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Compounds with fluorite-type Bi 2O 2 layers display various properties due to stereoactive Bi-ions. Bi 2O 2-based oxyhalides are promising visible-light photocatalysts, where several strategies have been demonstrated to control the valence band maximum
Susan T. Krueger, Joseph E. Curtis, Daniel R. Scott, Alexander Grishaev, Greg Glenn, Gale Smith, Larry Ellingsworth, Oleg Borisov, Ernest Maynard
Globally, respiratory syncytial virus (RSV)is a major cause of sever lower respiratory tract infection in young children, older adults, and immune compromised populations, for which there are no licensed vaccines. The RSV fusion (F)/polysorbate 80 (PS80)
Adrian Sanchez-Fernandez, Anna E. Leung, Elizabeth Kelley, Andrew J. Jackson
Here the microstructure of hydrotrope-surfactant assemblies in 1:2 choline chloride:glycerol (ChCl:Glyc) is presented. The effect of choline salicylate (ChSal) on the micellization of hexadecyltrimethylammonium chloride (C 16TAC) was investigated by
Po-Ya A. Chuang, Md A. Rahman, Felipe Mojica, Daniel S. Hussey, David L. Jacobson, Jacob LaManna
Despite recent advancement in fuel cell technology, significant challenges remain in achieving high power density operation to meet the stringent targets of performance, durability and cost. This is due to the lack of fundamental understanding in
The surface adsorption of BSA in pure water and salted aqueous solutions was studied by neutron reflection. With contract match technique, the surface excess in null reflect water as a function of protein concentration was revealed. It is found that, in a
Jason K. Lee, ChungHyuk Lee, Kieran F. Fahy, Pascal J. Kim, Jacob LaManna, Eli Baltic, Daniel S. Hussey, David L. Jacobson, A Gago, S Kolb, K Friedrich, Aimy Bazylak
Decarbonizing society's energy infrastructure is foundational for a sustainable future and can be realized by harnessing renewable energy for clean hydrogen and on-demand power with fuel cells. Here, we elucidate how graded porous transport layers (PTLs)
Maria Queralt-Martin, David Hoogerheide, Sergei Y. Noskov, Alexander M. Berezhkovskii, Tatiana Rostovtseva, Sergey Bezrukov
The voltage-dependent anion channel, VDAC, is the most abundant protein in the mitochondrial outer membrane and an archetypical β-barrel channel. Here, we study the effects of temperature on VDAC channels reconstituted in planar lipid membranes at the
Hector Vivanco, Benjamin Trump, Craig Brown, Tyrel M. McQueen
The Kitaev model is a rare example of an analytically solvable and physically instantiable Hamiltonian yielding a topological quantum spin liquid ground state. Here we report signatures of Kitaev spin liquid physics in the honeycomb magnet Li 3Co 2SbO 6
Hisan W. Shafaque, ChungHyuk Lee, Kieran F. Fahy, Jason K. Lee, Jacob LaManna, Eli Baltic, Daniel S. Hussey, David L. Jacobson, Aimy Bazylak
Despite the advantages of CO2 electrolyzers, efficiency losses due to mass and ionic transport across the membrane electrode assembly (MEA) are critical bottlenecks for commercial-scale implementation. In this study, more efficient electrolysis of CO2 was
Christina A. McConville, Yunwen Tao, Hayden Evans, Benjamin Trump, Jonathan B. Lefton, Wenqian Xu, Andrey A. Yakovenko, Elfi Kraka, Craig Brown, Tomce Runcevski
Benzene and acetonitrile are two of the most commonly used solvents found in almost every chemical laboratory. Titan, Saturn's icy moon, is one other place in the Solar system that has even larger amounts of these compounds, together with many other
The structural relaxation in water solutions of kosmotrope - structure maker and chaotrope - structure breaker salts, namely sodium chloride, potassium chloride, and cesium chloride, were studied through quasielastic neutron scattering measurements. We
Protein therapeutics typically require a concentrated protein formulation, which can lead to self-association and/or high viscosity due to protein-protein interaction (PPI). Excipients are often added to improve stability, bioavailability, and
