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[FeFe]-hydrogenases are efficient enzymes that produce hydrogen gas under mild conditions. Synthetic model compounds containing all CO or mixed CO/PMe3 ligands have been studied with ultrafast ultraviolet (UV) or visible pump-infrared (IR) probe
The study of the coupling between the conformational properties of a polyelectrolyte chain and the distribution of counter-ions surrounding the chain is important in developing predictive theories for more complex polymer materials such as polyelectrolyte
Size-exclusion separation of a water-soluble polyelectrolyte polymer, sodium polystyrene sulfonate (NaPSS), was demonstrated on common reversed-phase (C18, C4, phenyl, and cyano) and hydrophilic interaction chromatography (HILIC) columns. The effect of
Photothermal induced resonance (PTIR) is a scanning probe technique that provides sample composition information with a lateral resolution down to 20 nm. Interest in PTIR stems from its ability to identify unknown samples at the nanoscale thanks, in first
Walter J. Lafferty, Jean-Marie Flaud, Fridolin Kwabia Tchana, Agnes Perrin, Laurent Manceron, Mustafa Ndao
A Fourier transform spectrum of phosgene (Cl2CO) has been recorded in the 17.3 μm spectral region at a temperature of 180 K and at a resolution of 0.00102 cm-1 using a Bruker IFS125HR spectrometer coupled to synchrotron radiation leading to the observation
Luke W. Arbogast, Frank Delaglio, John E. Schiel, John P. Marino
Two-dimensional (2D) 1H13C methyl NMR provides a powerful tool to probe the higher order structure (HOS) of monoclonal antibodies (mAbs), since spectra can readily be acquired on intact mAbs at natural isotopic abundance, and small changes in chemical
Jeff L. Hernandez, Nabankur Deb, Rylan M. Wolfe, Chi K. Lo, Sebastian Engmann, Lee J. Richter, John R. Reynolds
To develop an understanding of the effect spin coating or blade coating have on the morphology of polymer:fullerene thin films for organic solar cells, we have investigated the morphology of poly[5-(2-hexyldecyl)-1,3-thieno[3,4-c]pyrrole-4,6-dione-alt-5,5-
Francis J. Lovas, Vadim V. Ilyushin, Alyssa M. Johnson, Jenna Hohl, Emily A. Cloessner, Richard Lavrich
We present here the first experimental study of the microwave spectrum of deuterated 5-methyltropolone, a molecule which exhibits two large-amplitude motions: an intramolecular hydrogen transfer (deuterium transfer in the current case of deuterated 5
Tracey B. Schock, Peter D. Moeller, Rick Belisle, Christopher W. Via, Tracy A. Villareal, Kevin Beauchesne, Matthew J. Bertin, Paul Zimba
Mass spectrometry-guided isolation of the lipophilic extract of Trichodesmium thiebautii bloom material led to the isolation and structure characterization of a new thiazole-containing di-chlorinated polyketide (1). The structure of 1 was deduced using 1D
Adam J. Fleisher, David A. Long, Qingnan Liu, Lyn Gameson, Joseph T. Hodges
High-precision measurements of radiocarbon (14C) near or below a fraction modern 14C of one (F14C ≤ 1) are costly, requiring the shipment of samples to accelerator mass spectrometer (AMS) facilities that specialize in reporting rare isotope relative
Evagelia C. Laiakis, Evan L. Pannkuk, Siddheshwar Chauthe, Yi-Wen Wang, Ming Liang, Tytus Mak, Christopher A. Barker, Giuseppe Astarita, Albert J. Fornace
The potential of radiological accidents and nuclear terrorism have increased the need for development of new rapid biodosimetry methods. In addition, in a clinical setting the issue of an individual's radiosensitivity should be taken into consideration
Frank Delaglio, Gregory S. Walker, Kathleen A. Farley, Raman Sharma, Jeffrey C. Hoch, Luke Arbogast, Robert Brinson, John Marino
Nuclear Magnetic Resonance (NMR) spectroscopy is an indispensable tool in pharmaceutical science, with uses in drug discovery, development, and manufacturing. Non-Uniform Sampling (NUS) is an acquisition method for NMR experiments with two or more