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Materials

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Displaying 1101 - 1125 of 2363

Assessment of PGAA capability for low-level measurements of H in Ti alloy

December 1, 2017
Author(s)
Danyal J. Turkoglu, Huaiyu H. Chen-Mayer, Rick L. Paul, Rolf L. Zeisler
The accuracy of low-level hydrogen measurements with prompt gamma-ray activation analysis (PGAA) depends on identifying and accounting for all background H signal, including interfering signals. At the cold-neutron (CN)PGAA facility at the NIST Center for

Clustering and Percolation in Suspensions of Carbon Black

November 22, 2017
Author(s)
Jeffrey J Richards, Julie Beth Hipp, John K Riley, Norman J. Wagner, Paul Butler
High-structured carbon fillers are ubiquitous as the conductive additive comprising suspension-based electrochemical storage technologies. Carbon black networks provide the necessary electric conductivity as well as mechanical percolation in the form of a

String-like Collective Motion and Diffusion in the Interfacial Region of Ice

November 20, 2017
Author(s)
Jack F. Douglas, Hao Zhang, Xuhang Tong, Xinyi Wang
We investigate the collective molecular motions and diffusion of water molecules in the mobile interfacial region of the secondary prismatic plane of hexagonal ice by molecular dynamics simulation based on the TIP4P/2005 water potential and metrologies of

Sketchnote summary of "The Backscattering Story: A Personal View"

November 16, 2017
Author(s)
Robert M. Dimeo
In August 2014, Dr. Anton Heidemann published a short, personal history of the development of neutron backscattering. His fascinating article 1 described the technical innovations that were made during the development of this technique, and it is

Electronic Conductivity in a Porous Vanadyl Prussian Blue Analogue upon Air Exposure

November 6, 2017
Author(s)
Mary Anne Manumpil, Carmen Leal-Cervantes, Matthew R. Hudson, Craig Brown, Hemamala I. Karunadasa
Exposure to humid oxygen or ambient air affords a 5-or-der-of-magnitude increase in the electronic conductivity of a new Prussian blue analog incorporation Co(II) and V(IV)-oxo units. Oxidation produces a mixed-valence framework, where the oxygen exposure

Synthesis and Transport Properties of Fe2SnSe4

November 2, 2017
Author(s)
Kaya Wei, Joshua Martin, George S. Nolas
Fe2SnSe4 was synthesized by elemental reaction and densified using hot pressing in order to investigate the transport properties. It crystallizes in the orthorhombic space group Pnma with the olivine-type crystal structure. Our report describes results and

Buckling Instabilities in Polymer Brush Surfaces via Postpolymerization Modification

October 30, 2017
Author(s)
Wei Guo, Cassandra M. Reese, Li Xiong, Phillip K. Logan, Brittany J. Thompson, Christopher Stafford, Anton Ievlev, Bradley S. Lokitz, Olga S. Ovchinnikova, Derek L. Patton
We report a simple route to engineer ultrathin polymer brush surfaces with wrinkled and creased morphologies using postpolymerization modification (PPM), where the length scale of the buckled features can be tuned using PPM reaction time and sequence. We

NOVEL ZIRCONIA MATERIALS IN DENTISTRY

October 16, 2017
Author(s)
Yu Zhang, Brian R. Lawn
Zirconias, the most durable of the dental ceramics, are increasingly being fabricated in monolithic form for a range of clinical applications, circumventing issues associated with weak porcelain veneers. Yttria-based tetragonal zirconia polycrystal (Y-TZP)

Structural, Chemical, and Dynamical Frustration: Origins of Superionic Conductivity in closo-Borate Solid Electrolytes

October 11, 2017
Author(s)
Kyoung E. Kweon, Joel B. Varley, Patrick Shea, Nicole Adelstein, Prateek Mehta, Tae Wook Heo, Terrence J. Udovic, Vitalie Stavila, Brandon C. Wood
Li 2B 12H 12 and Na 2B^12^H 12 closoboranes exhibit unusually high ionic conductivity, making them attractive as a new class of candidate electrolytes in solid-state Li- and Na-ion batteries. However, further optimization of these materials requires a

Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes

October 10, 2017
Author(s)
Oleg Borodin, Liumin Suo, Mallory Gobet, Xiaoming Ren, Fei Wang, Antonio Faraone, Jing Peng, Marco Olguin, Marshall Schroeder, Michael S. Ding, Eric Gobrogge, Arthur von Wald Cresce, Stephen Munoz, Joseph Dura, Steve Greenbaum, Chunsheng Wang, Kang Xu
Using molecular dynamics simulations, small angle neutron scattering and a variety of spectroscopic techniques, we evaluated the ion solvation and transport behaviors in aqueous electrolytes containing bis(trifluoromethane sulfonyl)imide (LiTFSI). We

Wrinkling-to-delamination transition in thin polymer films on compliant substrates

October 9, 2017
Author(s)
Adam J. Nolte, Jun Y. Chung, Chelsea S. Davis, Christopher Stafford
Compressing a thin, stiff film attached to a thick, compliant substrate can lead to a number of different modes of mechanical deformation depending upon the material properties of the system. In this article we explore direct transitions from surface

Redox-active Nanomaterials for Nanomedicine Applications

October 6, 2017
Author(s)
Christopher Sims, Shannon Hanna, Daniel A. Heller, Christopher Horoszko, Monique Johnson, Antonio Montoro Bustos, Vytas Reipa, Kathryn Riley, Bryant C. Nelson
Nanomedicine utilizes the remarkable properties of nanomaterials for the diagnosis, treatment, and prevention of disease. Many of these nanomaterials have been shown to have robust antioxidative properties, potentially functioning as strong scavengers of

Film Confinement Induced "Jump-Percolation" Wetting Transition in Amphiphilic Block Copolymer Films

October 1, 2017
Author(s)
Namrata Salunke, Asritha Nallapaneni, Guangcui Yuan, Christopher Stafford, Hui Niu, Matthew D. Shawkey, R. A. Weiss, Alamgir Karim
A sharp surface wettability transition with varying film thickness dependent morphology was observed in cast films of an amphiphilic triblock copolymer comprised of poly(2-(N-ethylperfluotooctanesulfonamido) ethyl methylacrylate), poly(FOSM), and poly(N,N'
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