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Displaying 51 - 75 of 134

Comparison of the Properties of Cellulose Nanocrystals and Cellulose Nanofibrils Isolated From Bacteria, Tunicate, and Wood Processed Using Acid, Enzymatic, Mechanical, and Oxidative Methods

April 18, 2014
Author(s)
Iulia A. Sacui, Jeffrey W. Gilman, Ryan C. Nieuwendaal, Stephan J. Stranick, Henryk Szmacinski, Mehdi Jorfi, Christopher Weder, Johan Foster, Richard Olsson, Daniel Burnett
This work describes the study and characterization of native cellulose nanocrystals and nanofibrils (CNCs, CNFs), whose crystallinity, morphology, aspect ratio, and surface chemistry depend on the raw material source and hydrolysis conditions. Measurement

Reducing the Risk of Fire in Buildings and Communities

January 1, 2014
Author(s)
Anthony Hamins, Jason D. Averill, Nelson P. Bryner, David Butry, Richard Gann, Rick D. Davis, Daniel M. Madrzykowski, Alexander Maranghides, Jiann C. Yang, Matthew Bundy, Samuel Manzello, Jeffrey W. Gilman, Francine K. Amon, William E. Mell
Fire costs and losses are a significant life safety and economic burden on society comprising about two percent of the United States gross domestic product. This paper presents the results of a roadmap developed by the National Institute of Standards and

Cellulose Nanomaterials: Nanocomposite Imaging using FRET

June 19, 2013
Author(s)
Jeffrey W. Gilman, Mauro Zammarano, Iulia A. Sacui, Jeremiah Woodcock
Cellulose is the most abundant organic polymer on Earth, found in plants (cotton, hemp, wood), marine animals (Tunicate), algae (Valonia) bacteria (Acetobacter xylium) and even amoeba (Dictyostelium discoideum). Critical features of the structural

Nanoparticles in Flame-Retardant Coatings for Flexible Polyurethane Foams: Effects on Flammability and Nanoparticle Release

May 15, 2013
Author(s)
Mauro Zammarano, Rick D. Davis, Yeon S. Kim, Richard H. Harris Jr., Marc R. Nyden, Jeffrey W. Gilman, Nasir M. Uddin
Nanoparticles can effectively reduce polymer flammability; however, the impact of nanoparticles on environmental and health safety is still unclear. The purpose of this study is twofold: (1) to develop and investigate the effect of nanoparticle-rich

Thermal and Burning Properties of Poly(lactic acid) Composites Using Cellulose-Based Intumescing Flame Retardants

December 21, 2012
Author(s)
Douglas M. Fox, Srilatha Temburni, Melissa Novy, Laura Flynn, Mauro Zammarano, Yeon S. Kim, Jeffrey W. Gilman, Rick D. Davis
Poly(lactic acid) was flame retarded using cellulose-based intumescing flame retardants. Cellulose was an excellent carbon source in combination with ammonium polyphosphate (APP), exhibiting good thermal stabilities and UL-94 ratings of V-0

Smoldering in Flexible Polyurethane Foams: the Effect of Foam Morphology

December 18, 2012
Author(s)
Mauro Zammarano, Szabolcs Matko, Roland H. Kraemer, Rick D. Davis, Jeffrey W. Gilman, Li Piin Sung, Douglas M. Fox, Shivani N. Mehta
Smoldering is a self-sustaining heterogeneous oxidation reaction that induces a slow, low temperature, flameless combustion. Flexible polyurethane foams (PUF) are prone to smoldering due to their high air permeability, low density and high specific surface

Formation of Extended Ionomeric Network by Bulk Polymerization of L,D-lactide with Layered Double Hydroxide

November 22, 2012
Author(s)
Edward D. McCarthy, Mauro Zammarano, Douglas M. Fox, Ryan Nieuwendaal, Yeon S. Kim, P H. Maupin, Paul C. Trulove, Jeffrey W. Gilman
We report the formation of an ionomeric network in a poly(L,D-lactide) hybrid nanocomposite, (PLDLA-HYB) during in-situ melt polymerization of L,D lactide in the presence of magnesium/aluminium layered-double-hydroxide (LDH) without added catalyst. The

Factors Influencing the Smoldering Performance of Polyurethane Foam

September 26, 2012
Author(s)
Mauro Zammarano, Szabolcs Matko, Roland H. Kraemer, Rick D. Davis, Jeffrey W. Gilman, Shivani N. Mehta
The objective of this study was to evaluate whether polyurethane foam (PUF) could be produced as a standard reference material for ultimate use in a standard test intended to ensure the smoldering performance of commercially available upholstered furniture

Ionic Liquid Facilitated Introduction of Functional Materials into Biopolymer Polymer Substrates

August 2, 2012
Author(s)
Shonali Nazare, Jeffrey W. Gilman, Mauro Zammarano, Luke Haverhals, W.Matthew Reichert, Hugh De Long, Paul C. Trulove
In addition to being efficient solvents for biopolymers, several ionic liquids (ILs) have been shown to be effective solvents for synthetic polymers such as meta-aramids, i.e., Nomex ® (1-5). In this report, meta-aramid/cotton composites are generated by

