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The relative rates of C-C and C-H β-scission reactions of i-butyl radicals were investigated with shock tube experiments at temperatures of (950 to 1250) K and pressures of (200 to 400) kPa. We produce i-butyl radicals from the decomposition of dilute
Densities of a 50/50 by volume mixture of JP-10 + a turpentine dimer fuel (TDF) have been measured in the compressed-liquid state from 270 K to 470 K, and 0.5 MPa to 45 MPa and at ambient pressure from 263.15 K to 373.15 K. Ambient pressure dynamic
Laura A. Mertens, Iftikhar A. Awan, Jeffrey A. Manion
The reactions of i-butane with CH3 and H were investigated with shock tube experiments (870 K to 1130 K and 140 kPa to 360 kPa). Propene and i-butene, measured with GC/FID and MS, were quantified as characteristic of H-abstraction from the primary and
To provide benchmark information needed to develop kinetic models of the combustion and pyrolysis of hydrocarbon ring structures, we have used the single pulse shock tube technique to study the kinetics of H atom addition to cyclopentene at 863 K to 1167 K
This paper presents new wide-ranging correlations for the thermal conductivity of n-hexadecane based on critically evaluated experimental data. The correlations are designed to be used with a recently published equation of state that is valid from the
The kinetics of H atom addition to cyclopentene has been studied with a single pulse shock tube at temperatures of (863 to 1167 K) and pressures of (160 to 370) kPa. Hydrogen atoms were generated with thermal precursors in dilute mixtures of cyclopentene
In this study, synchrotron-based in-operando multi-scale X-ray scattering analyses are used to connect the microstructural changes to the phase changes in kaolinite on heating from 30 °C to 1150 °C. Combined ultra-small-angle and small-angle X-ray
This paper presents new wide-ranging correlations for the viscosity and thermal conductivity of n-undecane based on critically evaluated experimental data. The correlations are designed to be used with a recently published equation of state that is valid
The thermochemical characteristics were determined for several National Institute of Standards and Technology Standard Reference Material petroleum-based and biodiesel fuels, using a novel laser-heating calorimetry technique. Measurements focused on the
Matthew Connolly, Peter Bradley, Andrew Slifka, Elizabeth S. Drexler
In situ transmission Bragg edge measurements of the strain field were performed near cracks grown in air and in hydrogen. Through the use of a novel test chamber which is capable of pressurization with hydrogen gas, and amenable to neutron-scattering
Michael T. Stocker, Bryan M. Barnes, Martin Y. Sohn, Eric S. Stanfield, Richard M. Silver
Widespread commercialization of proton exchange membrane fuel cells remains curbed by various manufacturing and infrastructure challenges. One such technical barrier identified by the U. S. Department of Energy is the need for high-speed, in-line process
Andrew Slifka, Robert L. Amaro, Devin T. O'Connor, Benjamin E. Long, Elizabeth S. Drexler
In this work, we applied a finite element model to predict the cyclic lifetime of 4130 steel cylinders under the influence of hydrogen. This example is used to demonstrate the efficacy of a fatigue crack growth (FCG) model we have developed. The model was
Andrew Slifka, Robert L. Amaro, Elizabeth S. Drexler, Devin T. O'Connor, Benjamin E. Long
In this work we further develop a model to predict hydrogen-assisted fatigue crack growth in steel pipelines and pressure vessels. This implementation of the model is informed by finite element code, which uses an elastic-plastic constitutive model in
Jessica L. Burger, Tara M. Lovestead, Mark LaFollette, Thomas J. Bruno
Although they are amongst the most efficient engine types, compression-ignition engines have difficulties achieving acceptable particulate emission and NOx formation. Indeed, catalytic after-treatment of diesel exhaust has become common and current efforts
A novel laser-heating technique, referred to as the laser-driven thermal reactor (LDTR), was used to determine sample thermal behavior, specific heat release rate, and total specific heat release of three volatile single-component liquid hydrocarbons, i.e
Matthew J. Connolly, Peter E. Bradley, Andrew J. Slifka, Elizabeth S. Drexler
A gas-pressure chamber has been designed, constructed, and tested at a moderate pressure (3.4 MPa, 500 psi) and has the capability of mechanical loading of steel specimens for neutron scattering measurements. The chamber will allow a variety of in situ
John M. Yarbrough, Ashutosh Mittal, Elisabeth Mansfield, Larry Taylor, Stephen R. Decker, Michael E. Himmel, Todd B. Vinzant
Commercial fungal cellulases used in biomass-to-biofuels processes can be grouped into three general classes: native, augmented, and engineered. Colorimetric assays for general glycosyl hydrolase activities showed distinct differences in enzyme binding to
Volatility is an important property in fuels research because it can significantly affect performance and because, as a property, it is highly sensitive to changes in the composition of a mixture. In the laboratory, volatility is measured as a distillation
Ab initio modeling of electrochemical systems is becoming a key tool for understanding and predicting electrochemical behavior. Development and careful benchmarking of computational electrochemical methods are essential to ensure their accuracy. Here
Werickson Fortunato de Carvalho Rocha, Michele M. Schantz, David Sheen, Katrice Lippa, Pamela M. Chu
As feedstocks transition from conventional oil to increasing amounts of unconventional petroleum sources and biomass, it will be necessary to determine whether a particular fuel or fuel blend is suitable for use in engines. Certifying a fuel as safe for
A combination of cold neutron prompt gamma-ray activation analysis (CNPGAA) and thermal neutron (TN) PGAA was used to determine sulfur in fuel oils down to 0.1 % for the purpose of developing a method to provide values for certification. The cold neutron
A. Koutian, Marc J. Assael, Marcia L. Huber, Richard A. Perkins
New, wide-range reference equations for the thermal conductivity of cyclohexane as a function of temperature and density are presented. The equations are based in part upon a body of experimental data that has been critically assessed for internal
Daniel V. Esposito, Youngmin Lee, Heayoung Yoon, Paul M. Haney, Natalie Labrador, Thomas P. Moffat, A. A. Talin, Veronika A. Szalai
Abstract Three-dimensionally (3D) structured photoelectrodes offer a number of potential benefits for solar fuels production compared to conventional planar photoelectrodes, including decreased optical losses, higher surface area for catalysis, more facile
We describe preliminary models for the viscosity, thermal conductivity, and surface tension for pure fluids that are constituents of four surrogate fuels for ultralow-sulfur diesel fuels developed under the auspices of the Coordinating Research Council