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Displaying 26 - 50 of 88

Radiolytic Dechlorination of Polychlorinated Biphenyls in Transformer Oil and in Marine Sediment

November 1, 2002
Author(s)
M Chaychian, C A. Jones, Dianne L. Poster, Joseph Silverman, Pedatsur Neta, Robert E. Huie, M I. Al-Sheikhly
Radiolytic dechlorination of PCBs in transformer oil and in marine sediments has been studied. At low PCB concentrations, complete degradation of the PCBs in transformer oil was achieved without degradation of the oil. Addition of an organic base

Temperature Dependence of the Acid Dissociation Constant of the Hydroxyl Radical

November 1, 2002
Author(s)
G A. Poskrebyshev, Pedatsur Neta, Robert E. Huie
The acid dissociation constant of the hydroxyl radical in aqueous solution was determined by pulse radiolysis from the pH dependence of the rate constant for reaction of the OH/O - radical with benzoate ions. The rate constant and the pKa( OH) values were

Reaction Kinetics of 2-Propanol Dehydration in Supercritical Water

March 1, 2002
Author(s)
V I. Anikeev, A Ermakova, Jeffrey A. Manion, Robert E. Huie
A study of the kinetics and mechanism of chemical reactions in supercritical fluids is considered. An experimental procedure was proposed for examining reversible chemical reactions in supercritical water. The reaction kinetics of 2-propanol dehydration in

Commemorative Issue for Prof. Simon H. Bauer II: Editorial Comment

December 1, 2001
Author(s)
Wing Tsang, Robert E. Huie, Jeffrey A. Manion
The next two issues of the International Journal of Chemical Kinetics are dedicated to Prof. Simon H. Bauer on the occasion of his 90th birthday. These issues contain a number of papers by his students and colleagues who have built on his pioneering

Commemorative Issue for Professor Simon H. Bauer I: Editorial Comment

November 1, 2001
Author(s)
Wing Tsang, Robert E. Huie, Jeffrey A. Manion
The next two issues of the International Journal of Chemical Kinetics are dedicated to Prof. Simon H. Bauer on the occasion of his 90th birthday. These issues contain a number of papers by his students and colleagues who have built on his pioneering

Atmospheric Oxidation Mechanism of Methyl Pivalate, (CH 3 ) 3 CC(O)OCH 3

August 1, 2001
Author(s)
T J. Wallington, Y Ninomiya, M Mashino, M Kawasaki, Vladimir L. Orkin, Robert E. Huie, Michael J. Kurylo III
Flash photolysis-resonance fluorescence techniques were used to measure the rate constant for the reaction of OH radicals with methyl pivalate, (CH 3) 3CC(O)OCH 3 over the temperature range 250-370 K. The rate constant exhibited a weak temperature

An Ab Initio Study of the Kinetics of the Reactions of Halomethanes With the Hydroxyl Radical. 2. A Comparison Between Theoretical and Experimental Values of the Kinetic Parameters for 12 Partially Halogenated Methanes

September 1, 2000
Author(s)
F Louis, Carlos A. Gonzalez, Robert E. Huie, Michael J. Kurylo III
Ab initio calculations have been performed for the H-atom abstraction reactions from a series of halogenated methanes by the hydroxyl radical. Geometry optimization and vibrational frequency calculations were performed for reactants, transition states and
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