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In this Letter we derive a new representation of the free energy of polymer mixing. We begin with a Flory-Huggins-like free energy of mixing, and assume that the excess free energy of mixing exhibits an arbitrary dependence on the blend composition that
Jack F. Douglas, Alamgir Karim, Arvind Arvind Modi1, Sarang Bhaway, Bryan D. Vogt, Abdullah Al-Enizi, Ahmed Elzatahry, Ashutosh Sharma
We demonstrate that direct immersion annealing (DIA) greatly enhances the rate at which block copolymer (BCP) films order into stable morphologies when the BCP films are immersed in carefully selected mixtures of good and marginal solvents that can impart
Gold electrodeposition was studied in a sulfite electrolyte to which micromolar concentrations of Tl2SO4 were added. Hysteresis and a regime of negative differential resistance (NDR) evident in electroanalytical measurements are correlated with deposit
Kaya Wei, Laura Beauchemin, Hsin Wang, Joshua Martin, George S. Nolas
Gallium doped Cu2ZnSnSe4 quaternary chalcogenides with and without excess Cu have been synthesized by elemental reaction and densified using hot pressing in order to investigate their high temperature thermoelectric properties. The resistivity, ρ, and
Although the scaling theory of polymer solutions has had many successes, this type of argument is deficient when applied to hydrodynamic solution properties. Since the foundation of polymer science, it has been appreciated that measurements of polymer size
Sara V. Orski, Richard J. Sheridan, Edwin P. Chan, Kathryn L. Beers
The stimuli-responsive behavior of densely grafted polymer brushes makes them attractive for designing tunable coatings and thin film sensors, provided physical properties and thermodynamics of the brush are well characterized. This work investigates the
Chad R. Snyder, Regis J. Kline, Dean M. DeLongchamp, Ryan C. Nieuwendaal, Lee J. Richter, Martin Heeney, Iain McCulloch
Semiconducting polymers form a variety of phases and mesophases that respond differently to post-deposition solvent or thermal treatments. Here it is shown that classification of these materials into their appropriate mesophases can be a useful tool to
Karl Fabian, V P. Shcherbakov, S. McEnroe, P. Robinson, Benjamin P. Burton
By rigorously deriving A spatially averaged mean-field model for fully or partially ordered members of the ilmenite-hematite solid solution series is rigorously derived from the Heisen-berg Hamiltonian by first assuming no temporal correlation of atomic
Materials and photoelectrode architectures that are highly efficient, extremely stable, and made from low cost materials are required for commercially viable photoelectrochemical (PEC) water-splitting technology. A key challenge is the heterogeneous nature
Heat transfer through thermal barrier coatings (TBCs) composed of alternating nanometer thick layers of aluminum oxide and 7% yttria stabilized zirconia (7YSZ) was studied by pulsed heating at temperatures in the range 1000 °C to 1100 °C. The thermal
Kirt A. Page, Jae W. Shin, Scott Eastman, Brandon W. Rowe, Sangcheol Kim, Ahmet Kusoglu, Kevin G. Yager, Gery R. Stafford
Perfluorinated ionomers, in particular Nafion, are an essential component in hydrogen fuel cells, as both the proton exchange membrane and the binder within the catalyst layer. During normal operation of a hydrogen fuel cell the ionomer will progressively
This work demonstrates how a modular transmission detector can be used to extend the analytical capabilities of a conventional SEM. By implementing a new sample holder and aperture system, we show that high angle and other dark field imaging techniques are
Surya R. Kalidindi, Joshua Gomberg, Zachary Trautt, Chandler Becker
Structure quantification is key to successful mining and extraction of core materials knowledge from both multiscale simulations as well as multiscale experiments. The main challenge stems from the need to transform the inherently high dimensional
Leonid A. Bendersky, Haoting Shen, Kwo Young, Taihei Ouchi
Hydrogen induced amorphization (HIA) of the LaMgNi4 phase at 30C was found in three LaMgNi4/LaNi5 two-phase metal hydride (MH)-forming alloys. The amorphization happened at the first dehydrogenation cycle from a fully hydrided alloy, and the process is
Hans T. Nembach, Justin M. Shaw, Mathias A. Weiler, Emilie M. Jue, Thomas J. Silva
Proposals for novel spin-orbitronic logic and memory devices are often dependent on assumptions as to how materials with large spin-orbit and ferromagnets interact when in contact. Such interactions give rise to a host of novel phenomena, such as spin
Aric W. Sanders, Kavita M. Jeerage, Ann C. Chiaramonti Debay, Alexandra Curtin
Gold nanoparticles (GNPs) are gaining importance as therapeutic chemical delivery vehicles, medical diagnostic tools, phototherapeutic and contrast enhancement agents. GNPs are uniquely suited for these biological uses because of their chemical stability
Ann C. Chiaramonti Debay, Birol Ozturk, Andres de Luna Bugallo, Eugene Panaitescu, Fangze Liu, Anthony Vargas, Xueping Jiang, Ozgur Yavuzcetin, Majed Alnaji, Yongui Zhao, Nicholas King, Madan Dubey, Saroj Nayak, Srinivas Sridhar, Swastik Kar
Atomically thin ternary compounds/alloys of boron, nitrogen and carbon have generated significant excitement as they provided the first instance of a tuneable 2D material that affords rich physics as well applications potentials. Interestingly, the crucial
Jonathan E. Seppala, Yoonae Heo, Paul E. Stutzman, John R. Sieber, Chad R. Snyder, Kirk D. Rice, Gale A. Holmes
Mechanical and thermal properties of Roma Plastilina Clay #1 (RP1) were studied through small-amplitude oscillatory shear (SAOS), large-amplitude oscillatory shear (LAOS), and differential scanning calorimetry (DSC), supplemented with thermogravimetric
Gery R. Stafford, Vijay Sethuraman, Deepa Vairavapandian, Manon C. Lafouresse, Tuhina Maark, Naba Karan, Shouheng Sun, Ugo Bertocci, Andrew Peterson, Pradeep Guduru
The effect of elastic strain on catalytic activity of platinum (Pt) towards oxygen reduction reaction (ORR) is investigated through de-alloyed Pt-Cu thin films; stress evolution in the de-alloyed layer and the mass of the Cu removed are measured in real
Chelsea S. Davis, Danielle L. Grolman, Alamgir Karim, Jeffrey W. Gilman
Cellulosic nanomaterials have the potential to become predominant nanoparticles utilized in materials engineering fields ranging from flexible electronic supports13 and tissue scaffolds4,5 to nanocomposite reinforcement materials69 and aerogels for oil
Kaya Wei, Joshua Martin, James Salvador, George S. Nolas
PbCuSbS3 nanocrystals were synthesized for the first time by a colloidal synthesis route and characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS). The particle size of
Yongkwan Dong, Lukasz Wojtas, Joshua Martin, George S. Nolas
Quaternary chalcogenides with tetrahedral zinc-blend structure types continue to be of interest for thermoelectrics applications. We report on the synthesis, crystal structure, and high temperature transport properties of Cu2.1Fe0.9SnSe4, Cu2.2Fe0.8SnSe4
Christopher C. White, Donald L. Hunston, Kar T. Tan
The toughness of polymer and glass laminates or win-dow glazing, are used to protect buildings and occupants from shattered glass resulting from natural disasters (e.g., hurricanes, tornadoes, seismic events), and intentional events (e.g., robbery