February 24, 2015
Author(s)
Eric D. Bloch, Wendy L. Queen, Sachin Chavan, Paul S. Wheatley, Joseph M. Zadrozny, Russell E. Morris, Craig Brown, Carlo Lamberti, Silvia Bordiga, Jeffrey R. Long
An iron-based metal-organic framework featuring coordinatively-unsaturated redox-active metal cation sites, Fe 2(dobdc) (dobdc 4- = 1,4-dioxido-2,5-benzenedicarboxylate), is shown to strongly bond nitric oxide at 298 K. Adsorption isotherms indicate an