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The atomic force microscope (AFM) was used to explore the nature of features formed on the surfaces of cracks in soda-lime-silicate glass that were held at stress intensity factors below the crack growth threshold. All studies were conducted in water
The structure of BaSrR4O8 (where R = La, Nd, Sm, Gd, Eu, Dy, Ho, Y, Er, Tm, Yb, and Lu) has been investigated, and the X-ray reference patterns of these compounds have been prepared using the Rietveld refinement technique. BaSrR2O4 are isostructural to
The objective of this work is to model the grinding forces and the associated stress and deformation fields generated in a ceramic workpiece during surface plunge grinding. A two-dimensional finite element model is constructed with the grinding parameters
We have studied single crystals of Β-Si 3N 4 with polarization-resolved Raman spectroscopy in order to unambiguously obtain the symmetry character of zone center optical phonon modes. By applying ultraviolet excitation radiation, approaching resonance
C E. Evans, A C. Smith, D J. Burnett, A L. Marsh, Daniel A. Fischer, J L. Gland
Polymer formation within ordered monolayer and thin-film assemblies is measured using fluorescence yield near edge spectroscopy (FYNES). This spectroscopic method measures soft X-ray absorption in the 270 to 330 eV energy range, probing core-electron
Li Ma, J Zhou, A Lau, Samuel R. Low III, Roland deWit
Indentation process of the Rockwell diamond indenter pressing into inelastic material is studies for the analysis, simulation and prediction of Rockwell hardness tests. The geometrical characteristics of the cone-spherical-shaped Rockwell indenter are
S A. Prosandeev, Eric J. Cockayne, Benjamin P. Burton
KTaO3-based solid solutions exhibit a variety of interesting physical phenomena. To better understand these phenomena, we performed first-principles calculations on [K1-x,Lix]TaO3 (KLT) and K[Ta1-xNbx]O3 (KTN) supercells. Our results show Li displacements
The mechanisms controlling normal and exaggerated grain growth in lead magnesium niobate - lead titanate (PMN - PT) ceramics have been investigated by varying the PbO-based liquid phase volume fraction, the PT content and the MgO stoichiometry. There is a
C Y. Kim, Michael Bedzyk, E J. Nelson, Joseph Woicik, L E. Berman
We have measured the site-specific valence-electronic structure of α-Fe 2O 3 by using a spatially modulated X-ray standing wave as the excitation source for photoemission. Contributions to the valence band density of states from oxygen and iron ions are
The phase diagrams of the BaO-Gd 2O 3-CuO z and BaO-Er 2O 3-CuO z systems were determined at 0.1% O 2 (810 C) using special apparatus and a procedure for preparing carbonate-free precursors based on BaO. The handling of these atmospherically sensitive
Current applications of BaO-Y 2O 3-CuO x phase equilibria are focused on the use of coated conductor technology for fabrication of superconducting tape. Although such processing is typically carried out with carbonate-free high T c precursors, the majority
Current interest in polycrystalline ceramics having properties that reflect anisotopic characteristics inherent to their single crystal forms has led to development of new processing techniques for producing textured microstructures. One such technique is
The origin of tribochemistry is from the rubbing of surfaces together. The precise nature of the chemical reactions and the driving force behind the reactions are not known except for a few simple chemical systems. In boundary lubrication, it is difficult
Ni-base alloys are the most widely used superalloys in applications involving high temperatures and severe environmental conditions. To model the various processing steps used for these alloys, improvements in thermodynamic databases are required. These
T Siegrist, Terrell A. Vanderah, C Svensson, Robert S. Roth
Single-crystal X-ray diffraction studies indicate that the compound Ba 27Fe 16Ti 33O 117- crystallizes in the rhombohedral space group R-3m, with a hexagonal unit cell a=5.7400(8) , c=127.11(3) ; Z=1.5. The arrangement may be described as a 54-layer (54L)
We report on preparing assemblies of gold nanoparticles with continuous gradients in number density on flat silica-covered substrates. The methodology consists of: i) first forming a one dimensional molecular gradient of amino groups (-NH2) on the
L M. Dieng, A Y. Ignalov, T A. Tyson, Mark Croft, A Dogan, C Y. Kim, Joseph Woicik, J Grow
To ascertain the role of bromination in the recovery of superconductivity in underdoped YBa 2Cu 3O 6+y (YBCO) we have performed polarized multiple-edge x-ray absorption fine structure (XAFS) measurements on normal (y nearly equal to} 0.6) and brominated
L M. Dieng, T A. Tyson, Mark Croft, T Dogan, C Y. Kim, Joseph Woicik, J Grow, A Y. Ignatov
To understand the role of bromination in the recovery of superconductivity in underdoped YBCO, the spatially resolved local structural changes in brominated single crystals have been measured and compared to those in a normal crystal. In polarized x-ray
Igor Levin, Terrell A. Vanderah, T J. Coutts, S M. Bell
Phase equilibria and dielectric properties were analyzed for selected compositions in both LaCao 5ZrO.503-CaTiO3 (LCZ-CT) [email protected],O,-SrTiO3 (LCZ-ST) systems using X-ray powder diffraction and transmission electron microscopy. The end-memberLaCao.,Zro
Ajitkumar Jillavenkatesa, James F. Kelly, S J. Dapkunas
Size and size distribution measurement of powders are conducted using different techniques of size analysis.Underlying all these techniques are certain fundamental issues that influence the accuracy and reproducibility ofthe results. A thorough
A survey of recent advances in the analysis of ceramic-based layer structures for biomechanical applications is presented. Data on model layer systems, facilitating development of explicit fracture mechanics relations for predicting critical loads to
The loading mechanisms of instrumented indentation machines are often calibrated using deadweights. In many cases, due to the geometry of the loading frame, the applied deadweight is tensile, while the indentation leads to be measured are compressive. In
Igor Levin, Julia Y. Chan, J J. Scott, L Farber, Terrell A. Vanderah, James E. Maslar
The complex structural behavior of the perovskite-related compound Sr4Nb2O9 (=Sr(Sr1/3Nb2/3)O3) has been investigated using electron, X-ray, and neutron powder diffraction. Analysis of well-equilibrated specimens annealed at various temperatures indicated
Ni-Mo and Fe-Mo alloys were electrodeposited using both DC and pulsed current from a phyrophosphate bath. Their composition and morphology were investigated by EDS and optical microscopy, respectively, in order to determine the influence of the deposition
A study is made of the crack resistance of multilaminates consisting of brittle layers interleaved with compliant interlayers and bonded to compliant substrates. Specific attention is paid to flexure generated radial cracks in the undersurfaces of