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Displaying 451 - 475 of 909

Abiotic bromination of soil organic matter

October 15, 2015
Author(s)
Bruce D. Ravel, Alessandra C. Leri
Biogeochemical transformations of plant-derived soil organic matter (SOM) involve complex abiotic and microbially mediated reactions. One such reaction is halogenation, which occurs naturally in the soil environment and has been associated with enzymatic

Identification and Quantification of Six-Ring C26H16 Cata-Condensed Polycyclic Aromatic Hydrocarbons in a Complex Mixture of Polycyclic Aromatic Hydrocarbons from Coal Tar

October 8, 2015
Author(s)
Jorge O. Ona Ruales, Arun K. Sharma, Stephen A. Wise
We applied a combination of normal-phase liquid chromatography (NPLC) with ultraviolet-visible spectroscopy and gas chromatography with mass spectrometry (GC/MS) for the fractionation, identification, and quantification of six ring cata-condensed C26H16

Top-top internal rotation coupling in the microwave spectrum of pinacolone

October 8, 2015
Author(s)
Jon T. Hougen, Yueyue Zhao, Ha Vanh L. Nguyen, Wolfgang Stahl
The molecular beam Fourier-transform microwave spectrum of pinacolone (methyl tert-butyl ketone) has been measured in several regions between 4 and 40 GHz. Fits of the assigned spectrum using several computer programs based on different models for treating

Microwave Rotational Spectral Study of SO2-CO

October 2, 2015
Author(s)
Francis J. Lovas, Matthew K. Sprague
The microwave spectrum of the molecular complex of sulfur dioxide (SO2) with carbon monoxide (CO) has been studied with a pulsed-beam Fourier Transform Microwave Spectrometer (FTMW) from a pair of gas samples of 1 % by volume of SO2 and CO in Ar, and

Non-collinear generation of angularly isolated circularly polarized high harmonics

September 21, 2015
Author(s)
Justin M. Shaw, Daniel Hickstein, Franklin Dollar, Patrik Grychtol, Jennifer Ellis, Carlos Hernandez-Garcia, Ronny J. Knut, Christian Gentry, Henry Kapteyn, Margaret Murnane
We generate ultrashort pulses of angularly isolated, circularly polarized extreme ultraviolet (EUV) light through the first implementation of noncollinear high harmonic generation with circularly polarized driving lasers. The noncollinear geometry offers

Broadband phase spectroscopy over turbulent air paths

September 4, 2015
Author(s)
Fabrizio R. Giorgetta, Greg B. Rieker, Esther Baumann, William C. Swann, Laura C. Sinclair, Jonathan Kofler, Ian R. Coddington, Nathan R. Newbury
Broadband atmospheric phase spectra are measured at sub-milliradian uncertainty corresponding to a 10-13 refractive index change, despite strong decoherence from atmospheric turbulence. A phase-sensitive dual-comb spectrometer acquires spectra over 233 cm

Correction for stray light in optical spectroscopy of crystals

September 1, 2015
Author(s)
Richard W. Hendler, Curtis Meuse, David Travis Gallagher, Joerg Labahn, Jan Kubicek, Paul D. Smith, John W. Kakareka
It has long been known in spectroscopy that light not passing through a sample, but reaching the detector (i.e. stray light) results in a distortion of the spectrum known as absorption- flattening. In spectroscopy with crystals, one must either include

Muffin tin potentials in EXAFS analysis

September 1, 2015
Author(s)
Bruce D. Ravel
Muffin tin potentials are the standard tool for calculating the potential surface of a cluster of atoms for use in the analysis of extended x-ray-absorption fine-structure (EXAFS) data. The set of Cartesian coordinates used to define the positions of atoms

Photovoltaic switching mechanism in lateral structure hybrid Perovskite solar cells

August 5, 2015
Author(s)
Yongbo Yuan, Jungseok Chae, Yuchuan Shao, Qi Wang, Zhengguo Xiao, Andrea Centrone, Jinsong Huang
Organometal trihalide perovskite solar cells with lateral device architecture recently attracted interest because of their switchable photovoltaic effect, which potentially could be leveraged to realize transparent-electrode-free solar cells. However, the

Infrared Imaging and Spectroscopy Beyond the Diffraction Limit

July 22, 2015
Author(s)
Andrea Centrone
Progress in nanotechnology is enabled by and dependent on the availability of measurement methods with spatial resolution commensurate with nanomaterials’ length scales. Chemical imaging techniques, such as scattering scanning near-field optical microscopy

Analysis of Several High-Resolution Bands of Spiropentane, C5H8

June 15, 2015
Author(s)
Alfons Weber, A. Maki, J. E. Price, Jared Harzan, J. W. Nibler, T. Masiello, T Blake
The high resolution absorption spectrum of spiropentane (C5H8) from 200 cm-1 to 4000 cm−1 has been measured and a detailed analysis is presented for eight bands in the region from 700 cm−1 to 2200 cm−1. Two fundamental perpendicular bands were analyzed
Displaying 451 - 475 of 909
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