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Displaying 1 - 25 of 88

Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation No. 18

October 30, 2015
Author(s)
Vladimir L. Orkin, James B. Burkholder, S. P. Sander, J. P. D. Abbatt D. Abbatt, J. R. Barker, Robert E. Huie, C E. Kolb, Michael J. Kurylo III, David M. Wilmouth, P. H. Wine
This is the eighteenth in a series of evaluated sets of rate constants, photochemical cross sections, heterogeneous parameters, and thermochemical parameters compiled by the NASA Panel for Data Evaluation. The data are used primarily to model stratospheric

Ionizing Radiation-Induced Destruction of Benzene and Dienes in Aqueous Media

March 28, 2006
Author(s)
M I. Al-Sheikhly, Dianne L. Poster, Jung-Chul An, Pedatsur Neta, Joseph Silverman, Robert E. Huie
Pulse radiolysis with spectrophotometric and conductometric detection was utilized to study the formation and reactions of radicals from benzene and dienes in aqueous solutions. The benzene OH adduct, C6H6OH, reacts with O2 (k = 3 x 108 L mol-1 s-1) in a

Radiolytic Reactions of Monochloramine in Aqueous Solutions

September 1, 2003
Author(s)
G A. Poskrebyshev, Robert E. Huie, Pedatsur Neta
Monochloramine reacts with hydrated electrons very rapidly, k(NH 2CI + e aq-) = (2.2 0.2) x 10 10 L mol -1, to produce oNH 2 radicals. It reacts with oOH radicals more slowly, k(NH 2Cl + oOH) = (5.2 0.6) x 10 8 L mol -1 s -1, to produce oNHCl radicals

Measurements of the Infrared Absorption Cross-Sections of Haloalkanes and Their Use in a Simplified Calculational Approach for Estimating Direct Global Warming Potentials

May 1, 2003
Author(s)
Vladimir L. Orkin, A G. Guschin, I K. Larin, Robert E. Huie, Michael J. Kurylo III
The infrared absorption cross-sections and integrated band intensities for 21 haloakanes: CFCl 3, CF 2Cl 2, CF 2Br 2, CH 2F 2, CHR 2Cl, CHF 2Br, CF 3Br, CHCl 2-CF 2Cl, CHFCl-CFCl 2, CHCl 2-CF 3, CHClBr-Cf 3, CHFCl-CFd2^Cl, CHFBr-CF 3, CHF 2-CF 3, CH 2Br-CF

NDRL/NIST Solution Kinetics Database on the WEB

March 1, 2003
Author(s)
Robert E. Huie
A Solution Kinetics Database, jointly created byNIST and the Notre Dame Radiation Laboratory, hasbeen made available on the Internet in a format similarto that utilized by the popular NIST KineticsDatabase, which covers gas-phase reactions. TheSolution

OH Reactivity and UV Spectra of Propane, n-Propyl Bromide, and Isopropyl Bromide

March 1, 2003
Author(s)
S N. Kozlov, Vladimir L. Orkin, Robert E. Huie, Michael J. Kurylo III
The rate constants for the reactions of OH radicals with the 1-bromopropane, 2-bromopropane, and propane were measured using the flash photolysis reasonance fluorescence technique over the temperature range between 210 K and 480 K. Arrhenius plots exhibit
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