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Christopher Szakal, David S. Simons, John D. Fassett, Albert J. Fahey
We present the ability to conduct single micrometer-sized uranium particle age-dating measurements on particles that are younger, smaller, and less enriched in 235U content than previously thought to be possible. Specifically, we use large geometry
The trace detection and forensic analysis of fuel-oxidizer mixtures, specifically targeting black powders and black powder substitutes, directly from wipe-based sample collections was demonstrated using infrared thermal desorption (IRTD) coupled with
Anzor I. Mikaia, Levan Megutnishvili, Nino G. Todua, Stephen Stein
A GC-MS method is described for the characterization of thebaol, a component of opium poppy. Themethod includes preliminary sample derivatization to TMS, TBDMS, TFA, PFP and HFB substitutedproducts. Fragmentation of resulting derivatives is unique under
Ambient mass spectrometry has evolved rapidly over the past decade, yielding a plethora of platforms and demonstrating scientific advancements across a range of fields from biological imaging to rapid quality control. These techniques have enabled real
Infrared thermal desorption (IRTD) was coupled with direct analysis in real time mass spectrometry (DART-MS) for the detection of both inorganic and organic explosives from wipe collected samples. This platform generated discrete and rapid heating rates
Thomas P. Forbes, Edward R. Sisco, Matthew E. Staymates, John G. Gillen
An ambient mass spectrometry (AMS) platform coupling Joule heating thermal desorption (JHTD) and direct analysis in real time (DART) was developed, generating discretely pulsed rapid heating ramps and elevated temperatures for the detection of inorganic
Edward R. Sisco, Thomas P. Forbes, Matthew E. Staymates, John G. Gillen
The need to rapidly analyze trace narcotic samples for screening or confirmatory purposes is of increasing desire to the forensic, homeland security, and criminal justice sectors. This work presents a novel method for the detection of trace drugs and
The discriminative potential of an ion trap mobility spectrometer (ITMS) for trace detection of illicit narcotics relative to environmental background was investigated with a receiver operator characteristic (ROC) curve framework. The ITMS response of
Megan Harries, Santiago Bukovsky-Reyes, Thomas J. Bruno
This paper details the sampling methods used with the field portable PLOT-cryoadsorption (PLOT-cryo) approach, described in Part I of this two-part series, applied to several analytes of interest. We conducted tests with coumarin and 2,4,6-trinitrotoluene
Building on the successful application in the laboratory of PLOT-cryoadsorption as a means of sampling vapor samples, in this paper a field portable apparatus is introduced. This device fits inside of an aluminum tool carrier, and can be easily transported
Age dating of fingerprints can have a significant impact in forensic science, as it has the potential to facilitate the judicial process by assessing the relevance of a fingerprint found in a crime scene. However, no reliable method currently exists that
Robert R. Keller, Katherine P. Rice, Mark Stoykovich
Transmission electron backscatter diffraction (t-EBSD), also known as transmission electron forward scatter diffraction (t-EFSD) or transmission Kikuchi diffraction in the SEM (TKD-SEM), can provide significant improvements in spatial resolution over
Based on three dimensional (3D) topography measurements on correlation cells, the National Institute of Standards and Technology (NIST) has developed the "NIST Ballistics Identification System (NBIS)" aimed to accurate ballistic identifications and fast
Cynthia J. Zeissler, Lawrence Forsley, Richard M. Lindstrom, Sean Newsome, Adrean Kirk, P.A. Mosier-Boss
A nondestructive analytical method based on autoradiography and gamma spectrometry was developed to perform activity distribution analysis for particulate samples. This was applied to aerosols collected in Fukushima Japan, 40 km north of the Daiichi
A long-held but untested fundamental assumption in Raman spectroscopy of carbon nanotubes is that intensities arising from resonance with incident and scattered photons are equal. We present here the first complete Raman excitation profiles (REPs) for the
A high quality x-ray spectrum image of a 3.3 μm diameter sphere of K411 glass resting on a copper substrate was collected at 25 keV. The same sample configuration was modeled using the NISTMonte Monte Carlo simulation of electron and x-ray transport as is
Spectrum simulation is a useful practical and pedagogical tool. Particularly with complex samples or trace constituents, a simulation can help to understand the limits of the technique and how to optimize the tools for the optimal measurement. DTSA-II
This document, Forensic Sciences: Status and Needs, is the product of a two-day meeting sponsored by OLES/NIJ/NIST on March 5-6, 1997. This meeting brought together 44 scientists and administrators with the common goal of helping the forensic science
Designing and building a forensic laboratory is a complicated undertaking. Design issues include those considerations present when designing any building, with enhanced concern and special requirements involving environmental health and safety, hazardous