Strategic Roadmap for Fire Risk Reduction in Buildings and Communities

April 18, 2012
Author(s)
Anthony P. Hamins, Jason D. Averill, Richard G. Gann, Nelson P. Bryner, Rick D. Davis, David T. Butry, Alexander Maranghides, Jiann C. Yang, Daniel M. Madrzykowski, Matthew F. Bundy, Samuel L. Manzello, Jeffrey W. Gilman, Francine K. Amon, William E. Mell
The burden of fire on the U.S. economy continues to be large, comprising approximately $280 billion annually, or 2 percent of GDP. Over the last 30 years, civilian fire deaths and injuries have decreased due to the efforts of many people and organizations

Char – Forming Behavior of Nanofibrillated Cellulose Treated with Glycidyl Phenyl POSS

April 15, 2012
Author(s)
Douglas M. Fox, Jieun Lee, Mauro Zammarano, Dimi Katsoulis, Donald V. Eldred, Luke Haverhals, Paul C. Trulove, Hugh C. De Long, Jeffrey W. Gilman
Cellulose-reinforced composites have received much attention due to their structural reinforcing, light weight, biodegradable, non-toxic, low cost and recyclable characteristics. However, the tendency for cellulose to aggregate and its poor dispersion in

Revealing the Interphase in Polymer Nanocomposites

March 16, 2011
Author(s)
Mauro Zammarano, Paul H. Maupin, Li Piin Sung, Jeffrey W. Gilman, Douglas M. Fox
Morphological characterization of polymer nanocomposites is a fundamental challenge that is complicated by multiple length scales. Here, we report a technique for high-throughput monitoring of interphase and dispersion in polymer nanocomposites based on

SUSTAINABLE FLAME RETARDANTS: BIO-DERIVED PRODUCTS AS INTUMESCING MATERIALS

February 2, 2011
Author(s)
Mauro Zammarano, Douglas M. Fox, Szabolcs Matko, Takashi Kashiwagi, Jeffrey W. Gilman, Rick D. Davis
Scientists are shifting their attention towards technology sustainability and sustainable materials, specifically in terms of energy and environmental impacts. The flame retardant community is also more concerned about these aspects. The recent banning of

Microencapsulated POSS in Cellulose Using 1-Ethyl-3-Methylimidazolium Acetate

October 10, 2010
Author(s)
Douglas M. Fox, Mauro Zammarano, Jeffrey W. Gilman
Polyhedral oligomeric silsesquioxane (POSS) and cellulose were reacted in the ionic liquid, 1-ethyl-3-methylimidazolium acetate (EmiAc). Side reactions between the EmiAc and each reactant were prevalent, but use of water as the coagulating solvent produced

POSS modified cellulose for improving flammability characteristics of polystyrene

April 2, 2010
Author(s)
Douglas M. Fox, Mauro Zammarano, Jeffrey W. Gilman, Jieun Lee, Eric Balsley, Erica Ford
Due to its strength, charring ability, and biodegradability, cellulose-based reinforced polymers have received considerable attention. However, its high polarity, large molecular size, and solvent resistivity, have often resulted in immiscible or

Proceedings of the 2009 Workshop on Innovative Fire Protection

February 17, 2010
Author(s)
Anthony P. Hamins, Francine K. Amon, Jason D. Averill, Nelson P. Bryner, David T. Butry, Rick D. Davis, Richard G. Gann, Jeffrey W. Gilman, Samuel L. Manzello, Randall J. McDermott, William E. Mell, Nathan D. Marsh
The Innovative Fire Protection Workshop was held at the National Institute of Standards and Technology (NIST) on June 4 and 5, 2009. The 70 participants represented a broad range of stakeholder perspectives, including various non-profit, academic, industry

Heat release and structural collapse of flexible polyurethane foam

January 1, 2010
Author(s)
Roland H. Kraemer, Mauro Zammarano, Gregory T. Linteris, Ulf W. Gedde, Jeffrey W. Gilman
Flexible polyurethane foam used in upholstered furniture remains one of the major fire hazards to date. The heat release rate of burning items made of foam depends strongly on the foam's physical behavior, notably its collapse to a burning liquid that can

SUSTAINABLE FLAME RETARDANT NANOCOMPOSITES

March 17, 2009
Author(s)
Jeffrey W. Gilman
This paper examines the current state of research into sustainable flame retardants with the work on nanocomposites highlighted. The motivations to move away from halogen-based flame retardants are discussed and a number of life-cycle-assessments are

High Throughput Flammability Characterization Using Gradient Heat Flux Fields.

December 1, 2005
Author(s)
Jeffrey W. Gilman, Rick D. Davis, John R. Shields, Richard H. Harris Jr.
The quest for small-scale flammability tests useful for predicting large-scale fire test performance is an enduring undertaking. Often, this work is motivated by limited access to larger quantities of samples, in the case of materials development efforts