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Anzor I. Mikaia, Vladimir G. Zaikin, Alexey V. Varlamov, Nikolay A. Prostakov
Fragmentation of derivatives of 9,10-dihydroanthracene and of its heterocyclic analogues containing atoms of O, S, N, P, Si, As, Se and Te at positions 9 and/or 10 is examined. The conditions reviewed are electron impact and chemical ionization in positive
Anzor I. Mikaia, Victor Shevtsov, Sergei Poshivalov, Alexey V. Varlamov
Major fragmentation of dihydrosilaazaanthracenes, contammg an azetidine substituent, spiro-3-lactam ring, or spirotetrahydrofuryl residue at C9 upon electron impact are due to the presence of these rings. The azetidine ring may be eliminated as a radical
It is determined that dissociation of molecular ions of aryl-isoxazolines under electron ionization takes place primarily through the nitro- and halogen-containing groups. Detailed analysis of the most important fragmentation pathways are presented
Peaks of characteristic ions in the electron ionization mass spectra of substituted β-nitrostyrenes are identified, and mechanisms of their formation are determined
Anzor I. Mikaia, George A. Kliger, OA Lesik, EV Marchevskaya, Vladimir G. Zaikin, Leonid S. Glebov, Sergai Loktev
Reaction gas chromatographymass spectrometry is applied to establish optimal conditions for the synthesis of N-alkylpiperidynes. Further optimization of the reaction was carried out in a pilot plant.