron spectroscopy for chemical analysis (ESCA) can be used as a quantitative tool for the determination of the chemical composition of the surface region of a solid if certain parameters are known. The least well known is the electron mean free path
Photoemission spectra at hv=21.2 eV reveal two 5p levels for xenon physisorbed on a tungsten (100) surface. The spin-orbit splitting of the two levels and their intensity ratio correspond closely to gas-phase measurements, while the 5p 3/2 peak is
In recent theoretical work by Gadzuk and by Liebsch, the importance of angle resolved photoemission studies of surfaces and chemisorbed atoms has been demonstrated. In the theory due to Gadzuk, the role of the initial state in the photoemission process has
It is shown that recent measurements of field ion energy distributions from clean tungsten surfaces probe the density of metal states in the vicinity of the surface. We find j() = (2/kh)m| d3rm(r) z|2(-m), where j() is the ion current a , mand m are
Creation of a deep localized hole in the process of x-ray photoemission from metals is followed by a drastic rearrangement of the surrounding electrons in the Fermi sea. This rearrangement in which low-energy electron-hole pairs are produced, in analogy
Relativistic Hartree-Fock-Wigner-Seitz band calculations have been performed for the actinide metals Ac through Am in order to estimate 5f excitation energies. Our calculations predict that the tetravalent state (i.e., four s-d conduction electrons) is
We calculate the dielectric response of adsorbate atoms on a metal surface assuming an Anderson model of the system. The dielectric function is then used to predict the change in the surface optical reflectance caused by the adsorbates. General results are
It is shown that the combination of spin-polarization and field-emission energy distribution measurements on ferromagnetic transition metals will provide direct information about the one-dimensional surface density of states in a direction normal to the
Recent theoretical work has suggested the possibility of determining chemisorption bond geometry by the use of uv photoemission. This possibility is being investigated experimentally in an apparatus developed at NBS. The apparatus is described, and
The upward shift in atomic energy levels (or decrease in electron binding energies) which occurs upon sorption of an atom on a metal surface due to polarization of the valence band electrons, is considered. The polarization shift or extra-atomic relaxation
A theory of the angular distributions of electrons photoemitted from submonolayer films of chemisorbed atoms is presented. Chemisorption is treated within the surface-molecule limit of the Anderson model. It is shown that the key features which