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Materials

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Displaying 726 - 750 of 2328

Electrically Conductive 3D Metal-Organic Framework Featuring p-Acidic Hexaazatriphenylene Hexacarbonitrile Ligands with Anion-p Interaction and Efficient Charge-Transport Capabilities

September 8, 2020
Author(s)
Ashok Yadav, Dillip K. Panda, Shiyu Zhang, Wei Zhou, Sourav Saha
Owing to their unparalleled synthetic simplicity, structural tunability, and functional versatility, electrically conductive metal–organic frameworks (MOFs) have emerged as one of the most promising electronic materials of the 21 st century. With much of

Cutting to Measure the Elasticity and Fracture of Soft Gels

August 31, 2020
Author(s)
Teresa T. Duncan, Joel M. Sarapas, Adrian P. Defante, Kathryn Beers, Edwin Chan
The fracture properties of very soft and/or brittle materials are challenging to measure directly due to the limitations of existing fracture testing methods. To address this issue, we introduce a razorblade-initiated fracture test (RIFT) to measure the

Niche partitioning of microbial communities at an ancient vitrified hillfort: implications for vitrified radioactive waste disposal

August 30, 2020
Author(s)
Andrew Plymale, Jacqueline Wells, Carolyn Pearce, Colin Brislawn, Emily Graham, Tanya Cheeke, Jessica Allen, Sarah Fansler, Bruce Arey, Mark Bowden, Danielle Saunders, Vincent Danna, Kimberly Tyrrell, Jamie Weaver, Rolf Sjoblom, Rick L. Paul, John McCloy, Eva Hjarthner-Holdar, Mia Englund, Erik Ogenhall, David Peeler, Albert Kruger
A pre-Viking era vitrified hillfort, Broborg, provides a habitat analogue for disposed radioactive waste glass and shows strong niche partitioning among the organisms involved in glass alteration. Microbes cannot be eliminated from radioactive waste

Thickness-Dependent Permeability of Molecular Layer-By-Layer Polyamide Membranes

August 28, 2020
Author(s)
William D. Mulhearn, Vladimir Oleshko, Christopher Stafford
We present the thickness-dependent permeability of highly crosslinked polyamide (PA) membranes formed by a molecular layer-by-layer (mLbL) deposition process. The deposition allows for the synthesis of extremely smooth, uniform PA films of tunable

Layering of Magnetic Nanoparticles at Amorphous Magnetic Templates with Perpendicular Anisotropy

August 26, 2020
Author(s)
Apurve Saini, Julie Borchers, Sebastian George, Brian B. Maranville, Kathryn L. Krycka, Joseph Dura, Katharina Theis-Brohl, Max Wolff
We reveal the assembly of monodisperse magnetite nanoparticles of sizes 5 nm, 15 nm and 25 nm from dilute water-based ferrofluids onto an amorphous magnetic template with out-ofplane anisotropy. From neutron reflectometry experiments we extract density

X-ray Scattering Studies of Reverse Osmosis Materials

August 25, 2020
Author(s)
Qinyi Fu, Nisha Verma, Benjamin S. Hsiao, Francisco J. Medellin-Rodriguez, Peter Beaucage, Christopher Stafford, Benjamin M. Ocko
Scarcity of freshwater is becoming a world crisis. In a recent annual risk report, the World Economic Forum lists it in their greatest global risk category. Currently, about four billion people live under conditions of severe water scarcity for at least

Structural and Dynamical Properties of Potassium Dodecahydro-Monocarba-Closo-Dodecaborate: KCB 11 H 12

August 20, 2020
Author(s)
Mirjana Dimitrievska, Hui Wu, Vitalie Stavila, Olga A. Babanova, Roman V. Skoryunov, Alexei V. Soloninin, Wei Zhou, Benjamin Trump
MCB 11H 12 (M: Li, Na) dodecahydro-monocarba-closo-dodecaborate salt compounds are known to have stellar superionic Li + and Na + conductivities in their high-temperature disordered phases, making them potentially appealing electrolytes in all-solid-state

Magnetic Properties of (Fe 1-x Mn x ) 2 AlB 2 and the Impact of Substitution on the Magnetocaloric Effect

August 6, 2020
Author(s)
D. Potashnikov, Elad Nisan NMN Caspi, A. Pesach, S. Kota, M. Sokol, L. A. Hanner, M. W. Barsoum, Hayden Evans, A. Eyal, A. Keren, O. Rivin
In this work, we investigate the magnetic structures of (Fe 1−xMn x) 2AlB 2 solid-solution quaternaries in the x = 0 to 1 range using X-ray and neutron diffraction, magnetization measurements, and mean field theory calculations. While Fe 2AlB 2 and Mn 2AlB

