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Search Publications by: Christopher Soles (Fed)

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Displaying 1 - 25 of 174

PMSE Centennial: Celebration of Success and New Frontiers in Polymer Materials Science and Engineering

September 18, 2025
Author(s)
Mellissa Grunlan, LaShanda Korely, Qinghuang Lin, Christopher Soles, Rigorberto Advincula, Arthi Jayaraman, Elizabeth Cosgriff-Hernandez, Elsa Reichmanis, Jodie Lutkenhaus, Rodney Priestly, Bridgitte Voit, Thomas Epps
In 2024, the American Chemical Society (ACS) Division of Polymeric Materials: Science and Engineering (PMSE) marked celebrated its centennial. This historic occasion was marked at the 2024 Spring ACS Meeting in New Orleans with a Centennial Symposium

Material Needs and Measurement Challenges for Advanced Semiconductor Packaging: Understanding the Soft Side of Science

August 27, 2025
Author(s)
Ran Tao, Polette Centellas, Stian Romberg, Anthony Kotula, Gale Holmes, Amanda Forster, Christopher Soles, Bob Allen, Edvin Cetegen, William Chen, Jeff Gotro, Mark Poliks
This perspective builds upon insights from the National Institute of Standards and Technology (NIST)-organized workshop, "Materials and Metrology Needs for Advanced Semiconductor Packaging Strategies," held at the 35th annual Electronics Packaging

Advanced Metrology Suite for Linking Residual Stress to Fundamental Properties of Thermoset Packaging Materials

June 26, 2025
Author(s)
Polette Centellas, Stian Romberg, Ran Tao, Alexander Landauer, Karl Schoch, Huong Giang Nguyen, Gale Holmes, Gery Stafford, Christopher Soles
Residual stresses inevitably develop in thermosetting materials used for semiconductor packaging during the curing process and in service. Understanding the development of these deleterious stresses is necessary for improving predictive models and

Controlling Impact Mitigation via Stimuli-Responsive Bouligand Nanostructures

May 16, 2025
Author(s)
Sujin Lee, Katherine Evans, Jeremiah Woodcock, Jan Obrzut, Liping Huang, Christopher Soles, Edwin Chan
Critical to their survival, natural organisms have developed exoskeletons that can withstand and inflict damage over their lifetime. The Bouligand structure of the exoskeleton plays a key role in toughness and damage resistance under external impacts

Visualizing Shockwave Interactions and Sub-Catastrophic Damage in Materials via Mechanophores

October 7, 2024
Author(s)
Polette Centellas, Kyle Mehringer, Andrew Bowman, Katherine Evans, Parth Vagholkar, Travis Thornell, Liping Huang, Sarah Morgan, Christopher Soles, Yoan Simon, Edwin Chan
Understanding the physical and chemical response of materials to impulsive deformation is crucial for applications ranging from soft robotic locomotion to space exploration to seismology. However, investigating material properties at extreme strain rates

Measuring the Influence of CO2 and Water Vapor on the Dynamics in Polyethylenimine To Understand the Direct Air Capture of CO2 from the Environment

June 5, 2024
Author(s)
Avery Baumann, Takeshi Yamada, Kanae Ito, Chad R. Snyder, John Hoffman, Craig Brown, Christopher Stafford, Christopher Soles
Aminopolymer sorbents are leading candidates for extracting CO2 directly from the atmosphere under ambient conditions. For effective carbon capture, this requires not only that the CO2 actively binds with amine groups of the polymer under low gas

Dealloyed Pt74Ni26 and Pt26Ni74 Electrodeposited Thin Film Electrocatalysts for Oxygen Reduction

May 30, 2024
Author(s)
Carlos Hangarter, Eric Rus, Yihua Liu, Jaw Wook Shin, Vladimir Oleshko, Hyun Wook Ro, Russell Composto, Christopher Soles, Joseph A. Dura, Gery R. Stafford, Leonid Bendersky, Thomas P. Moffat
Pt100-xNix alloys are among the most active binary alloys for electrocatalysis of the oxygen reduction reaction (ORR) in PEM fuel cells. Electrodeposition and microstructure of thin films close to Pt75Ni25 and Pt25Ni75 stoichiometry are described and their

An autonomous design algorithm to experimentally realize three-dimensionally isotropic auxetic network structures without compromising density

