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Displaying 976 - 1000 of 3672

13C - NMR Absorptions of Major Functional Groups

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The table below lists the 13C chemical shift ranges (in ppm) with the corresponding functional groups in descending order. A number of typical simple compounds for every family are given to illustrate the corresponding range. The shifts for the carbons of

15 N - NMR Chemical Shifts of Major Chemical Families

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table contains 15N NMR chemical shifts of various organic nitrogen compounds. Chemical shifts are expressed relative to different standards (NH 3, NH 4Cl, CH 3NO 2, NH 4NO 3, HNO 3, etc.) and are interconvertible. Chemical shifts are

Analytical Standardization and Calibration

June 22, 2012
Author(s)
Thomas J. Bruno
Most modern instrumental techniques used in analytical chemistry produce an output or signal that is not absolute; the signal or peak is not a direct quantitative measure of concentration or target analyte quantity. Thus, to perform quantitative analysis

Atomic Masses and Abundances

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table lists the atomic masses and relative percent concentrations of naturally occurring isotopes of importance in mass spectroscopy.

Common Mass Spectral Fragmentation Patterns of Organic Compound Families

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides a guide to the identification and interpretation of commonly observed mass spectral fragmentation patterns for common organic functional groups [1-10]. It is of course highly desirable to augment mass spectroscopic data with as

Common Mass Spectral Fragments Lost

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table gives a list of neutral species that are most commonly lost when measuring the mass spectra of organic compounds. The list is suggestive rather than comprehensive, and should be used in conjunction with other sources [1-5]. The listed

Common Spurious Infrared Absorption Bands

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides some of the common potential sources of spurious infrared absorptions that might appear on a spectrum.

Common Spurious Signals Observed in Mass Spectrometers

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides guidance in the recognition and interpretation of spurious signals (m/z peaks) that will sometimes be observed in measured mass spectra [1]. Often, the occurrence of these signals can be predicted by the recent history of the

Common Spurious Signals Observed in Mass Spectrometers

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides guidance in the recognition of spurious signals (m/z peaks) that will sometimes be observed in measured mass spectra, especially when the mass spectrometer is interfaced to a gas chromatograph [1]. Often, the occurrence of

Detection of outliers in measurements

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The field of outlier detection and treatment is considerable, and a rigorous mathematical discussion is well beyond any treatment that is possible here. Moreover, the practice in the treatment of analytical results is usually simplified, since the number

Detectors for Gas Chromatography

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides some comparative data for the selection and operation of the more common detectors applied to capillary and packed column gas chromatography [1-8]. For more detailed information regarding operation and interpretation of results

Eluotropic Values of Solvents on Octadecylsilane and Octylsilane

June 22, 2012
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The following table provides, for comparative purposes, eluotropic values on bonded octadecyl silane (ODS) and octyl silane (OS) for common solvents.[1-3] For additional information on common, specific and chiral stationary phases for HPLC, and for
Displaying 976 - 1000 of 3672
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