Rolf L. Zeisler, Danyal J. Turkoglu, Nicholas Sharp, Huaiyu Chen-Mayer
Traditional instrumental neutron activation analysis (INAA) subjects a sample to in- or near- reactor irradiation to determine concentrations of trace and major elements in a variety of matrices. Depending on the facility-specific neutron spectrum for INAA
Keith Bethune, Jean St-Pierre, Jacob LaManna, Daniel S. Hussey, David L. Jacobson
Several experimental methods were used to identify the cause of the concurrent increase in kinetic and mass transfer overpotentials during the contamination of proton exchange membrane fuel cells outfitted with a commercially relevant cathode catalyst
Dagan C. Marx, Ashlee M. Plummer, Anneliese M. Faustino, Taylor Devlin, Michaela A. Roskopf, Mathis J. Leblanc, Henry J. Lessen, Barbara T. Amann, Patrick J. Fleming, Susan T. Krueger, Stephen D. Fried, Karen G. Fleming
The periplasmic chaperone network ensures the biogenesis of bacterial outer membrane proteins (OMPs) and has recently been identified as a promising target for antibiotics. SurA is the most important member of this network, both due to its genetic
Qilong Gao, Xinwei Shi, Alessandro Venier, Qingzhen Huang, Hui Wu, Jun Chen, Andrea Sanson, Erjun Liang
The understanding of the role of guest molecules in the lattice void of open-framework structures is vital for thermal expansion tailoring. Here, we take a new NTE compound, TiCo(CN) 6 as a case study from the local structure perspective to investigate the
Elizabeth Kelley, Michihiro Nagao, Paul Butler, Lionel Porcar, Bela Farago
Like many soft materials, lipids undergo a melting transition associated with a significant increase in their dynamics. At temperatures below the main melting transition (T m), all molecular and collective dynamics are suppressed, while above T m the alkyl
Dagan C. Marx, Mathis J. Leblanc, Ashlee M. Plummer, Susan T. Krueger, Karen G. Fleming
SurA is thought to be the most important periplasmic chaperone for outer membrane protein biogenesis. Its structure is composed of a core region and two peptidylprolyl isomerase domains, termed P1 and P2, connected by flexible linkers. As such these three
Gregory R. Lorzing, Krista P. Balto, Alexandra M. Antonio, Benjamin Trump, Craig Brown, Eric D. Bloch
Ru-HKUST-1 (Ru 3(btc) 2X 1.5; btc 3– = 1,3,5-benzentricarboxylate; X –^ = chloride, acetate, trimesate) has received considerable attention as a result of its structure type, tunability, and the redox-active nature of its constituent metal paddlewheel
Elizabeth Kelley, Paul Butler, Rana Ashkar, Robert Bradbury, Michihiro Nagao
The elastic and viscous properties of biological membranes play a vital role in controlling cell functions that require local reorganization of the membrane components as well as dramatic shape changes such as endocytosis, vesicular trafficking, and cell
Y.- Y. Jau, Daniel S. Hussey, Thomas R. Gentile, Wangchun Chen
We experimentally demonstrate that electrically neutral particles, neutrons, can be used to directly visualize the electrostatic field inside a target volume that can be physically isolated or occupied. Electric field images are obtained using a spin
Jason K. Lee, ChungHyuk Lee, Kieran F. Fahy, Pascal J. Kim, Kevin Krause, Jacob LaManna, Eli Baltic, Daniel S. Hussey, David L. Jacobson, Aimy Bazylak
Mass transport losses ultimately suppress gas evolving electrochemical energy conversion technologies, such as fuel cells and carbon dioxide electrolyzers, from reaching the high current densities needed to realize commercial success. In this work, we
A traveling wave or wave packet may possess orbital angular momentum in the form of a phase vortex about its axis of propagation. These orbital angular momentum states are a general wave phenomenon, and, as such, can be realized for individual wave packets