May 29, 2024
Author(s)
Meng Shen, Marcos Reyes-Martinez, Ami Ahure Powell, Mark Iadicola, Abhishek Sharma, Fabian Bylehn, Nidhi Pashine, Edwin P. Chan, Christopher Soles, Heinrich Jaeger, Juan de Pablo
Auxetic materials have a negative Poisson's ratio and are of significant interest in applications that include impact mitigation, membrane separations and biomedical engineering. While there are numerous examples of structured materials that exhibit

Assessing Composite Structure in Metal-Organic Framework-Polymer Mixed-Matrix Membranes

March 15, 2024
Author(s)
Avery Baumann, Peter Beaucage, Richard Vallery, David Gidley, Ryan Nieuwendaal, Chad R. Snyder, Jan Ilavsky, Fu Chen, Christopher Stafford, Christopher Soles
Metal-organic frameworks (MOFs) are renowned for their tunable structure, porosity, and internal chemistry with demonstrated applications in molecular separations, storage, and conversion. While they are widely usable, the powdery characteristics of MOF

Topology as a limiting factor in mechanical properties for disordered networks

March 5, 2024
Author(s)
Marcos Reyes-Martinez, Edward Barron III, Dohgyu Hwang, Christopher Soles, Michael Bartlett, Edwin Chan
Disordered networks are ubiquitous in both the natural and synthetic worlds. Depending on the application, some are extremely soft while others are rigid. However, how network topology and intrinsic material properties combine to control deformation and

Scaling the Projectile Perforation Resistance of Soft Materials

June 29, 2023
Author(s)
Katherine Evans, Shawn Chen, Amanda Souna, Stephan J. Stranick, Christopher Soles, Edwin P. Chan
From space dust to ballistic impact, controlling or mitigating a high velocity projectile impact event is a desirable outcome. The design and development of new and novel impact mitigating materials are greatly hindered by the use of macroscale projectile

Correlating the Diffusion of Water in Model Polyamides with Controlled Crosslink Densities to the Performance in Reverse Osmosis Membranes for Desalination

April 18, 2023
Author(s)
Velencia Witherspoon, Kanae Ito, Chad R. Snyder, Madhusudan (Madhu) Tyagi, Tyler Martin, Peter Beaucage, Ryan Nieuwendaal, Richard Vallery, David Gidley, Jeffrey Wilbur, Dean Welsh, Christopher Stafford, Christopher Soles
To elucidate robust design cues for improving the active polyamide (PA) filtration layers in reverse osmosis (RO) membrane for desalination, we systematically reduce the cross-link density of a PA network based on m-phenylene diamine by substituting a

Relative effects of polymer composition and sample preparation on glass dynamics

August 17, 2022
Author(s)
Christopher Soles, Amanda L. Forster, Katherine Evans, Madhusudan (Madhu) Tyagi, Robert M. Elder, Timothy Sirk, Joseph Dennis, Kanae Ito, Osama Yamamuro, Hiroshi Akiba
Modern design of common adhesives, composites and polymeric parts makes use of polymer glasses that are stiff enough to maintain their shape under a high stress while still maintaining a ductile behavior after the yield point. Typically, material

Pruning the Mechanical Impedance of Three-Dimensional Disordered Networks

February 21, 2022
Author(s)
Marcos Reyes-Martinez, Edwin Chan, Christopher Soles, Michael Riley, Endao Han, Nidhi Pashine, Kieran Murphy, Heinrich Jaeger, Sidney Nagel, Daniel Reid, Meng Shen, Juan J. de Pablo
Disordered networks, comprised of random arrangements of bonds and nodes, have emerged as materials with the unique ability for independent control over the shear and bulk moduli. Recent computational studies have demonstrated that an extremely high degree

Additive-Containing Rinses for LER and Defectivity Control During High-Resolution Resist Patterning

October 12, 2021
Author(s)
D L. Goldfarb, S D. Burns, M Angelopolous, S Skordas, R L. Burns, M C. Lawson, C J. Brodsky, V Vishnu, E Jablonski, Vivek Prabhu, Ronald L. Jones, B D. Vogt, Christopher Soles, Eric K. Lin, Wen-Li Wu
The addition of a surface conditioning agent to the de-ionized water rinse used to quench the photoresist development process is an attractive methodology that can afford a controlled decrease in resist line edge roughness (LER) or a reduction in

Chemically Amplified Photoresists Fundamental Properties and Limits of Applicability to Sub-100 nm Lithography

