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Jessica M. Torres, Chengqing C. Wang, E. B. Coughlin, John P. Bishop, Richard A. Register, Robert A. Riggleman, Christopher Stafford, Bryan D. Vogt
The effect of main chain stiffness and side chain flexibility on the elastic modulus and glass transition temperature (Tg) of thin polymer films is investigated using non-traditional polymers formed from 5-(2-phenylethylnorbornene). Depending on the
Albert Davydov, G. Jacopin, S. Bellei, Denis Tsvetkov, Kristine A. Bertness, L. Rigutti, Norman A. Sanford, John B. Schlager, M. Tchernycheva, F. H. Julien
Over the past decade, core-shell nanowires (NWs) have been intensively used as the building blocks of novel optoelectronic devices as solar cells [1], LEds [2], naolasers [3]. Indeed, this geometry not only allows to passivate surface states, but also
Romil Bhandavat, William Kuhn, Elisabeth Mansfield, John H. Lehman, Gurpreet Singh
We demonstrate synthesis of a polymer-derived ceramic (PDC)-multiwall carbon nanotube (MWCNT) composite using microwave irradiation at 2.45 GHz. The process takes about 10 minutes of microwave irradiation for the polymer to ceramic conversion. The
Carl G. Simon Jr., Kaushik Chatterjee, Christopher K. Tison, Girish Kumar, Patrick S. Pine, Marc L. Salit, Jennifer H. McDaniel, Marian F. Young
Cells are sensitive to tissue scaffold architecture and these cell-material interactions drive cell functions critical in tissue regeneration. Results presented here demonstrate that nanofiber scaffolds force primary human bone marrow stromal cells (hBMSCs
Guillaume Messin, Stephanie S. Watson, Amanda L. Forster, John R. Sieber
In recent years, there has been concern in the soft body armor community that copolymer fibers based on 5-amino-2-(p-aminophenyl)-benzimidazole can release hydrochloric acid, which could potentially be detrimental to other fibers that might come in contact
Christopher C. White, Donald L. Hunston, Kar T. Tan, James J. Filliben
Previous industry consensus postulated that four elements of the weather: Temperature, Humidity, Ultraviolet Radiation, and Mechanical loading were responsible for the majority of the changes observed in sealants exposed to outdoor weathering. The NIST
Christopher L. Soles, Hyun W. Ro, A. Wood, N. Estrada, B. Dick, Y. Wang, Micheal Thouless, Rachel Goldman
Nanostructured materials with ultra-small crystallites (approaching the exciton Bohr radius) embedded in a solid-state matrix have great potential for optoelectronic and energy-conversion applications owing to the possibility of invoking quantum effects
Matthew R. Hammond, Regis J. Kline, Andrew A. Herzing, Lee J. Richter, David Germack, Hyun W. Ro, Christopher L. Soles, Daniel A. Fischer, Tao Xu, Luping Yu, Michael F. Toney, Dean M. DeLongchamp
We report quantitative measurements of ordering, molecular orientation, and nanoscale morphology in the active layer of bulk heterojunction organic photovoltaic cells based on a thieno[3,4-b]thiophene-alt-benzodithiophene copolymer (PTB7), which has been
Edwin Chan, Joseph J. Walish, Edwin L. Thomas, Christopher Stafford
In this work, we describe a strategy based on mechanochromic sensing, the coupling between mechanical and optical properties, of a block copolymer photonic gel. Although this phenomena has been observed in many materials, we demonstrate this concept for
Jeffrey W. Hudgens, John M. Pettibone, Thomas P. Senftle, Ryan N. Bratton
This report outlines the determination of a reaction mechanism that can be manipulated to develop directed syntheses of gold monolayer protected clusters (MPCs) prepared by the reduction of solutions containing 1,3-bis(diphenylphosphino)propane (L 3)
Jean-Yves Chauleau, Benjamin James McMorran, R. Belkhou, Nicolas Bergeard, Tevfik Mente?, Miguel Angel Nino, Andrea Locatelli, John Unguris, Stanislas Rohart, Jacques Miltat, Andre Thiaville
We have observed peculiar magnetization textures in Ni80Pd20 nanostructures, by three different imaging techniques (MFM, XMCD-PEEM and SEMPA). The appearance of diamond-like domains with strong lateral charges, and of weak stripes structures brings into
Eric L. Shirley, Maria K. Chan, Naba Karan, Mahalingam Balasubramanian, Yang Ren, Jeffrey P. Greeley, Timothy T. Fister
The reliable identification of lithium oxides species, especially lithium peroxide (Li2O2), is of vital importance to the study of Li-air batteries. Previous x-ray diffraction studies of Li2O2 resulted in the proposal of two disparate structures by Féher
Constantine Y. Khripin, Nicholas A. Arnold-Medabalimi, Ming Zheng
Emerging applications require single-wall carbon nanotubes (SWCNTs) of welldefined length. Yet the use of length-defined SWCNTs is limited, in part due to the lack of an easily accessible materials preparation method. Here, we present a new strategy for
The objective of this study is to investigate the influence of the filler dispersion of nano-TiO2 in polymeric coatings on the surface morphology evolution of the coatings under UV exposure. Two types of nano-TiO2 with different surface treatments were
This chapter presents a summary of the information and reasoning needed to justify learning about peridynamics for the purpose of analyzing electromigration and provides guidance for the development of a complete peridynamics analysis. The additions needed
Edwin P. Chan, Yuhang Hu, Peter M. Johnson, Zhigang Suo, Christopher M. Stafford
Recently, an indentation approach has been demonstrated to quantify the poroelastic relaxations of hydrogels. Although the approach has been demonstrated to quantify the transport properties of thick hydrogel materials, its relevance for thin hydrogel
We develop a set of computationally efficient and accurate interatomic interactions for an atomistic simulation of the properties of graphene on nickel surface. The approach is based on the modified embedded atom method (MEAM) for the C-C and Ni-Ni
Biofilm density, porosity, and thickness are biofilm architecture properties that are important but often difficult to measure. In this study, wet and dry biofilm densities and biofilm porosity in shredded tire biofilters were determined using conventional
Measurements of liquid permeation through freestanding Parylene C membranes were made using a high- performance testing system, which demonstrated fast response (≤ 30 seconds) to changing concentrations in the sweep gas stream and detectability of less
Rick D. Davis, Yeon S. Kim, Richard H. Harris Jr., Marc R. Nyden, Nasir M. Uddin, Treye Thomas
An innovative technology was evaluated to generate fire and health safe soft furnishings. Nanoparticle-based thin coatings on a polyurethane foam and nonwoven barrier fabric were applied using Layer-by-layer (Lbl) assembly. This is the first report of
Jan Obrzut, Bernd Schumacher, Heinz-Gunter Bach, Petra Spitzer
The dielectric properties of materials are used to describe electrical energy storage, dissipation and energy transfer. The most relevant physical processes in dielectric materials from the practical view point are those which result in power loss
Joseph T. Hodges, David A. Long, Daniel K. Havey, S. S. Yu, M Okumura, Charles E. Miller
Frequency-stabilized cavity ring-down spectroscopy (FS-CRDS) was employed to measure over 100 transitions in the R-branch of the b1Σg+←X3Σg-(0,0) band for the rare O2 isotopologues. The use of 17O- and 18O-enriched mixtures allowed for line positions to be