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Displaying 351 - 375 of 1922

Fundamentals and characterizations of scratch resistance on automotive clearcoats

September 11, 2018
Author(s)
Li Piin Sung, Linqian Feng, Nadia Benhamida, Pierre Morel, Andrew T. Detwiler, Jon M. Skelly, Leslie T. Baker, Deepanjan Bhattacharya
As original equipment manufacturers (OEMs) strive to deliver improved coating performance with a sustainable footprint, opportunities for innovation are emerging, particularly on improving mechanical properties, appearance, and solids content. Resistance

Flow-induced crystallization during materials extrusion additive manufacturing

September 10, 2018
Author(s)
Lily Northcutt, Sara Orski, Kalman D. Migler, Anthony Kotula
Material extrusion additive manufacturing processes force molten polymer through a printer nozzle at high (> 100 s-1) wall shear rates prior to cooling and crystallization. These high shear rates can lead to flow-induced crystallization in common polymer

Protocols for Determining the Mechanical Properties of High Strength Copolymer Aramid Fibers

September 1, 2018
Author(s)
Amanda L. Forster, Viviana Rodriguez Cardenas, Ajay Krishnamurthy, Amy E. Engelbrecht-Wiggans, Zois Tsinas
The primary goal of the manuscript is to develop a protocol to prepare consistent specimens for accurate mechanical testing of high strength copolymer aramid fibers, by removing a coating and disentangling the individual fiber strands without introducing

SEIRAS Study of Chloride Mediated Polyether Adsorption on Cu

August 31, 2018
Author(s)
Thomas P. Moffat, Daniel Josell, Lee J. Richter
Surface enhanced infrared absorption spectroscopy (SEIRAS) was used to examine the co- adsorption of a selection of polyethers with Cl- under conditions relevant to superconformal Cu electrodeposition in CuSO4-H2SO4 electrolytes. In 0.1 mol/L H2SO4 a

A Readily Programmable, Fully Reversible Shape Switching Material

August 24, 2018
Author(s)
Matthew McBride, Alina Martinez, Lewis M. Cox, Marvin Alim, Kimberly Childress, Michael Beiswinger, Maciej Podgorski, Brady Worrell, Jason Killgore, Christopher N. Bowman
Liquid crystalline elastomers (LCEs) enable large scale reversible shape changes in polymeric materials; however, they require intensive, irreversible programming approaches to facilitate controllable actuation. We have implemented photo-induced dynamic

Complex coacervation in polyelectrolytes from a coarse-grained model

August 22, 2018
Author(s)
Vivek M. Prabhu, Marat Andreev, Jian Qin, Matthew Tirrell, Juan J. de Pablo, Jack F. Douglas
Polyelectrolyte coacervation refers to the formation of distinct liquid phases that arise when polyelectrolytes of opposite charge are mixed under appropriate polymer and salt concentrations. Molecular-level studies of complex polyelectrolyte coacervation

Competitive solvation effects in polyelectrolyte solutions

August 1, 2018
Author(s)
Alexandros Chremos, Jack F. Douglas
An understanding of the solution properties and phase behavior of natural and synthetic polyelectrolytes requires an understanding of the competitive association of water (“hydration”) and ion association to the polymer backbone and the consequences of

Aggregation and Solubility of a Model Conjugated Donor-Acceptor Polymer

July 31, 2018
Author(s)
Daniel R. Reid, Nicholas E. Jackson, Alexander J. Bourque, Chad R. Snyder, Ronald L. Jones, Juan de Pablo
In organic semiconductors, solution-phase polymer structure and aggregation have a strong influence on device morphology and performance. Thus, understanding solubility of conjugated polymers is crucial for their rational design. Using a combination of

Effect of temperature on the structure and dynamics of triblock copolymer coacervate hydrogels

July 16, 2018
Author(s)
Vivek M. Prabhu, Ryan C. Nieuwendaal, Anand Rahalkar, Juan J. DePablo, Samanvaya Srivastava, Matthew Tirrell
Triblock copolymer coacervate gels were characterized by small-angle neutron scattering (SANS) and dynamic light scattering. The oppositely charged polyelectrolyte complex core size does not change with temperature. However, the neutral middle block that

Characterization of Interfacial Structure in Polymer-Fullerene Bulk Heterojunctions via 13C {2H} Rotational Echo Double Resonance NMR

July 13, 2018
Author(s)
Ryan C. Nieuwendaal, Dean M. DeLongchamp, Martin Heeney, Jan Hummelen, Chad R. Snyder, Ronald L. Jones, Sebastian Engmann, Lee J. Richter, Zhuping Fei, Alex Sieval
We introduce a new application of solid state NMR measurements towards characterizing the donor-acceptor interfaces within bulk heterojunction (BHJ) films. Rotational echo double resonance (REDOR) is used to measure dipolar couplings between 13C nuclei on

Polyelectrolyte association and solvation

July 10, 2018
Author(s)
Alexandros Chremos, Jack F. Douglas
There has been significant interest in the tendency of highly charged particles having the same charge to form dynamic clusters in solution, but an accepted theoretical framework that can account for this ubiquitous phenomenon has been slow to develop. The

Design and Implementation of pyPRISM: A Polymer Liquid-State Theory Framework

June 15, 2018
Author(s)
Tyler B. Martin, Thomas E. Gartner, Ronald L. Jones, Chad R. Snyder, Arthi Jayaraman
Polymer Reference Interaction Site Model (PRISM) theory describes the equilibrium spatial- correlations, thermodynamics, and structure of liquid- like polymer systems and macromolecular materials. Here, we describe the code structure, implementation, and

Poroelastic Fracture Transition of a Biopolymer Gel

May 24, 2018
Author(s)
Edwin P. Chan, Bradley R. Frieberg, Ronald L. Jones, Ray-Shimry Garatsa, John Bachert, Benjamin Crawshaw
Controlling the fracture behavior of thermoreversible biopolymer gels is important in many con- sumer based applications. For example, gelatin gels are used in the encapsulation and release in vitamin capsules, the manipulation of texture in gelled foods
Displaying 351 - 375 of 1922
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