October 12, 2021
Author(s)
D M. Goldfarb, Eric K. Lin, Christopher Soles, B C. Trinque, S D. Burns, Ronald L. Jones, Joseph~undefined~undefined~undefined~undefined~undefined Lenhart, M Angelopoulos, C G. Wilson, Sushil K. Satija, Wen-Li Wu
State-of-the-art lithographic technologies combine chemically amplified photoresists and sophisticated radiation sources to delineate patterned areas with high spatial resolution, enabling the fabrication of continually decreasing feature sizes in the

Why Polymer Glasses with Enhanced Sub-nanosecond Relaxation are Tougher

February 12, 2021
Author(s)
Christopher Soles, Adam B. Burns, Kanae N. Ito, Jack Douglas, Robert Dimeo, Madhu Sudan Tyagi, Jingsheng Wu, Albert F. Yee, Yueh-Ting Shih, Liping Huang
This manuscript explores the connection between the fast relaxation processes in a polymer glass and essential trends in the mechanical toughness, a non-linear mechanical property that is of practical interest for engineering polymers with high impact

Importance of Sub-Nanosecond Fluctuations on the Toughness of Polycarbonate Glasses

July 23, 2020
Author(s)
Christopher L. Soles, Kanae N. Ito, Adam B. Burns, Edwin P. Chan, Robert M. Dimeo, Madhu Sudan Tyagi, Albert F. Yee, Jianwei Liu
This article explores the relationship between the nano- to picosecond dynamics, as quantified by elastic incoherent neutron scattering, in polycarbonate (PC) glasses with their mechanical toughness. We establish a robust correlation between mechanical

Using Microprojectiles to Study the Ballistic Limit of Polymer Thin Films

April 1, 2020
Author(s)
Shawn H. Chen, Amanda J. Souna, Christopher L. Soles, Stephan J. Stranick, Edwin P. Chan
The dynamic impact between a particle and a planar material is important in many high impact events, andthereisagrowingneedtocharacterizethemechanicalpropertiesoflight-weightpolymeric materials at dynamic loading conditions. Here, a laser-induced

Insights into the Water Transport Mechanism in Polymeric Membranes from Neutron Scattering

February 5, 2020
Author(s)
Edwin P. Chan, Bradley R. Frieberg, Jacob Daniel Tarver, Madhusudan Tyagi, WenXu Zhnag, Bryan Coughlin, Christopher M. Stafford, Abhishek Roy, Steve Rosenberg, Christopher L. Soles
Polymeric membranes are ubiquitous in a number of transport ap- plications including gas separation, water desalination, solid state batteries and fuel cells. The permeability and selectivity of these membranes are intimately linked to the structure and

Chain and Ion Dynamics in Precise Polyethylene Ionomers

October 11, 2019
Author(s)
Christopher L. Soles, Amalie Frischknecht, Benjamin Paren, Robert Middleton, Karen Winey, Jason Koski, Madhu Sudan Tyagi, Jacob Daniel Tarver
We analyze the dynamics from microsecond-long, atomistic molecular dynamics (MD) simulations of a series of precise poly(ethylene-co-acrylic acid) ionomers neutralized with lithium, with three different spacer lengths between acid groups on the ionomers

Engineered Sulfur-MoS2-Graphene Heterostructure Cathodes for Diagnostics of Nanoscale Electrochemical Processes in High Energy Density Li-S Batteries

August 5, 2019
Author(s)
Vladimir P. Oleshko, William R. McGehee, Saya Takeuchi, Siyuan Zhang, Andrei A. Kolmakov, Jabez J. McClelland, Christopher L. Soles
Lithium-sulfur (Li-S) batteries have recently attracted enormous attention because of high theoretical specific energy (2600 Wh kg-1) and high specific capacity (1672 mAhg-1), as well as the low cost, natural abundance, and nontoxicity of elemental sulfur

Direct-write Lithiation of Silicon Using a Focused Ion Beam of Li+

July 8, 2019
Author(s)
William R. McGehee, Evgheni Strelcov, Vladimir P. Oleshko, Christopher L. Soles, Nikolai B. Zhitenev, Jabez J. McClelland
Electrochemical processes that govern the performance of lithium ion batteries involve numerous parallel reactions and interfacial phenomena that complicate the microscopic understanding of these systems. As a new way to study the behavior of ion transport
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