Stromberg, C.
and Heilweil, E.
(2011),
Terahertz, Infrared and Raman Vibrational Assignments of [FeFe]-Hydrogenase Model Compounds, Journal of Molecular Spectroscopy, [online], https://doi.org/10.1016/j.vibspec.2011.02.012
(Accessed October 9, 2024)
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Terahertz, Infrared and Raman Vibrational Assignments of [FeFe]-Hydrogenase Model Compounds
Published
Author(s)
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Abstract
Using Raman, Terahertz (THz), and mid-Infrared (IR) spectroscopies, the vibrational spectra of two chromophore models of hydrogen-producing [FeFe]-hydrogenase, Fe2(μ-S2C3H6)(CO)6 and Fe2(μ-S2C2H4)(CO)6, have been assigned. The combination of absorption and scattering techniques, along with DFT calculations, allows for assignments to be made without traditional isotopic substitution methods.Citation
Journal of Molecular Spectroscopy
Volume
56 (2011)
Pub Type
Journals
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Keywords
Hydrogenase, Infrared spectrum, Raman spectrum, Terahertz spectrum, Vibrational assignments
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Created March 2, 2011, Updated October 12, 2021