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Chemistry

Analytical chemistry

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Displaying 1151 - 1175 of 2094

Geographic Differences in Organic Contaminants and Stable Isotopes (d13C, d15N) in Thick-billed Murre (Uria lomvia) Eggs from Alaska

March 9, 2011
Author(s)
Stacy S. Schuur, Russell D. Day, Paul R. Becker, Rebecca S. Pugh, Michael B. Ellisor, Keith A. Hobson, David G. Roseneau
Thick-billed murre (Uria lomvia) eggs were collected from four Alaskan colonies in 2002. The contents were analyzed for organic contaminants and carbon (δ13C) and nitrogen (δ15N) stable isotopes. Contaminant concentrations in eggs varied from below

High Accuracy Measurements of OH Reaction Rate Constants and IR and UV Absorption Spectra: Ethanol and Partially Fluorinated Ethyl Alcohols.

March 4, 2011
Author(s)
Vladimir L. Orkin, Victor Khamaganov, Larissa E. Martynova, Michael J. Kurylo III
Rate constants for the gas phase reactions of OH radicals with ethanol and three fluorinated ethyl alcohols, CH3CH2OH (k0), CH2FCH2OH (k1), CHF2CH2OH (k2), and CF3CH2OH (k3) were measured using a flash photolysis resonance-fluorescence technique over the

Comparison of the Sensitivity and Image Contrast in Spontaneous Raman and Coherent Stokes Raman Scattering Microscopy of Geometry Controlled Samples

February 9, 2011
Author(s)
Hyun M. Kim, Chris A. Michaels, Garnett W. Bryant, Stephan J. Stranick
We experimentally compare the performance and contrast differences between spontaneous and coherent Stokes Raman scattering microscopy. We demonstrate the differences on a series of geometry controlled samples that range in complexity from a point (array

Passive Intermodulation due to Self-Heating in Printed Transmission Lines*

February 2, 2011
Author(s)
Eduard Rocas, Juan C. Collado Gomez, Nathan D. Orloff, Jordi Mateu, James C. Booth, Juan M. O'Callaghan, Alberto Padilla
Abstract—This article proposes a mechanism by which third-order intermodulation distortion due to self-heating is generated in transmission lines. The work shows how transmission lines made of several materials whose properties are independent of the

Approximate theoretical model for the five electronic states (? = 5/2, 3/2, 3/2, 1/2, 1/2) arising from the ground 3d9 configuration in nickel halide molecules and for the rotational levels of the two ? = 1/2 states in this manifold

January 25, 2011
Author(s)
Jon T. Hougen
This paper is divided into two parts. In the first part an effective Hamiltonian for a non-rotating diatomic molecule containing only crystal-field and spin-orbit operators is set up to describe the energies of the five spin-orbit components that arise in

Influence of substrate on crystallization in polythiophene/fullerene blends

January 13, 2011
Author(s)
Lee J. Richter, Christine He, David Germack, R Joseph Kline, Dean DeLongchamp, Daniel A. Fischer, Chad R. Snyder, James G. Kushmerick
The nanoscale morphology of the active layer in organic, bulk heterojunction (BHJ) solar cells is crucial to device performance. Often a combination of casting conditions and post deposition thermal treatment are used to optimize the morphology. In general

Quantification of cholesterol-metabolizing P450s CYP27A1 and CYP46A1 in neural tissues reveals a lack of enzyme-product correlations in human retina but not human brain

January 7, 2011
Author(s)
Wei-Li Liao, Gun-Young Heo, Nathan G. Dodder, Rachel Reem, Natalia Mast, Suber Huang, Pier L. DiPatre, Illarion Turko, Irina A. Pikuleva
Improper cholesterol metabolism in the brain causes neurological diseases. Factors affecting cholesterol homeostasis includes cholesterol hydroxylation reactions, which are regulated by cytochrome P450 enzymes. One approach to estimate the total enzymatic

Performance of a coherent dual frequency comb spectrometer

January 1, 2011
Author(s)
Nathan R. Newbury, Esther Baumann, Ian R. Coddington, Fabrizio R. Giorgetta, William C. Swann, Alexander M. Zolot
We discuss the performance of a coherent dual frequency comb spectrometer in terms of signal-to-noise ratio, resolution, and accuracy based on experimental data in the near and short-wave infrared centered at 1.5 and 3.4 micrometers.
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