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Aaron Johnson, Iosif Isaakovich Shinder, Rodney A. Bryant, JohnPaul R. Abbott, Keith A. Gillis, Joey Boyd, James Filla, Michael R. Moldover
Accurate flow measurements are essential to quantify the amount of greenhouse gases (GHGs) and other pollutants emitted from power plant stacks. Although protocols have been developed, the uncertainty of stack flow measurements has not been documented.
Winnie K. Wong-Ng, Jeffrey T. Culp, Yu-Sheng Chen, Christopher Matranga
In recent years, a number of novel compounds known as flexible pillared layer porous coordination polymer (or flexible metal organic framework (MOFs)) have been discovered which show reversible structural transitions between low porosity and high porosity
The eye-safe transmitter of a ground-based, integrated path differential absorption (IPDA) LIDAR (light detection and ranging) system is described and specified in detail. The transmitter is based on an actively stabilized, continuous-wave, single
Richard A. Perkins, Marcia L. Huber, Marc J. Assael
New experimental data on the thermal conductivity of 1,1,1,3,3-Pentafluoropropane (R-245fa) are reported that cover a wide range of liquid conditions. These new experimental data were made with a transient hot-wire apparatus and cover the liquid phase over
Two major types of porphyrinic framework structures offer promise for carbon capture and sequestration (CCS) applications: 1) metal-organic frameworks (MOFs) in which the porphyrins serve as struts linking vertices comprised of metal -based clusters; 2)
Jessica L. Reiner, John Bowden, Ian Christie, Matthew P. Guillette, Theresa M. Cantu, Russell H. Lowers, Hannes Botha, Wilmien Luus-Powell, Willem J. Smit, Danny Govender, Danie Pienaar, Louis J. Guillette Jr.
Perfluorinated alkyl acids (PFAAs) are environmental contaminants that have been used in many products for over 50 years. Interest and concern has grown since 2000 on the widespread presence of PFAAs, when it was discovered that PFAAs were present in
The number of consumer and industrial products that are nano-enabled and/or nano-enhanced has been increasing rapidly in recent years. The nano-composite materials offer an exciting mix of material properties that cannot be achieved in conventional
Nanoparticle stabilizer type, casting solution additives, and nanoparticle processing by centrifugal or magnetic separation were varied, and specific membrane characteristics were evaluated. Specifically, membrane casting solution viscosity, cast membrane
Nanomaterials are currently being used for in situ remediation of soils and groundwater. However, their improvement and continued use for a sustainable approach requires a more complete understanding of the ecological impact, which should include the
George C. Rhoderick, Duane Kitzis, Michael E. Kelley, Walter R. Miller Jr., Bradley Hall, Edward Dlugokencky, Pieter Tans, Antonio M. Possolo, Jennifer Carney
The National Institute of Standards and Technology (NIST) recently began to develop standard mixtures of greenhouse gases as part of a broad program mandated by the 2009 United States Congress to support research in climate change. To this end, NIST made
Megan Harries, Santiago Bukovsky-Reyes, Thomas J. Bruno
This paper details the sampling methods used with the field portable PLOT-cryoadsorption (PLOT-cryo) approach, described in Part I of this two-part series, applied to several analytes of interest. We conducted tests with coumarin and 2,4,6-trinitrotoluene
Nanomaterials are currently of interest for water treatment and remediation applications because they can exhibit high adsorption capacities and high reactivity to degrade or transform contaminants. Research is ongoing to further increase the adsorption
Winnie K. Wong-Ng, James A. Kaduk, Lawrence P. Cook, B Chakraborty, Greg Brewer
X-ray data of a powder sample of alpha-chlorohemin (a member of the porphyrin family), C34H32ClFeN4O4, was collected using synchrotron radiation at the Advanced Photon Source (APS, Argonne National Laboratory). Rietveld Refinement and Density Functional
Jessica L. Reiner, Paul R. Becker, Jennifer M. Lynch, Amanda J. Moors, Jennifer M. Ness, Rebecca S. Pugh, Catherine A. Rimmer, John R. Kucklick, Matthew O. Gribble, Danielle Peterson, Jody Rhoderick, Jennifer Trevillian
During native subsistence hunts from 1987 to 2007, blubber and liver samples from 50 subadult male northern fur seals (Callorhinus ursinus) were collected on St. Paul Island, Alaska. Samples were analyzed for legacy persistent organic pollutants (POPs)
Ashley S. Boggs-Russell, Heather J. Hamlin, James C. Nifong, Brittany L. Kassim, Russell H. Lowers, Thomas M. Galligan, Stephen E. Long, Louis J. Guillette Jr.
The American alligator, a freshwater species, is known to forage in marine environments which could lead to increased dietary uptake of iodine, a nutrient necessary for the production of thyroid hormones. To explore the influence of dietary iodine on
Winnie K. Wong-Ng, Jeffrey T. Culp, Yu-Sheng Chen, Jeffrey R. Deschamps, Christopher Matranga
The flexible metal organic framework (MOF), Ni(L)[Ni(CN)4], (L= 1,4-Bis(4-pyridyl)benzene, or DpBz) is a novel 3D porous material that adopts Hofmann type structure. The purple monoclinic Ni-DpBz crystal assumes a pillared structure with layers defined by
Winnie K. Wong-Ng, Igor Levin, James A. Kaduk, Laura Espinal, Hui Wu
Ambient-temperature capture of CO2 by metal-organic framework Cu3(BTC)2 (BTC ≡ 1,3,5-benzenecarboxylate), known as HKUST-1, have been studied in situ in a laboratory X-ray powder diffractometer under gas-flowing conditions. The diffraction patterns were
George C. Rhoderick, Bradley Hall, Christina Harth, Jin Seog Kim, Jeogsoon Lee, Stephen Montzka, J. Muhle, Stefan Reimann, Martin Vollmer, Ray Weiss
The growing awareness of climate change/global warming, and continuing concerns regarding stratospheric ozone depletion, will require continued measurements and standards for many compounds, in particular halocarbons that are linked to these issues. In
Chiao-Chi Lin, Peter J. Krommenhoek, Stephanie S. Watson, Xiaohong Gu
In this study, Raman imaging was used to depth profiling the chemical degradation of a commercial PPE (polyethylene terephthalate (PET)/PET/ethylene vinyl acetate (EVA)) backsheet films during exposure with UV irradiance of 170 W/m2 (300 nm to 400 nm) at
Linear mixtures of materials in a scene often occur because the pixel size of a sensor is relatively large and consequently they contain patches of different materials within them. This type of mixing can be thought of as areal mixing and modeled by a
Mark O. McLinden, J. Steven Brown, Andrei F. Kazakov, Piotr A. Domanski
We explore the possibilities for low-GWP refrigerants through two approaches. First, we explore the performance of hypothetical refrigerants to define the limits of what is allowed by thermodynamics. In the second approach, we apply property estimation
Here, we highlight articles examining different aspects contributing to the fate and role of carbon nanomaterials in environmental systems by developing new insight through measurement methodologies or systematic approaches. The first study examined the
Water absorption in the metal-organic framework (MOF) material Cu-BTC, up to a concentration of 3.5 H2O per Cu ion, is studied via density functional theory at the meta-GGA+U level. The stable arrangements of water molecules show chains of hydrogen-bonded
We present experimental measurements of the density, speed of sound, and vapor pressure of trans-1-chloro-3,3,3-trifluoropropene, which is also known as R1233zd(E). Densities were measured over the temperature range from (215 to 444) K, with pressures from