Early stage nucleation in barium disilicate glass

August 1, 2020
Author(s)
Ling Cai, Randall E. Youngman, David E. Baker, Aram Rezikyan, Minghui Zhang, Bryan Wheaton, Indrajit Dutta, Bruce G. Aitken, Andrew J. Allen
Early stage nucleation in silicate glasses is often evidenced by formation of nanosized regions that are stoichiometrically different from the surrounding matrix. The structural origin of these early stage nucleation sites is of great interest in gaining a

Effect of Molecular Weight and Layer Thickness on the Dielectric Breakdown Strength of Neat and Homopolymer Swollen Lamellar Block Copolymer Films

July 31, 2020
Author(s)
Saumil Samant, Monali Basutkar, Maninderjeet Singh, Ali Masud, Christopher A. Grabowski, Kim Kisslinger, Joseph Strzalka, Guangcui Yuan, Sushil K. Satija, Ikeoluwa Apata, Dharmaraj Raghavan, Michael Durstock, Alamgir Karim
Designing next generation light-weight pulsed power sources hinges on understanding the factors influencing the performance of high energy density storage materials. In prior work, we demonstrated the use of Cold Zone Annealing with Soft Shear (CZA-SS) as

Polymer Surface/Interface Consortium 2018 Workshop Report

July 29, 2020
Author(s)
Ronald S. Lankone, Li Piin Sung, David G. Goodwin, Andrew Fairbrother
The Polymer Surface/Interface (PSI) consortium held a two-day workshop at the National Institute of Standards and Technology (NIST) in Gaithersburg, MD on October 17th & 18th, 2018 titled, “The development of characterization tools, test methods, modeling

Cesium Substitution Disrupts Concerted Cation Dynamics in Formamidinium Hybrid Perovskites

July 28, 2020
Author(s)
Eve M. Mozur, Michael A. Hope, Julia C. Trowbridge, David M. Halat, Luke L. Daemen, Annalise E. Maughan, Timothy R Prisk, Clare P. Grey, James R. Neilson
While hybrid perovskites show great promise for photovoltaic applications, several of the most technologically relevant hybrid perovskites degrade rapidly when exposed to water, oxygen, or infrared and ultraviolet radiation. Empirical studies have shown

The Art in Science of MicroTAS 2019

July 28, 2020
Author(s)
Gregory A. Cooksey
The 2019 MicroTAS conference (the 23rd International Conference of Miniaturized Systems for Chemistry and Life Sciences) held in Basel, Switzerland, brought great opportunities to viewinspiring microscale compositions. Many of the best images were

Experimental and Theoretical Evidence of Hydrogen Doping in Solution Processed Indium Gallium Oxide via Polymer Incorporation

July 23, 2020
Author(s)
Wei Huang, Joshua Tedesco, Po-Hsiu Chien, Kyle McMillen, Li Zeng, Subhrangsu Mukherjee, Binghao Wang, Yao Chen, Gang Wang, Yang Wang, Yanshan Gao, Michael Bedzyk, Dean DeLongchamp, Julia E. Medvedeva, Yan-Yan Hu, Tobin Marks, Antonio Facchetti
Aqueous solution processed high performance indium gallium oxide (IGO) thin-film transistors (TFTs) are realized by the simple addition of a hydroxyl (C-OH) containing polymer [polyvinyl alcohol (PVA)] into an IGO precursor solution. The field-effect

Capillary RheoSANS: Measuring the Rheology and Nanostructure of Complex Fluids at High Shear Rates

July 15, 2020
Author(s)
Ryan P Murphy, Zachary W. Riedel, Marshall A. Nakatani, Paul Salipante, Javen S. Weston, Steven D. Hudson, Kathleen M Weigandt
Complex fluids containing micelles, proteins, polymers and inorganic nanoparticles are often processed and used in high shear environments that can lead to structural changes at the nanoscale. Here, capillary rheometery is combined with small-angle neutron

Scientific AI in Materials Science: a Path to a Sustainable and Scalable Paradigm

July 14, 2020
Author(s)
Brian L. DeCost, Jason R. Hattrick-Simpers, Zachary T. Trautt, Aaron G. Kusne, Martin L. Green, Eva Campo
Recent years have seen an ever-increasing trend in the use of machine learning (ML) and artificial intelligence (AI) methods by the materials science, condensed matter physics, and chemistry communities. This perspective article identifies key scientific

Charpy Instrumented Test Suite and User's Manual

July 9, 2020
Author(s)
Damian Lauria, Enrico Lucon, Felipe Baldner
The NIST Instrumented Charpy Test Suite is a set of standalone programs intended to allow anyone with appropriate hardware to perform and analyze instrumented Charpy impact tests. The software is provided in both raw code and executable formats with an
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