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Chemistry

Analytical chemistry

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Displaying 801 - 825 of 2086

A Demonstration of Fast and Accurate Discrimination and Quantification of Chemically Similar Species Utilizing a Single Cross-Selective Chemiresistor

June 14, 2014
Author(s)
Alexander (. Vergara Tinoco, Kurt D. Benkstein, Christopher B. Montgomery, Stephen Semancik
Performance characteristics of gas-phase microsensors will determine the ultimate utility of these devices for a wide range of chemical monitoring applications. Considerable effort has led to electronic nose devices that utilize multiple cross-selective

Flux growth of Yb6.6Ir6Sn16 having mixed valent ytterbium

June 12, 2014
Author(s)
Sebastian Peter, Udumula Subbarao, Sudhindra Rayaprol, Joshua Martin, Mahalingam Balasubramanian, Christos D. Malliakas, Mercouri G. Kanatzidis
The new compound Yb6.6Ir6Sn16 was obtained as single crystals in high yield from the reaction of Yb with Ir and Sn run in excess indium. Single crystal X-ray diffraction analysis shows that Yb6.6Ir6Sn16 crystallizes in the tetragonal space group P42/nmc

Mid-Infrared Time-Resolved Frequency Comb Spectroscopy of Transient Free Radicals

June 10, 2014
Author(s)
Adam J. Fleisher, Bryce Bjork, Thinh Q. Bui, Kevin C. Cossel, Mitchio Okumura, Jun Ye
Quantitative measurements in chemical kinetics require unambiguous determinations of reactant, intermediate, and product concentrations on time scales faster than the reaction rate. Direct absorption spectroscopy in the mid-infrared (mid-IR) can fulfill

Organic Analytical Reagents for the Determination of Inorganic Ions

June 4, 2014
Author(s)
Thomas J. Bruno, Paris D. Svoronos
The table entitled Organic Analytical Reagents for the Determination of Inorganic Substances, by G. Ackermann, L. Sommer, and D. Thorburn Burns, has been revamped and considerably expanded for this edition. The many recent advancements in this area have

CCQM-K83 Draft A Report: International Comparison CCQM-K83 Halocarbons in Dry Whole Air

June 3, 2014
Author(s)
George C. Rhoderick, Franklin R. Guenther, David L. Duewer, Jeongsoon Lee, Jin Seog Kim, Dongmin Moon, Jinbok Lee
The growing awareness of climate change/global warming and continuing concerns regarding stratospheric ozone depletion will require future measurements and standards for many compounds, in particular halocarbons that are linked to these issues. In order to

CCQM-P151 Draft A Report Pilot Study CCQM P151 Halocarbons in Dry Whole Air

May 28, 2014
Author(s)
George C. Rhoderick, Franklin R. Guenther, David L. Duewer, Jeongsoon Lee, Jin S. Kim, Bradley Hall, Ray Weiss, Christina Harth, Stefan Reimann, Martin Vollmer
The growing awareness of climate change/global warming and continuing concerns regarding stratospheric ozone depletion will require future measurements and standards for many compounds, in particular halocarbons that are linked to these issues. In order to

Microsensors for Mars: Trace Analyte Detection in a Simulated Martian Environment

May 23, 2014
Author(s)
Kurt D. Benkstein, Phillip H. Rogers, Christopher B. Montgomery, C. Jin, Baranidharan Raman, Stephen Semancik
Chemiresistive microsensor arrays are being developed and tested in a simulated Martian environment. Target analyte species include trace small molecules that may indicate current geological or, potentially, biological activity on Mars. The sensing films

Nanomaterials-Enabled Photonic and Chemiresistive Sensing of Chemicals and Biochemicals

May 12, 2014
Author(s)
Charles J. Choi, Kurt D. Benkstein, Phillip H. Rogers, Christopher B. Montgomery, Stephen Semancik
Contact events occurring between target species and surface sites on sensing materials initiate front-end interactions and subsequent transduction processes that can yield viable signals for target detection. By offering high surface-to-volume ratios, and

Multiheterodyne spectroscopy with optical frequency combs generated from a continuous-wave laser

May 1, 2014
Author(s)
David A. Long, Adam J. Fleisher, Kevin O. Douglass, Stephen E. Maxwell, Katarzyna E. Bielska, Joseph T. Hodges, David F. Plusquellic
Dual-drive Mach-Zehnder modulators were utilized to produce power-leveled optical frequency combs (OFCs) from a continuous-wave laser. The resulting OFCs contained up to fifty unique frequency components and spanned more than 200 GHz. Simple changes to the

Time-resolved surface infrared spectroscopy during atomic layer deposition of TiO2 using tetrakis(dimethylamido)titanium and water

April 23, 2014
Author(s)
Brent A. Sperling, John Hoang, William A. Kimes, James E. Maslar, Kristen L. Steffens, Nhan V. Nguyen
Atomic layer deposition of titanium dioxide using tetrakis(dimethylamido)titanium (TDMAT) and water vapor is studied by reflection-absorption infrared spectroscopy (RAIRS) with a time resolution of 120 ms. Decomposition of the adsorbed TDMAT is observed

Comparison of the Properties of Cellulose Nanocrystals and Cellulose Nanofibrils Isolated From Bacteria, Tunicate, and Wood Processed Using Acid, Enzymatic, Mechanical, and Oxidative Methods

April 18, 2014
Author(s)
Iulia A. Sacui, Jeffrey W. Gilman, Ryan C. Nieuwendaal, Stephan J. Stranick, Henryk Szmacinski, Mehdi Jorfi, Christopher Weder, Johan Foster, Richard Olsson, Daniel Burnett
This work describes the study and characterization of native cellulose nanocrystals and nanofibrils (CNCs, CNFs), whose crystallinity, morphology, aspect ratio, and surface chemistry depend on the raw material source and hydrolysis conditions. Measurement

AN EXAMINATION OF METAL DEPOSITION DERIVED FROM AEROSPACE-RELATED ACTIVITY IN SEVERAL ENVIRONMENTAL MATRICES COLLECTED FROM WATERS SURROUNDING THE KENNEDY SPACE CENTER (KSC), FLORIDA

April 8, 2014
Author(s)
John Bowden, Theresa M. Cantu, Douglas M. Scheidt, Russell H. Lowers, Brian A. Nocito, Vaneica Y. Young, Louis J. Guillette
Metal deposition originating from anthropogenic activity was examined in a two-tier study using environmental samples collected from several locations at the Kennedy Space Center (KSC) and surrounding Merritt Island National Wildlife Refuge (MINWR) with

Isolated line shapes of molecular oxygen: ab initio calculations versus measurements

April 8, 2014
Author(s)
Vincent T. Sironneau, Joseph T. Hodges, Jean M. Hartmann, Julien Lamouroux
We present comparisons between measured isolated line shapes of molecular oxygen in air and those calculated, free of any adjusted parameter, using requantized Classical Molecular Dynamics Simulations (rCMDS). This work extends a previous study made for a
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