An official website of the United States government
Here’s how you know
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you’ve safely connected to the .gov website. Share sensitive information only on official, secure websites.
Igor Levin, Leonid A. Bendersky, James P. Cline, Robert S. Roth, Terrell A. Vanderah
Four Ca 4Nb 2O 9 polymorphs with perovskite-related A(B' 1/3B 2/3)O 3 structures and different arrangements of B-site cations were identified and characterized by X-ray powder diffraction and transmission electron microscopy. The B-cation ordering in three
The phase diagram of the SrO-R 2O 3-CuOx system, where R=Ho, was investigated in air. The tie-line relationships of this system were determined. Two ternary phases were found, namely, the green phase SrHo 2CuO 5 and the A14-24 solid solution (Sr 14-xHo x
Julia Y. Chan, Terrell A. Vanderah, Robert S. Roth, Winnie Wong-Ng, B A. Reisner, Richard G. Geyer
The structure and dielectric properties of bulk ceramics in the xCa2AlNbO6: (1-x)Ca3Nb2O8 system were studied. Ca2AlNbO6 (P21/n, a = 5.3785(1) , b = 5.4158(1) , c = 7.6259(1) , b = 89.93(1)o) is a double perovskite with structure similar to CaTiO3 and
Julia Y. Chan, Igor Levin, Terrell A. Vanderah, Richard G. Geyer, Robert S. Roth
Subsolidus phase equilibria in the SrO-Al 2O 3-Nb 2O 5 system were determined by synthesis of 75 compositions in air in the temperaturerange 1200-1600 C. Phase assemblages were determined by X-ray powder diffraction at room temperature. Two new ternary
Jan Genzer, E Sivaniah, E K. Kramer, J G. Wang, H Koerner, K Char, Christopher K. Ober, B M. DeKoven, Robert A. Bubeck, Daniel A. Fischer, S Sambasivan
Near-edge X-ray absorption fine structure is used to investigate the temperature dependence of molecular orientation of semi-fluorinated liquid crystalline (SF-LC) mesogens, which are attached to the modified isoprene backbone of i) a polyisoprene
Using Brillouin scattering, we have determined the five independent elastic constants of Β-Si 3N 4 single crystals. They are (in units of GPa) c 11 = 433(3), C 33=574(3), c 13 = 127(5), c 44 = 108(2), C 66 =119(4), and C 12 = C 11-2c 66 = 195(8), giving a
Fully relaxed, planewave pseudopotential calculations of formation energies (δE) were performed for ordered supercells in the perovskite based system (1 - X) PbNbO 3 - (X).PbMgO 3, including six different supercells at the X = 1/3 composition [Pb(Mg 1/3Nb
L Gamble, J R. Long, P S. Stayton, Daniel A. Fischer, S Sambasivan, David G. Castner
The orientation of surface bound proteins may play an important role in the function and properties of materials to which they are adsorbed. Near edge absorption fine structure (NEXAFS) is a technique which allows the user to determine the presence of
M Widom, I Al-Lehyani, Yijun Wang, Eric J. Cockayne
We perform ab-initio total energy calculations for approximants to a model of decagonal A1CoCu. These calculations support previously proposed chemical ordering of Co and Cu atoms along tile edges. Preferred arrow orientations are identified and shown to
We present a columnar cluster with 46 atoms per repeat distance which forces a quasicrystal when space is filled by interpenetrating copies of itself. The atomic positions in the resultant quasicrystal are remarkably similar to those in models for real
We have computed the frequencies of selected normal modes in perovskite PbZrO 3 (PZ) as a function of lattice parameter using local density functional theory variational linear response. The most significant instabilities that freeze in to give the
A M. Gabelnick, A T. Capitano, D J. Burnett, Daniel A. Fischer, J L. Gland
