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From all-electron fixed-spin-moment calculations we show that ferromagnetic and checkerboard antiferromagnetic ordering in LaFeAsO are not stable and the stripe antiferromagnetic configuration with is the only stable ground state. The main exchange
Wei Zhou, Hui Wu, Taner Yildirim, Jeffrey R. Simpson, Angela R. Hight Walker
Metal-organic framework-5 (MOF-5) was recently suggested to possess an exceptionally large negative thermal expansion coefficient. Our direct experimental measurement of the thermal expansion of MOF-5, using neutron powder diffraction, in the temperature
C. Sudakar, K. Pradmanabhan, R Naik, G Lawes, Brian Kirby, Sanjiv Kumar, V. M. Naik
We investigated the magnetic properties of CuO–ZnO heterostructures to elucidate the origin of the ferromagnetic signature in Cu doped ZnO. The CuO and ZnO layer thickness were varied from 15 to 150 nm and from 70 to 350 nm, respectively. Rutherford
H. D. Zhou, C. R. Wiebe, A. Harter, Naresh S. Dalal, Jason Gardner
The new pyrochlore Mn2Sb2O7 has been synthesized via a low-temperature method to retain cubic Fd2m symmetry. The resulting material has an unconventional spin glass state at TSG∼41 K, in the absence of detectable site disorder or a structural phase
J Park, X Li, D Tran, T Abdel-Baset, Daniel S. Hussey, David L. Jacobson, Muhammad D. Arif
In this study neutron radiography is applied to investigate the performance of a PEM fuel cell based on the effect of liquid water accumulation in the cell. Dynamic performance tests have been carried out on a PEM fuel cell with a specially designed
M. B. Stone, M. D. Lumsden, Sung Chang, E. C. Samulon, C. D. Batista, I. R. Fisher
We present single crystal inelastic neutron scattering measurements of the S=1 dimerized quasi-two-dimensional antiferromagnet Ba3Mn2O8. The singlet-triplet dispersion reveals nearest-neighbor and next-nearest-neighbor ferromagnetic interactions between
Vivek M. Prabhu, Jihoon Kang, Nayool Shin, Do Y. Yoon, Do Y. Jang
A comprehensive structural and electrical characterization of solution-processed blend films of 6,13-bis(triisopropylsilylethynyl)pentacene (TIPS-pentacene) and poly(alpha-methylstyrene) (PaMS) was performed to understand and optimize the blend
Shannon Watson, T. Hauet, Julie A. Borchers, S Mangin, Eric E. Fullerton
Using magnetometry and polarized neutron reflectometry (PNR), we have mapped the reversal processes of the antiferromagnetically coupled, hard/soft system, TbFeCo/[Co/Pd(tpd)}15, with perpendicular anisotropy. The magnitude of the exchange coupling within
Seoungsu Lee, William D. Ratcliff, S.-W. Cheong, V. Kiryukhin
Single crystals of multiferroic BiFeO 3 were investigated using neutron scattering. Application of an electric field reversibly switches ferroelastic domains, inducing changes in the magnetic structure which follows rotation of the structural domains. In
The spatial intensity distribution of neutrons emerging from a curved guide is asymmetric, and straight guide sections are sometimes appended to curved guides to make the intensity distribution more nearly uniform. For idealized uniform illumination and in
Metal−organic framework (MOF) compounds with exposed transition-metal (TM) sites were recently found to exhibit significantly larger experimental heats of adsorption of H2 than classical MOFs, thus attracting greater attention. Here we show that the
Chunxia Chen, Praveen Depa, Janna K. Maranas, Victoria G. Sakai
We evaluate explicit atom, united atom, and coarse-grained force fields for molecular dynamics simulation of poly(methyl methacrylate)(PMMA)by comparison to structural and dynamic neutron scattering data. The coarse-grained force field is assigned based on
Kristopher Lavery, Vivek M. Prabhu, Eric K. Lin, Wen-Li Wu, Kwang-Woo Choi, Sushil K. Satija, M Wormington
Off-specular reflectivity, or diffuse scattering, probes the lateral compositional variations at surfaces and interfaces. Of particular interest is the characterization at buried interfaces for the form and amplitude of roughness. Recent advances in
Jon P. Owejan, T Trabold, David L. Jacobson, D Baker, Daniel S. Hussey, Muhammad D. Arif
An interdigitated cathode flow field was tested in-situ with neutron radiography to measure the water transport through the porous gas diffusion layer in a PEM fuel cell. Constant current density to open circuit cycles were tested and the resulting liquid
Daniel S. Hussey, David L. Jacobson, Muhammad Arif, Jon P. Owejan, Jeffrey J. Gagliardo, T Trabold
Neutron imaging has proven an invaluable tool for water metrology in operating proton exchange membrane fuel cells. Due to limitations in scintillator-based detector resolution, neutron imaging has been applied only to assessing the in-plane water
Jon P. Owejan, T Trabold, Jeffrey J. Gagliardo, Robert N. Carter, Daniel S. Hussey, David L. Jacobson, Muhammad D. Arif
Single fuel cells running independently are often used for fundamental studies of water transport. It is also necessary to assess the dynamic behavior of fuel cell stacks comprised of multiple cells arranged in series, thus providing many paths for flow of
L C. Teague, S Banerjee, S S. Wong, Curt A. Richter, Bindhu Varughese, J Batteas
A significant challenge exists in probing the transport behavior of chemically modified single- walled carbon nanotubes (SWNTs). Thin films of SWNTs offer one facile approach to integration of these materials into electronics and sensing applications. Data
A S. Tremsin, Daniel S. Hussey, David L. Jacobson, Muhammad D. Arif, Robert Gregory Downing, W B. Feller, David F. Mildner
A new type of high performance and compact neutron collimator can be manufactured from Gd- or B-doped microchannel plates (MCPs). Structures only a few mm thick have very narrow rocking curves and high out-of-angle rejection ratios, as observed previously
D J. Ludlow, M K. Jensen, C M. Calebrese, G A. Eisman, S Yu, C Dannehy, Daniel S. Hussey
Neutron scattering experiments on a proton exchange membrane fuel cell wereperformed to assess the ability to quantify water in the membrane and electrode/gas diffusion layers. Previous studies have shown that liquid water is easily resolved within flow
Jeffrey A. Fagan, Brian Landi, Idan Mandelbaum, Vardhan Bajpai, Barry J. Bauer, Kalman D. Migler, Jeffrey R. Simpson, Angela R. Hight Walker, Ryan Raffaelle, Erik K. Hobbie
Model polymer composites of DNA wrapped single-wall carbon nanotubes (SWNTs) dispersed in polyacrylic acid are used for a systematic comparison of the different metrologies currently used to evaluate SWNT dispersion. Application of a pH-controlled
N Smith, Sung Kim, Prasad T. Reddy, David T. Gallagher
ABSTRACT: The crystal structure of the class IV adenylyl cyclase from Yersinia pestis is reported at 1.9 resolution. The class IV fold is distinct from the previously described folds for class II and class III ACs. The dimeric Yp AC-IV folds into an