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It is determined that dissociation of molecular ions of aryl-isoxazolines under electron ionization takes place primarily through the nitro- and halogen-containing groups. Detailed analysis of the most important fragmentation pathways are presented
Peaks of characteristic ions in the electron ionization mass spectra of substituted β-nitrostyrenes are identified, and mechanisms of their formation are determined
General fragmentation pathways for nitro-substituted di(aryl)isoxazolines under electron ionization are determined. Ions useful for differentiation of positional and stereo-isomers are established.
Anzor I. Mikaia, Alexander Ivanov, Vladimir G. Zaikin
General and specific fragmentation pathways of trifluoroacetyl and heptafluorobutyryl derivatives of primary and secondary amines under electron ionization are determined. The derivatives are obtained as a result of on-column acylation.