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The effect of Sb5+ substitution on the crystal chemistry and dielectric properties of Ba3MNb2-xSbxO9 (M = Mg, Zn, Ni) was investigated using a combination of X-ray and neutron powder diffraction, and dielectric property measurements at microwave
The preparation, modeled and refined crystal structures, and structure-dielectric property relationships of five Ba3MM 2O9 (M = Mg, Ni, Zn; M = Nb, Ta) perovskites are reported. Crystal structure modeling was used to generate initial structure models for
Crystallography has a long and successful history of self-organization and was one of the first areas to create numerical scientific databases. Virtually all structure determinations have been archived in databases that allow ready access and complete
Winnie Wong-Ng, James A. Kaduk, Debra L. Kaiser, Julia Frank
This paper reports an investigation of the homogeneity range, crystal chemistry and crystallography of a technologically-important (Ba2-xSrx)TiO4 solid solution series. Since the end members of the series - Ba2TiO4 (Pnma (No.62)) and Sr2TiO4 (I4/mmm (No
Biomaterials are nonviable materials used in medical devices, that are intended to interact with biological systems. In 2002 the total U.S. Medical device market stood at $77 billion, with global sales estimated at 2-3 times this figure. Approximately 40
TEM has been used to characterize residual defect structures produced in 111} Si and 001] MgO by Berkovich nanoindentation at loads ranging from 5 mN to 0.1 mN. The plane-section observations provide a description of the primary defects, found to be
A Method is described for reconstructing the crystal habit from the observations of many random planar sections of known orientation. We have generated simulated observations based on five different assumed crystal habits and found that it is possible to
K Zhang, G Rosenbaum, R Liu, G Bunker, C Y. Liu, Daniel A. Fischer
The development of Multilayer Analyzer Array Detector (MADD) for X-ray fluorescence is to eliminate the count rate limitation encountered with the multi-element Ge detector. A 24-element multilayer detector has been fabricated which is tunable in a large
Igor Levin, M Stennett, I Reaney, G Miles, D I. Woodward, C Kirk, A R. West
The structure and dielectric properties of a new family of tetragonal tungsten bronze structured ceramics with the general formula, Ba 2ReNb 3Ti 2O 15 (BReNTO 15,Re=Bi 3+,La 3+,Nd 3+,Sm 3+,Gd 3+) have been investigated. BLNTO15 Tmax -100 C) and BBNTO15
Atomic force microscopy measurements of the piezoelectric response of a lead zirconate titanate (PZT) thin film detect domain pinning sites along grain boundaries. The locations of these sites are reproducible and 180 degrees domains appear to extend from
The Frank-Bilby equation (FBE) can give many solutions for the dislocation content of a grain boundary (GB); most of them are considered to have little physical reality except in limited ranges of the angles which characterize low-angle GBs. We explore two
Interface wear behavior and its effects on the shear frictional sliding resistance in fiber-reinforced ceramics have been studied using SiC fiber (SCS-6)-reinforced A1203 matrix composite. Thin specimen pushout tests were performed and surface wear
Mechanisms of energy dissipation during solid-solid and solid-liquid friction are discussed. A conservative van der Waals adhesion force, when combined with surface imperfectness, such as deformation, leads to adhesion histeresis (AH). When an asperity
We have uncovered the fact that colloidal probes often have random surface features which when not properly accounted for, can significantly affect the magnitudes of the measured adhesive forces using atomic force microscopes (AFM). Colloidal probes have
Julia Slutsker, Igor Levin, Jiying Li, Andrei Artemev, Alexander L. Roytburd
The theoretical and experimental studies of self-assembled multiferroic nanostructures in epitaxial films were combined to reveal the dominant role of elastic interactions, as caused by expitaxial stresses during growth, in defining the nanostructure
Wear tests were conducted using a pin-on-disk tribometer to evaluate the effect of disk track diameter on the tribological behavior. High purity alumina balls were used as pins sliding against glass-ceramic (IPS empress 2) disks under distilled water
This paper addresses issues of fracture for materials in which large grains, exist in a matrix of much smaller grains. Materials used for optical components, such as ZnS and ZnSe frequently fall into this category. For materials of this sort failure can
Boundary migration of ZnO has been investigated using single crystals with defined crystallographic orientations. The migration rate of the basal C planes depended on the crystallographic polarity: Zn-terminated positive (0001)-planes. The migration in the
ramic thermal barrier coatings (TBC) can exhibit premature in-service failure due to spallation as a consequence of exposure to elevated temperatures, aggressive environments, and cyclic loading. Lifetime assessment for TBC-systems requires methods for
The hole mobility and carrier lifetime of [alpha] mercuric iodide high energy radiation detectors have been enhanced through crystal growth in microgravity. The improvement is closely correlated with specific characteristics of the crystal lattice, which
NASA=S interest in tracing the structural origins of the superior electronic performance of mercuric iodide crystals grown in microgravity has led to an unusually productive series of imaging experiments at Brookhaven. High resolution diffraction imaging
Over the past few years, there has been increased attention paid by ceramic manufacturers in the United States to environmental issues facing their businesses. In a recent survey of its members, the environment was identified as the primary issue facing
Secondary creep in tension was characterized by power-law functions of stress that were evaluated from load-point displacement on four-point flexure specimens and published compressive creep data for two ceramic materials. The flexural creep of 99 % mass
Joseph Woicik, E J. Nelson, L Kronik, M Jain, J R. Chelikowsky, D Heskett, L E. Berman, G S. Herman
X-ray photoelectron spectroscopy (XPS) has emerged as a premier method by which to study the chemical bonding in solids. Owing to the conservation of energy between the incident photon and the ejected photoelectron, XPS has provided much direct and