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Katelyn Goetz, Jun?ya Tsutsumi, Sujitra Pookpanratana, Jihua Chen, Curt A. Richter, Christina Hacker, Tatsuo Hasegawa, Oana Jurchescu
The organic charge-transfer (CT) complex dibenzotetrathiafulvalene - 7,7,8,8-tetracyanoquinodimethane (DBTTF-TCNQ) is found to crystallize in two polymorphs when grown by physical vapor transport: the known α-polymorph and a new structure, the β-polymorph
Christina A. Hacker, Sujitra J. Pookpanratana, Curt A. Richter, Mariona Coll
In this chapter we examine the various approaches to making electrical contact to large area molecular junctions. We will highlight the experimental concerns that one must consider and the various approaches to make reliable structures and characterize the
A Padilla, Alex Watson, Christopher L. Holloway, James Booth
This work presents the design, fabrication and characterization results for a thick film (6µm Cu), coplanar waveguide (CPW) resonator operating at 2.2GHz with a high Q (177), integrated with a microfluidic channel. We demonstrate detection of changes in
Edwin J. Heilweil, Jin Zuanming, Dominik Gehrig, Clare Dyer-Smith, Frederic Laquai, Mischa Bonn, Dmitry Turchinovich
Ultrafast photo-induced carrier dynamics in prototypical low band-gap polymer:fullerene photovoltaic blend films PTB7:PC70BM and P3HT:PC70BM is investigated using ultrafast terahertz (THz) spectroscopy. The sub-picosecond (ps) and few-ps decays of THz
Albert A. Talin, Andrea Centrone, Alexandra C. Ford, Michael E. Foster, Vitalie Stavila, Paul M. Haney, Robert A. Kinney, Veronika Szalai, Farid El Gabaly, Heayoung Yoon, Francois Leonard, Mark Allendorf
We report a strategy for realizing tunable electrical conductivity in MOFs in which the nanopores are infiltrated with redox-active, conjugated guest molecules. This approach is demonstrated using thin-film devices of the MOF Cu3(BTC)2 (also known as HKUST
Juan C. Collado Gomez, Eduard Rocas, Jordi Mateu, Nathan D. Orloff, James C. Booth, Alberto Padillo, Juan Callaghan
This work proposes a procedure to characterize the intrinsic nonlinearities of bulk acoustic wave resonators by performing one port measurements of the second harmonic and second order intermodulation spurious signals. Closed-form expressions have been
Oana Jurchescu, Brad Conrad, Christina Hacker, David J. Gundlach, Curt A. Richter
The fabrication of top metal contacts for organic electronics represents a challenge and has important consequences for electrical properties of such systems. We report a low cost and non-destructive printing process, Flip Chip Lamination (FCL), to
Nadine Gergel-Hackett, Nizeet Aquilar, Curt A. Richter
We demonstrate that charge transport through a CMOS-compatible molecular electronic device is dominated by one of two different transport regimes depending on the dipole of the molecular monolayer in the junction,doping level of the silicon substrate, and
Transistors have been made from single molecules, where the flow of electrons is controlled by modulating the energy of the molecular orbitals. Insight from such systems could aid the development of future electronic devices.
Mariona Coll Bau, Christina A. Hacker, Lauren H. Miller, Daniel R. Hines, E. C. Williams, Curt A. Richter
In the emerging area of molecular electronics, fabrication of reliable metallic contacts remains one of the most critical challenges. Nanotransfer printing (nTP) is an attractive low-cost non-destructive technique to provide contact to organic monolayers
Alessandro Troisi, J M. Beebe, Laura B. Picraux, Roger D. van Zee, D R. Stewart, M Ratner, James G. Kushmerick
Using inelastic electron tunneling spectroscopy (IETS) to measure the vibronic structure of non-equilibrium molecular transport, aided by a quantitative interpretation scheme based on non-equilibrium Greens function/density functional theory methods, we
The use of molecules in electronic circuit has been the subject of recent study. Experimentally, two-terminal, molecular rectifiers have been demonstrated, three-terminal, single-molecule transistors demonstrated, and electromechanical molecular switches
Christopher D. Zangmeister, Laura B. Picraux, Roger D. van Zee, Yuxing Yao, J M. Tour
Photoemission spectra have been used to determine the energy-level alignment and work function of monolayers of 4,4'-bis-(phenylethynyl)benzenethiol, 2 naphthalene thiol, and 3-(naphthalen-2-yl)propane-1-thiol self-assembled on Ag, Cu, Au, and Pt. For each
Christopher D. Zangmeister, Steven W. Robey, Roger D. van Zee
Photoelectron spectroscopy was used to explore changes in Fermi level alignment, within the p-p* gap, arising from changes in the coupling chemistry of conjugated phenylene ethynlene oligomers to the Au surface. Self-assembled monolayers were formed
Laura B. Picraux, Christopher D. Zangmeister, J Batteas
This study investigates the formation of low-density, flat-lying decanethiol chemisorbed on Au prepared by heating the surface covered with a densely-packed, upright monolayer to a surface temperature above the onset of desorption. We determined conditions
Christopher D. Zangmeister, Steven W. Robey, Roger D. van Zee, Yuxing Yao, J M. Tour
One- and two-photon photoemission spectra have been measured for monolayers of oligo(para-phenylene-ethynylene) thiolate chemisorbed on gold surfaces. Within 5 eV of the Fermi level, four states are observed, two occupied (2.0 eV and 4.0 eV below the Fermi