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This chapter reviews calibration techniques relevant to aerosol measurement devices, such as sizing instruments, condensation nuclei counters, and mass monitors. The generation methods for test aerosols and important parameters in instrument calibration
Laura J. Wood, Katherine E. Sharpless, Monique Pichon, Barbara J. Porter, James H. Yen
The National Institute of Standards and Technology (NIST) has been working with the National Institutes of Health Office of Dietary Supplements to produce Standard Reference Materials (SRMs) of interest to analysts of dietary supplements. Some of these
A procedure is described for assigning values of the number of equivalent reference fluorophores (ERF) to microspheres labeled with a fluorophore designed to produce fluorescence in a given channel of a multicolor flow cytometer. There is a different
Vytautas Reipa, Jonghoon Choi, Nam S. Wang, Victoria M. Hitchins, Peter L. Goering, Robert Malinauskas
In anticipation of the increased use of various forms of silver as an antimicrobial agent in medical devices, the objective of this study was to evaluate the in vitro hemolytic potential of silver nanoparticles in dilute human blood, and to relate particle
Methods for determination of sulfur by activation analysis are discussed. The discussion includes descriptions of procedures, sources of uncertainties and detection limits. Methods discussed include instrumental and radiochemical neutron activation
William R. Kelly, Kenneth W. Pratt, William F. Guthrie, Keith R. Martin
The Method of Standard Additions or the Standard Addition Method, often referred by its acronym as just SAM, is now a proverbial workhorse in both inorganic and organic quantitative analytical chemistry and in related disciplines such as geochemistry. Its
John R. Kucklick, Lori Schwacke, Randall S. Wells, Aleta Hohn, Aurore Guichard, Jennifer Yordy, Larry Hansen, Eric Zolman, Rachel Wilson, J. L. Litz, Doug Nowacek, Teresa Rowles, Rebecca S. Pugh, Brian C. Balmer, Carrie Sinclair, Patricia Rosel
Persistent organic pollutants (POPs) including legacy POPs (PCBs, chlordanes, mirex, DDTs, HCB, and dieldrin) and polybrominated diphenyl ether (PBDE) flame retardants were determined in 300 blubber biopsy samples from coastal and near shore/estuarine male
Joseph T. Hodges, David A. Long, Mitchio Okumura, Charles E. Miller
Carbon dioxide (CO2) isotopic ratios were measured at 1.6 μm through the use of frequency-stabilized cavity ring-down spectroscopy (FS-CRDS). We report the highest spectrum signal-to-noise ratios to date for CO2 transitions, with values as high as 28,000:1
Interest in the domestic production of all fuels, sparked by the high cost of petroleum crude oil, has led to consideration of fluids to replace or extend conventional petroleum-derived fuels. There is particular interest in formulating oxygenated diesel
Thomas J. Bruno, Tara Lovestead, Jennifer Riggs, Erica Jorgensen, Marcia L. Huber
There is a great deal of interest in formulating oxygenated diesel fuels that produce low particulate emissions. The most common oxygenating additives for diesel fuels include the glycol ethers, glycol esters, alcohols, ethers and ketones. It is important
Thomas J. Bruno, Tara M. Lovestead, Marcia L. Huber, Jennifer Riggs
There is a great deal of interest in formulating oxygenated diesel fuels that produce low particulate emissions. The most common oxygenating additives for diesel fuels include the glycol ethers, glycol esters, alcohols, ethers and ketones. It is important
In this brief paper we describe a simple apparatus that can produce sufficient quantities of thermally stressed complex fluids (such as fuels) to allow a full range of thermophysical property measurements to be performed on the resulting fluid. The
Kevin O. Knabe, Paul A. Williams, Nathan R. Newbury
We evaluate the signal-to-noise ratio penalty for dual comb spectroscopy caused by the excess optical phase noise and relative intensity noise on the long-wavelength supercontinuum of a spectrally broadened Er-fiber laser frequency comb.
We have recently introduced several important improvements in the measurement of distillation curves for complex fluids. The modifications include a composition explicit data channel for each distillate fraction and temperature measurements that are true
Terrence J. Jach, Fernando D. Vila, W. T. Elam, J. D. Denlinger, John J. Rehr
Non-resonant x-ray emission spectroscopy was used to compare the nitrogen-rich compounds ammonium nitrate, trinitrotoluene, and cyclotrimethylene-trinitramine. They are representative of crystalline and molecular structures of special importance in
Stephen A. Montzka, S. Reimannander, Andreas Engel, Kirstin Kruger, O?Doherty Simon, William T. Sturges , Donald R. Blake , Marcel Dorf Dorf, Paul J. Fraser , Lucien Froidevaux , Kenneth Jucks, Karin Kreher, Michael J. Kurylo III, Abdelwahid Mellouki , John Miller , Ole J. Nielsen , Vladimir L. Orkin, Ronald G. Prinn , Robert Rhew , Michelle L. Santee , Andreas Stohl , Daniel P. Verdonik
The present document will be part of the information upon which the Parties to the United Nations Montreal Protocol will base their future decisions regarding protection of the stratospheric ozone layer. OVERVIEW It has been recognized since the 1970s that
Mingdong M. Li, Suvajyoti S. Guha, Rebecca A. Zangmeister, Michael J. Tarlov, Michael R. Zachariah
Electrospray (ES) sources are commonly used to introduce non-volatile materials (e.g. nanoparticles, proteins, etc.) in to the gas phase for characterization by mass spectrometry and ion mobility. Recent studies in our group using electrospray ion mobility
Lee L. Yu, Carl Verdon, William C. Davis, Gregory C. Turk, Kathleen Caldwell, Robert Jones, Brian Buckley, Ruimin Xie
Arsenic is a toxic element, and the toxicity of the element is dependent upon the molecular form it is in. Accurate assessments of arsenic exposure require the measurement of a complete panel of inorganic, organic, and metabolite As species in urine
Bret Windom, Tara Lovestead, Mark Mascal, Edward Nikitin, Thomas J. Bruno
Diminishing petroleum reserves, the potential of supply disruptions, price volatility, as well as environmental considerations resulting from polluting emissions, have led to development of alternative liquid fuels and fuel additives produced from
Paul C. DeRose, Melody V. Smith, Klaus Mielenz, Jeffrey R. Anderson, Gary W. Kramer
Standard Reference Material (SRM) 2942 is a cuvette-shaped, Ce-ion-doped glass, recommended for use for relative spectral correction of emission and day-to-day performance verification of steady-state fluorescence spectrometers. Properties of this standard
Triphenylphosphine (PPh3) is commonly used during syntheses of stable closed-shell monolayer protected clusters (MPCs). Models of transition metal (TM) cluster and nanoparticle syntheses commonly assign PPh3 a passive role as a chemical placeholder