The catalytic oxidation of propylene with both propylene and oxygen in the gas phase has been characterized on the Pt(111) surface. In situ soft x-ray kinetic and spectroscopic measurements using fluorescence detection have been used to characterize this
K J. Yoon, Sheldon M. Wiederhorn, William E. Luecke
The creep behavior of most commercial grade of Si 3N 4 was studied at 1350 and 1400 C. Stresses ranged from 10 to 200 Mpa in tension and from 30 to 300 Mpa in compression. In tension, the creep rate increased linearly with stress at low stresses and
By detecting valence-photoelectron under condition of strong x-ray Bragg reflection, we have determined that a majority of GaAs valence charge resides on the anion sites of this heteropolar crystal, in quantitative agreement with the Ga-As bond polarity as
J A. Gupta, S P. Watkins, E D. Crozier, Joseph Woicik, D A. Harrison, D Jiang, I J. Pickering, B A. Karlin
X-ray diffraction (XRD), X-ray standing wave (XSW) and X-ray absorption fine structure (XAFS) measurements were used to assess the layer perfection and positions of 1 and 2 monolayer (ML) InAs quantum wells buried in GaAs(001). Photoluminescence (PL)
A Fatigue damage accumulation model based on the Paris law has been proposed for strain rate-sensitive polymer composite materials. A pre-exponent factor c 2/f and strain-rate sensitive exponent n is introduced. Numerical analysis of the model has been
A M. Gabelnick, A T. Capitano, S M. Kane, J L. Gland, Daniel A. Fischer
The oxidation of propylene on the Pt(111) surface has been characterized in oxygen pressures up to 0.02 torr using fluorescence yield near -edge spectroscopy (FYNES) and temperature programmed fluorescence yield near-edge spectroscopy (TP-FYNES) above the
J A. Rodriguez, T Jirsak, J Dvorak, S Sambasivan, Daniel A. Fischer
Synchrotron-based high-resolution photoemission and x-ray absorption near-edge spectroscopy (XANES) have been used to study the interaction of NO 2 with polycrystalline surfaces of metallic zinc and zinc oxide. NO 2 exhibits a complex chemistry on metallic
Igor Levin, Leonid A. Bendersky, Robert S. Roth, Terrell A. Vanderah
Four Ca 4Nb 2O 9=Ca(Ca1/3Nb 2/3)O 3 polymorphs based on ABO 3 perovskite-like structure were identified. These polymorphs feature three different arrangements of Ca/Nb cations on B-sites of perovskite. In three of the polymorphs, cation ordering is
Ceramics are increasingly being considered for wear resistant applications. The design and prediction of ceramics wear, however are lacking behind metals. This paper addresses the ability to predict wear of ceramics by examining a large data base of four
M C. Shen, Stephen M. Hsu, John A. Tesk, A Christou
A versatile wear tester has been designed and built. The initial study showed that that with this tester, tes procedures can be developed to achieve clinically relevant simulations in a short time. With the continuously monitored force traces, this tester
C I. Lang, Frank S. Biancaniello, Stephen D. Ridder, D Shechtman
Powders for thermal spray coating were produced by gas atomization in NIST's Supersonic Inert Gas Metal Atomizer (SIGMA). Bulk speciments were produced by Hot Isostatic Press (HIP) consolidation at NIST, and plasma sprayed coatings were produced at Ames
Bruce D. Ravel, Eric J. Cockayne, E Newville, K M. Rabe
The narrow band-gap semiconductor Pb 1-xGe xTe has a low-temperature ferroelectric rhombohedral phase whose average structure is a distorted rocksalt structure. We have measured the Extended X-Ray-Absorption Fine-Structure (EXAFS) spectra of Pb 1-xGe xTe
D K. Kim, Yeon-Gil G. Jung, I M. Peterson, Brian R. Lawn
Contact damage modes in cyclic loading with spheres are investigated in three relatively brittle ceramics, soda-lime glass, porcelain and fine-grain silicon nitride, in moist environments. Initial damage at small numbers of cycles and low loads consists of