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Wendy H. Carande, Andrei F. Kazakov, Chris D. Muzny, Michael D. Frenkel
Knowledge of vapor-liquid equilibrium properties (such as critical constants and phase boundary pressure) is essential to understanding thermodynamic behavior of substances and is often required in practical process design applications. Where experimental
Keith A. Gillis, James B. Mehl, James W. Schmidt, Michael R. Moldover
With calibrations of large flow meters in mind, we established the feasibility of determining the mass Mof argon gas contained within a 0.3 m 3 commercially manufactured pressure vessel ("tank") with a relative uncertainty of u r(M) = 0.0015 at 0.6 MPa by
Michael R. Moldover, James W. Schmidt, Keith A. Gillis, James B. Mehl, John D. Wright
Using microwave techniques that are scalable to very large volumes, we measured the interior volume of a 0.3 m 3, commercially-manufactured, pressure vessel with an uncertainty of 0.05 %, as confirmed by independent, more-accurate, gas-expansion
We describe the principles, techniques, and performance of acoustic resonators used to measure the shear viscosity, the thermal conductivity, and the bulk viscosity in gases. We developed the Greenspan acoustic viscometer at NIST, where colleagues used it
Viscosity-ratio measurements made with capillary viscometers exploit the accurate values of the viscosity of helium resulting from ab initio calculations. Accurate values of the argon-to-helium viscosity ratio are now used for primary acoustic thermometry
We describe a flow meter for gas flows in the range from 0.01 sccm to 100 sccm with a relative standard uncertainty of 0.03 % at 1 sccm. (1 sccm ≈ 1 cm3/min of an ideal gas at 101325 Pa and 0 C ≈ 0.7 mol/s.) The flow meter calibrates a secondary meter by
Viscosity-ratio measurements made with capillary viscometers exploit the accurate values of the viscosity of helium calculated ab initio. Accurate values of the argon-to-helium viscosity ratio are now used for primary acoustic gas thermometry and for the
Iosif I. Shinder, Christopher J. Crowley, Bernard J. Filla, Michael R. Moldover
We discuss five significant improvements to the Air Speed Calibration Service conducted by the National Institute of Standards and Technology (NIST): 1. Reduced-uncertainty calibrations of the secondary standard [Laser Doppler Anemometer, (LDA)] using a
Hong Lin, Keith A. Gillis, XiaoJuan Feng, Michael R. Moldover, J.P. Sun, J.T. Zhang, Y.Y. Duan
We report improvements to our previous [Zhang et al., Intl. J. Thermophysics, 32, 1297 (2011)] determination of the Boltzmann constant kB using a single 80 mm-long cylindrical cavity. In this work, the shape of the gas-filled resonant cavity is closer to
Desorption electro-flow focusing ionization (DEFFI), a desorption-based ambient ion source, was developed and evaluated as a possible source for field deployable ambient pressure mass spectrometry (APMS). DEFFI, based on an electro-flow focusing system
Christopher J. Crowley, Iosif I. Shinder, Michael R. Moldover
Abstract- Accurate calibrations of multi-hole Pitot tubes require thousands of measurements spanning ranges of the fluids velocity, and the pitch and yaw angles. When calibrating a commercially-manufactured multi-hole Pitot tube in NISTs low-turbulence
Vladimir Diky, Robert D. Chirico, Chris D. Muzny, Andrei F. Kazakov, Kenneth G. Kroenlein, Joe W. Magee, Ilmutdin M. Abdulagatov, Carlos A. Diaz-Tovar, Jeong W. Kang, Rafiqul Gani, Michael D. Frenkel
ThermoData Engine (TDE) is the first full-scale software implementation of the dynamic data evaluation concept, as reported in this journal. The present paper describes the first application of this concept to the evaluation of thermophysical properties for
Andrei F. Kazakov, Mark O. McLinden, Michael D. Frenkel
We present a systematic search for new classes of refrigerants that would possess low values of Global Warming Potential (GWP), along with low- to moderate flammability and suitable thermodynamic characteristics. We have developed new methods for
Matthew E. Staymates, Wayne Smith, Eric S. Windsor
Swipe-based explosive trace detectors rely on thermal desorption to vaporize explosive particles collected on a swipe. The vaporized material is carried by air flows from the desorption unit to the inlet of the chemical analyzer, typically an ion mobility
The bilateral comparison between NIM and NIST for gas flow was conducted from June 2008 to October 2009. Two critical flow venturis (CFVs) with nominal throat diameters of 10 mm and 20 mm, respectively, were selected as transfer standards. The CFVs were
Accurate gas properties are needed to take full advantage of the low uncertainties provided by NISTs Gas Flow Calibration Services. If a flowmeter user and NIST use different values for these properties (molecular mass, compressibility, density, viscosity
We used NIST's primary water flow standard to study the feasibility of accurately determining mass flow rates m dot of water "dynamically," that is from the time derivative of the weight W of the collection tank: m dot,dynamic = (dW/dt)/g. When data for a
The decomposition kinetics of the kerosene-based rocket propellants RP-1 and RP-2 was studied. For RP-2, decomposition reactions were performed at 375, 400, 425, and 450 °C. For RP-1, decomposition reactions were only performed at 450 °C because we had
The thermal decomposition of RP-2 with three potential stabilizing additives was investigated. The additives were 1,2,3,4-tetrahydroquinoline (THQ), 1,2,3,4-tetrahydronaphthalene (tetralin) and the additive package that is used to make JP-8+100 (herein
Critical flow venturis (CFVs) can be used to measure flow under transient pressure, temperature, and flow conditions with k=2 uncertainties of 0.4 % or less. Blow-down tests transferred 630 g of nitrogen during a 100 s interval from an unregulated cylinder
Measurements of the flow and the energy content of natural gas rely on equations of state to compute four thermodynamic properties: 1) compressibility factor; 2) critical flow factor; 3) speed of sound; and 4)isentropic exponent. We compare these computed
We report progress in testing a dynamic gravimetric standard using both steady and unsteady water flows. For steady flows in the range 10 kg/s to 60 kg/s, the difference between the dynamic standard and NIST s static primary standard was 0.015 % with a
The calculation of natural gas viscosity has been implemented many different ways including the use of constants. Different methods of calculating natural gas viscosity may produce values with differences as large as 50%. Increasing natural gas prices