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A microwave-discharge uv light source has been improved to yield significant photon fluxes at 26.9 and 40.81 eV. In order to optimize the 26.9-eV (NeII) and 40.81-eV (HeII) radiation, the discharge was operated at ~2.5 Pa (0.019 Torr) in an external
We present estimates of various contributions to the free-atom-metal binding-energy shifts, Δ}E B, for the 2>s and 2p core levels of teh iron series elements and, for comparison, the 3 d s/2 level of Sn. Our results indicate that the sharp break in the
We describe calculations of 4f electron binding energies for the rare-earth metals. Relativistic Hartree-Fock calculations for atomic configurations most closely approximating those of the metals are initially performed, and crystal potentials are
R E. Watson, J F. Herbst, L Hodges, B I. Lundqvist, J W. Wilkins
Self-consistent energy-band calculations for paramagnetic Ni have been performed in an effort to compare ground-state and excitationpotential prescriptions; potentials of the Hartree-Fock-Wigner-Seitz and Hedin-Lundqvist type are examined. We find the
A survey is given of the available cross-section data for ionization of inner-shell electrons by incident electrons in the range of interest for electron-probe microanalysis and for Auger-electron spectroscopy of solid surfaces. Owing to the paucity of
Mean free paths for electrons in bulk jellium are calculated for hot electrons with energies from a few hundred to a few thousand electron volts and for values of r s from 1.5 to 5. Exchange and correlation effects are included and the results are compared
Electron spectroscopy for chemical analysis (ESCA) can be used as a quantitative tool for the determination of the chemical composition of the surface region of a solid if certain parameters are known. The least well known is the electron mean free path
Photoemission spectra at hv=21.2 eV reveal two 5p levels for xenon physisorbed on a tungsten (100) surface. The spin-orbit splitting of the two levels and their intensity ratio correspond closely to gas-phase measurements, while the 5p 3/2 peak is
In recent theoretical work by Gadzuk and by Liebsch, the importance of angle resolved photoemission studies of surfaces and chemisorbed atoms has been demonstrated. In the theory due to Gadzuk, the role of the initial state in the photoemission process has
It is shown that recent measurements of field ion energy distributions from clean tungsten surfaces probe the density of metal states in the vicinity of the surface. We find j() = (2/kh)m| d3rm(r) z|2(-m), where j() is the ion current a , mand m are
Creation of a deep localized hole in the process of x-ray photoemission from metals is followed by a drastic rearrangement of the surrounding electrons in the Fermi sea. This rearrangement in which low-energy electron-hole pairs are produced, in analogy
Relativistic Hartree-Fock-Wigner-Seitz band calculations have been performed for the actinide metals Ac through Am in order to estimate 5f excitation energies. Our calculations predict that the tetravalent state (i.e., four s-d conduction electrons) is
We calculate the dielectric response of adsorbate atoms on a metal surface assuming an Anderson model of the system. The dielectric function is then used to predict the change in the surface optical reflectance caused by the adsorbates. General results are
It is shown that the combination of spin-polarization and field-emission energy distribution measurements on ferromagnetic transition metals will provide direct information about the one-dimensional surface density of states in a direction normal to the