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Brian R. Lawn, Antonia Pajares, Yu Zhang, Y N. Deng, M Polack, Isabel K. Lloyd, E D. Rekow, Victoria Thompson
Results from a systematic study of damage in material structures representing the basic elements of dental crowns are reported. Tests are made on model flat-layer specimens fabricated from various dental ceramic combinations bonded to dentin-like polymer
Sheng Lin-Gibson, H W. Kim, G Schmidt, Charles C. Han, Erik K. Hobbie
Abstract: The equilibrium structure and shear response of model polymer-clay nanocomposite gels are measured using X-ray scattering, light scattering, optical microscopy, and rheometry. The suspensions form physical gels via the bridging of neighboring
Vytautas Reipa, Marcia J. Holden, M P. Mayhew, V L. Vilker
Putidaredoxin (Pdx) is an 11,400 Da iron-sulfur protein that sequentially transfers two electrons to the cytochrome P450cam during the enzymatic cycle of the stereo specific camphor hydroxylation. We report two transitions in the Pdx UV-VIS absorption and
Joy P. Dunkers, Marcus T. Cicerone, James Cooper, Forrest A. Landis, N Washburn
We present a novel application of optical coherence microscopy (OCM) by combining it with confocal fluorescence microscopy (CFM) to gather simultaneous structural and functional information on tissue engineered medical products (TEMPs) in a registered
In prvious publications, we described a technique based on fluorescence spectrocopy to monitor resin temperature during processing. The method consists of using optical fiber sensors to monitor fluorescence from a fluorescent dye that has been doped into
Aaron M. Forster, A Chiche, Martin Chiang, Christopher Stafford, Alamgir Karim
High-throughput and combinatorial methods unlock novel approaches to investigations of new materials, allowing the materials community to carry out studies that promise greater efficiency to materials discovery and optimization. To this end, we have
Marcus T. Cicerone, Joy Dunkers, N. R. Washburn, Forrest A. Landis, James A. Cooper
Tissue scaffold morphological properties are determined and correlated with osteoblast proliferation and ingrowth. Scaffold pore size and connectivity were characterized with x-ray tomography. Cell proliferation and ingrowth were measured with confocal
Three polymers of differing thermal stability, polystyrene (PS), polyethylene glycol (PEG), and polypropylene glycol (PPG) were studied by matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) as the electro-spray deposition voltage was
Advanced ceramics are increasingly being used for wear applications. The strength and fatigue resistance of ceramics have increased several fold in the last decade. Wear prediction of ceramics has become an important subject in these arenas. Ceramic wear
D J. Burnett, A M. Gabelnick, A T. Capitano, Daniel A. Fischer, J L. Gland
In-situ oxidation experiments in oxygen pressures up to 1.3 Pa indicate that the 140 K carbon monoxide oxidation process is self-limiting. This experimental data suggests that adsorbed atomic oxygen may be responsible for limiting the extent of reaction
Joy P. Dunkers, Forrest A. Landis, K Niihara, Hiropshi Jinai
It has been shown that scaffold microstructure impacts cell response.1 Determining the relationship between scaffold structure and cellular response facilitates scaffold design. Some descriptors of scaffold morphology thought to be influential are pore
D J. Burnett, A M. Gabelnick, A L. Marsh, H D. Lewis, S M. Yalisove, Daniel A. Fischer, J L. Gland
rbon monoxide oxidation experiments were performed on a well-characterized supported platinum thin film using in-situ x-raytechniques and temperature-programmed reaction spectroscopy (TPRS) experiments over the 100 to 1000 K temperature range andhigh
Using an optical sensor, fluorescence anisotropy and fluorescence temperature measurements were carried out during the processing of biaxially stretched polypropylene films in a tenter. The fluorescence derived from a dye that was doped into the resin
We examine Gibbs' conditions for equilibrium of a non-hydrostatically stressed single component solid in equilibrium across one of its faces with a pure liquid at pressure p(superscriptF). We show that the equilibrium melting temperature T(subscriptN) for
D J. Burnett, A M. Gabelnick, A L. Marsh, Daniel A. Fischer, J L. Gland
Propyne and propylene oxidation have been studied on a 1 0 nm Pt/A 1 20 3 thin film catalyst using a combination of synchrotron basedsoft x-ray techniques for oxygen pressures up to 1.3 Pa. In-situ temperature-programmed and isothermal kinetic experiments
Aaron M. Forster, Christopher Stafford, Alamgir Karim
The NIST Combinatorial Methods Center (NCMC) has adapted the Johnson Kendall, and Roberts (JKR) adhesive contact test for the development of a high-throughput adhesion measurement platform. This technique utilizes an array of hemispherical lenses to
The strengths of fine microstructural scale yttria stabilized rectangular bars and circular disks were measured by four-point flexure and by flat ball (piston) on three ball methods. Fracture mirror sizes were measured and correlated to the strengths
Sheldon M. Wiederhorn, A R D Lopez, William E. Luecke, Michael J. Hoffmann, B Hockey, J French, D C. Yoon
The effect of grain size on the tensile creep of silicon nitride is investigated on two materials, one containing 5 % by volume Yb2O3, the other containing 5 % by volume Yb203 and 0.5 % by mass Al2O3. Annealing of the alumina-free silicon nitride increased
A layered preparation method is introduced that produces structured MALDI targets with well-defined phase sizes and compositions. Tri-a-naphthyl benzene is a glassy matrix that forms smooth films. It is layered with polystyrenes or polyethylene glycol
The propagation behavior (subcritical crack growth) of machining induced cracks in silicon nitride was investigated by conducting constant stress (CS) and constant stress rate (CSR) tests. A dye impregnation technique that forces a palladium nitrate
Ying Mei, Kathryn L. Beers, H M. Byrd, David L. VanderHart, N. R. Washburn
A versatile methodology for preparing hybrid biomaterials by atom transfer radical polymerization from resin-supported peptides has been established. As an example, we have synthesized a GRGDS-functionalized poly(2-hydroxyethyl methacrylate). The peptide
A Kulkarni, J Gutleber, S Sampath, A N. Goland, W B. Lindquist, H Herman, Andrew J. Allen, B A. Dowdy
High-velocity oxygen-fuel (HVOF) spraying stands out among the various processes to improve metal and ceramic coating density and surface characteristics. This paper explores microstructure development, coating characterization and properties of HVOF