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Chemistry

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Displaying 301 - 325 of 1920

Tailoring electrode-electrolyte-interfaces in lithium-ion batteries using molecularly engineered functional polymers

February 22, 2021
Author(s)
Laisuo Su, Jamie Weaver, Mitchell C. Groenenboom, Nathan Nakamura, Eric Rus, Priyanka Anand, Shikhar Krishn Jha, Joseph Okasinski, Joseph Dura, B Reeja-Jayan
Electrode−electrolyte interfaces (EEIs) affect the rate capability, cycling stability, and thermal safety of lithium-ion batteries (LIBs). Designing stable EEIs with fast Li+ transport is crucial for developing advanced LIBs. Here, we study Li+ kinetics at

National Institute of Standards and Technology Environmental Scan 2020

February 9, 2021
Author(s)
Heather Evans, Kristen K. Greene, William M. Healy, Elizabeth Hoffman, Kate Rimmer, Anna V. Sberegaeva, Neil M. Zimmerman
The 2020 National Institute of Standards and Technology Environmental Scan provides an analysis of key external factors that could impact NIST and the fulfillment of its mission in coming years. The analyses were conducted through four separate lenses

Quantitative Analysis of Zirconium Alloys Using Borate Fusion and Wavelength Dispersive X-Ray Fluorescence Spectrometry

January 26, 2021
Author(s)
John R. Sieber, Anthony F. Marlow, Rick L. Paul, Charles A. Barber, Laura J. Wood, Lee L. Yu, Alaina Rieke, Amy Kutnerian, Jessica McCandless, Candace Wallace
The National Institute of Standards and Technology (NIST) uses borate fusion, wavelength dispersive X-ray fluorescence (WDXRF) spectrometry and synthetic calibration standards for high performance, quantitative analyses of a wide range of materials

Structural resolution and mechanistic insight into hydrogen adsorption in flexible ZIF-7

January 1, 2021
Author(s)
Ryan Klein, Sarah Shulda, Philip Parilla, Pierre Le Maqueres, Rachelle Richardson, William Morris, Craig Brown, C. Michael McGuirk
Flexible metal–organic frameworks offer a route towards high useable hydrogen storage capacities with minimal swings in pressure and temperature via step-shaped adsorption and desorption profiles. Yet, the understanding of hydrogen-induced flexibility in

Production and Analysis of RM 8403 Cocoa Flavanol Extract

October 23, 2020
Author(s)
Catherine A. Rimmer, Katrice A. Lippa, James H. Yen, Ugo Bussy, Gregory Hewitt, Nicholas P. Anderson, Catherine Kwik-Uribe
NIST Reference Material 8403 is intended for use in harmonizing methods for the determination of cocoa flavanols monomers and their oligomers up to a degree of polymerization (DP) of 7 units. RM 8403 is a free-flowing powder containing cocoa flavanols

Semiconducting to Metallic Electronic Landscapes in Defects Controlled Two-Dimensional ?-d Conjugated Coordination Polymer Thin Films

October 16, 2020
Author(s)
Cherno Jaye, Daniel Fischer, Jonathan Ogle, Nabajit Lahiri, Christopher Tassone, Janis Louie, Luisa Whittaker-Brooks
Two-dimensional coordination polymers (2D CPs) are of significant interest due to their intriguing structural, optical, and electrical properties which can be tuned through the selective coordination of different metals and organic linkers. Although, 2D

High-density polyethylene - an inert additive with stabilizing effects on organic field-effect transistors

September 11, 2020
Author(s)
Alberto Scaccabarozzi, James Basham, Liyang Yu, Paul Westcott, Weimin Zhang, Aram Amassian, Iain McCulloch, Mario Caironi, David J. Gundlach, Natalie Stingelin
Organic electronics technologies have attracted considerable interest over the last decades and have become promising alternatives to conventional, inorganic platforms for specific applications. To fully exploit the touted potential of plastic electronics

Early stage nucleation in barium disilicate glass

August 1, 2020
Author(s)
Ling Cai, Randall E. Youngman, David E. Baker, Aram Rezikyan, Minghui Zhang, Bryan Wheaton, Indrajit Dutta, Bruce G. Aitken, Andrew J. Allen
Early stage nucleation in silicate glasses is often evidenced by formation of nanosized regions that are stoichiometrically different from the surrounding matrix. The structural origin of these early stage nucleation sites is of great interest in gaining a

Reversible Room-Temperature Fluoride-Ion Insertion in a Tunnel-Structured Transition Metal Oxide Host

July 6, 2020
Author(s)
Cherno Jaye, Wasif Zaheer, Justin L. Andrews, Forrest P. Hyler, Conan Weiland, David A. Shapiro, Jinghua Guo, Jesus M. Velazquez, Sarbajit Banerjee, Abhishek Parija, Daniel Fischer
An energy storage paradigm orthogonal to conventional Li-ion battery chemistries can be conceptualized by employing anions as the primary charge carriers. F-ion conversion chemistries show promise but have limited cyclability as a result of the significant

IFCC working group recommendations for correction of bias caused by non-commutability of a certified reference material used in the calibration hierarchy of an end-user measurement procedure

June 1, 2020
Author(s)
Johanna Camara, W. Greg Miller, Jeffrey R. Budd, Neil Greenberg, Weykamp Cas, Harald Althaus, Heinz Schimmel, Mauro Panteghini, Vincent Delatour, Ferruccio Ceriotti, Thomas Keller, Douglas Hawkins, Robert Rej, Finlay MacKenzie, Elina van der Hagen, Hubert W. Vesper
Establishing metrological traceability to a matrix-based certified reference material (CRM) that has been validated to be commutable among a group of measurement procedures (MPs) is central to producing equivalent results for a measurand in clinical

Quasi-elastic Neutron Scattering Measurement of Hydrogen Diffusion in a Graphene Oxide Framework

April 16, 2020
Author(s)
Matthew J. Connolly, Z. N. Buck, Carlos Wexler, Joseph C. Schaeperkoetter, H. Taub, Andrew Gillespie, Helmut Kaiser
We present quasielastic neutron scattering (QENS) spectra from molecular hydrogen adsorbed in GOF. The measurements probed the motion of adsorbed hydrogen as a function of pressure, in order to understand the relationship between the motion of adsorbed
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